Methods of ceramming glass articles having improved warp

Patent metadata

Field	Value
Publication number	US-11613491-B2
Application number	US-201916511443-A
Country	US
Kind code	B2
Filing date	Jul 15, 2019
Priority date	Jul 16, 2018
Publication date	Mar 28, 2023
Grant date	Mar 28, 2023

Abstract

Glass stack configurations including a carrier plate, setter plates, and glass sheets for thermal treatment of the glass sheets to form glass ceramic articles are provided. The glass stacking configurations and components described herein are selected to improve thermal uniformity throughout a glass stack during ceramming processes while maintaining or even reducing the stresses in the resultant glass ceramic article. Accordingly, the glass ceramic articles made according to the various embodiments described herein exhibit improved optical qualities and less warp than glass ceramic articles made according to conventional processes. Various embodiments of carrier plates, setter plates, parting agent compositions, and methods of stacking glass sheets are described.

First claim

What is claimed is:

1. A method of ceramming a plurality of glass sheets comprising:
positioning a first portion of the plurality of glass sheets in a first stack between a first setter plate and a second setter plate and a second portion of the plurality of glass sheets in a second stack between the second setter plate and a third setter plate on top of the first stack in a glass stack configuration;
forming a parting agent layer between and adjacent to one of the plurality of glass sheets and an adjacent one of the plurality of glass sheets from an aqueous dispersion of boron nitride and a colloidal inorganic binding agent; and
exposing the glass stack configuration to a ceramming cycle to ceram the plurality of glass sheets of the glass stack configuration,
wherein a ΔT of the first stack or the second stack is less than 10° C. when the glass sheets are heated to a nucleation temperature for a predetermined period of time during the ceramming cycle; or
wherein a ΔT of the first stack or the second stack is less than 10° C. when the glass sheets are heated to a crystallization temperature for a predetermined period of time during the ceramming cycle.

2. The method of claim 1 , wherein the plurality of glass sheets of the glass stack configuration have a maximum thickness variation of 21 μm or less.

3. The method of claim 1 , wherein during the predetermined period of time at which the glass sheets are maintained at the nucleation temperature, the glass stack configuration has a ΔT of 2.2° C. or less between a bottom of the first stack proximate the first setter plate and a top of the second stack proximate the third setter plate.

4. The method of claim 1 , wherein the ceramming process includes a controlled cooling from a maximum temperature in the ceramming process to a temperature of about 450° C. at a rate of 4° C./min followed by a quenching step to a temperature of approximately room temperature.

5. The method of claim 1 , wherein each of the first setter plate, the second setter plate, and the third setter plate comprise reaction bonded silicon carbide.

6. The method of claim 1 , wherein each of the first setter plate, the second setter plate, and the third setter plate have a maximum flatness of less than or equal to about 100 μm.

7. The method of claim 1 , wherein each of the first setter plate, the second setter plate, and the third setter plate has a thickness t of from about 6.5 mm to about 10 mm.

8. The method of claim 1 , wherein the glass stack configuration is supported on a carrier plate comprising steel in an open grid configuration.

9. A method of ceramming a plurality of glass sheets comprising:
reducing a thickness variation in the plurality of glass sheets;
positioning the plurality of glass sheets between a first setter plate and a second setter plate in a glass stack configuration;
forming a parting agent layer between and adjacent to one of the plurality of glass sheets and an adjacent one of the plurality of glass sheets from an aqueous dispersion of boron nitride and a colloidal inorganic binding agent; and
exposing the glass stack configuration to a ceramming cycle to ceram the plurality of glass sheets.

10. The method of claim 9 , wherein reducing the thickness variation in the plurality of glass sheets comprises reducing the thickness variation in the plurality of glass sheets to a maximum thickness variation of 21 μm or less.

11. The method of claim 9 , wherein during the predetermined period of time at which the glass sheets are maintained at a nucleation temperature, the glass stack configuration has a ΔT of 2.2° C. or less between a glass sheet proximate the first setter plate and a glass sheet proximate the second setter plate.

12. The method of claim 9 , wherein the ceramming process includes a controlled cooling from a maximum temperature in the ceramming process to a temperature of about 450° C. at a rate of 4° C./min followed by a quenching step to a temperature of approximately room temperature.

13. The method of claim 9 , wherein each of the first setter plate and the second setter plate has a maximum flatness of less than or equal to about 25 μm.

Assignees

• Corning Inc

Inventors

• Hall Jill Marie
• Hubert Mathieu Gerard Jacques
• Kittleson Andrew Peter
• Saltzer Jr John Robert

Classifications

• C03B32/02 Primary

  Thermal crystallisation, e.g. for crystallising glass bodies into glass-ceramic articles {(C03B27/012 takes precedence)} · CPC title

• C03B27/0404 Primary

  Nozzles, blow heads, blowing units or their arrangements, specially adapted for flat or bent glass sheets · CPC title

• C03C21/002

  to perform ion-exchange between alkali ions (C03C21/005 takes precedence) · CPC title

• C03B27/0413

  Stresses, e.g. patterns, values or formulae for flat or bent glass sheets · CPC title