Method for producing oxide catalyst, and method for producing unsaturated nitrile and unsaturated acid

Patent metadata

Field	Value
Publication number	US-11612880-B2
Application number	US-201716319712-A
Country	US
Kind code	B2
Filing date	Aug 8, 2017
Priority date	Aug 12, 2016
Publication date	Mar 28, 2023
Grant date	Mar 28, 2023

Abstract

The present invention provides a method for producing an oxide catalyst containing antimony, comprisinga step (A) of obtaining the oxide catalyst using antimony particles containing a diantimony trioxide as a source of the antimony,wherein an abundance of a pentavalent antimony in a surface layer of the antimony particle to be measured in XPS analysis is less than 70 atom %, andthe antimony particle has an average particle size of 1.2 μm or less.

First claim

The invention claimed is:

1. A method for producing an oxide catalyst comprising antimony, comprising
obtaining the oxide catalyst using an antimony particle comprising a diantimony trioxide as a source of the antimony, by a process including the steps of:
step (1): dissolving or dispersing a starting material containing the antimony particle to thereby obtain a formulated starting material liquid,
step (2): drying the formulated starting material liquid to thereby obtain a dried material,
step (3): calcining the dried material to thereby obtain a calcined material, and
step (4): removing projections present on the particle surface of the calcined material to thereby obtain a main body of the oxide catalyst;
wherein an abundance of a pentavalent antimony in a 2 nm surface layer of the antimony particle to be measured in XPS analysis is less than 70 atom %, and
the antimony particle has an average particle size of 1.2 μm or less,
wherein, the obtained oxide catalyst is represented by following formula (1):
Mo 1 V a Nb b Sb c X d Z e O n   (1)

wherein X represents at least one element selected from the group consisting of W, Bi, Mn, and Ti; Z represents at least one element selected from the group consisting of La, Ce, Pr, Yb, Y, Sc, Sr, and Ba; a, b, c, d, e, and n represent atomic ratios of respective elements, and 0.01≤a≤1.00, 0.01≤b≤1.00, 0.01≤c≤1.00, 0.00≤d≤1.00, 0.00≤e≤1.00; and n is a value satisfying balance among a valence.

2. The method for producing the oxide catalyst according to claim 1 , wherein an oxide catalyst further comprising 20 to 70% by mass of silica, in terms of SiO 2 , is obtained.

3. A method for producing an unsaturated nitrile, comprising a step of obtaining an oxide catalyst by the method for producing the oxide catalyst according to claim 1 , and a production step of subjecting propane or isobutane and NH 3 to a gas-phase catalytic ammoxidation reaction in the presence of the oxide catalyst obtained to obtain the unsaturated nitrile.

4. A method for producing an unsaturated acid, comprising a step of obtaining an oxide catalyst by the method for producing the oxide catalyst according to claim 1 , and a production step of subjecting propane or isobutane to a gas-phase catalytic oxidation reaction in the presence of the oxide catalyst obtained to obtain the unsaturated acid.

5. A method for producing an unsaturated nitrile, comprising a step of obtaining an oxide catalyst by the method for producing the oxide catalyst according claim 2 , and a production step of subjecting propane or isobutane and NH 3 to a gas-phase catalytic ammoxidation reaction in the presence of the oxide catalyst obtained to obtain the unsaturated nitrile.

6. A method for producing an unsaturated acid, comprising a step of obtaining an oxide catalyst by the method for producing the oxide catalyst according to claim 2 , and a production step of subjecting propane or isobutane to a gas-phase catalytic oxidation reaction in the presence of the oxide catalyst obtained to obtain the unsaturated acid.

7. The method for producing the oxide catalyst according to claim 1 , wherein
the range of the abundance of a pentavalent antimony in a 2 nm surface layer of the antimony particle is 24 atom % or more and 69 atom % or less; and/or
the range of the average particle size of antimony particles is 0.38 μm or more and 1.18 μm or less.

8. The method for producing the oxide catalyst according to claim 1 , wherein, in the formula (1), 0.01≤a≤0.189.

9. The method for producing the oxide catalyst according to claim 1 , wherein, in the formula (1), 0.02≤b≤0.70 or 0.03≤b≤0.40.

10. The method for producing the oxide catalyst according to claim 1 , wherein, in the formula (1), 0.03≤c≤0.80 or 0.05≤c≤0.50.

11. The method for producing the oxide catalyst according to claim 1 , wherein, in the formula (1), 0.001≤d≤0.50 or 0.003≤d≤0.40 or 0.005≤d≤0.30.

12. The method for producing the oxide catalyst according to claim 1 , wherein, in the formula (I), 0.0001≤e≤0.50 or 0.0005≤e≤0.30.

13. The method for producing the oxide catalyst according to claim 1 , wherein, in formula (I), 0.50≤(a/c)≤2.00 or 0.60≤(a/c)≤1.80 or 0.70≤(a/c)≤1.60.

Assignees

• Asahi Chemical Ind

Inventors

• Nagata Dai
• Miike Satoshi

Classifications

• B01J2235/00

  Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties · CPC title

• B01J35/55

  Cylinders or rings · CPC title

• Y02P20/52

  using catalysts, e.g. selective catalysts · CPC title

• B01J37/0236

  Drying, e.g. preparing a suspension, adding a soluble salt and drying · CPC title

• B01J37/08

  Heat treatment {(B01J37/0009, B01J37/0018 take precedence)} · CPC title