Tunable anisotropy of co-based nanocomposites for magnetic field sensing and inductor applications

Patent metadata

Field	Value
Publication number	US-11609281-B2
Application number	US-201816190656-A
Country	US
Kind code	B2
Filing date	Nov 14, 2018
Priority date	May 15, 2013
Publication date	Mar 21, 2023
Grant date	Mar 21, 2023

Abstract

A method includes producing an amorphous precursor to a nanocomposite, the amorphous precursor comprising a material that is substantially without crystals not exceeding 20% volume fraction; performing devitrification of the amorphous precursor, wherein the devitrification comprises a process of crystallization; forming, based on the devitrification, the nanocomposite with nano-crystals that contains an induced magnetic anisotropy; tuning, based on one or more of composition, temperature, configuration, and magnitude of stress applied during annealing and modification, the magnetic anisotropy of the nanocomposite; and adjusting, based on the tuned magnetic anisotropy, a magnetic permeability of the nanocomposite.

First claim

What is claimed is:

1. A method of controlling a nano-crystallization process in one or more geometries, the process comprising:
producing an amorphous precursor to a nanocomposite, the amorphous precursor comprising a material that is substantially without crystals such that the crystals are not exceeding a 20% volume fraction of the material;
performing devitrification of the amorphous precursor, wherein the devitrification comprises a process of crystallization;
forming, based on the devitrification, the nanocomposite with nano-crystals that comprise an induced magnetic anisotropy;
tuning, based on one or more of composition, temperature, configuration, and magnitude of stress applied during annealing and modification of a geometry of the nanocomposite, the magnetic anisotropy of the nanocomposite, wherein tuning comprises:
varying the magnitude of the stress applied during annealing to apply a given stress value to a portion of the nanocomposite, wherein the given stress value is below 400 megapascals (MPa); and

adjusting, based on the tuned magnetic anisotropy, a magnetic permeability of the nanocomposite at the portion of the nanocomposite to be below 100 based on the given stress value that is below 400 MPa.

2. The method of claim 1 , wherein the nanocomposite has a ribbon geometry with a thickness of 10-35 microns.

3. The method of claim 1 , wherein the nanocomposite has a wire geometry with a thickness of 1-20 microns and a glass coating thickness between 0.5-20 microns.

4. The method of claim 1 , wherein tuning, based on the magnitude of stress applied during annealing comprises:
applying stress to the amorphous precursor at an annealing temperature to create the nanocomposite, wherein the stress is applied in one or more of direct tension, compression, bending, and centripedal direction.

5. The method of claim 1 , wherein tuning based on the magnitude of stress applied during annealing comprises:
applying stress to the amorphous precursor by:
applying heat with one or more thermal blocks in contact with to the amorphous precursor to evenly distribute heat; and
using a feedback system to adjust annealing temperature and/or tension applied by a strain annealing system.

6. The method of claim 1 , wherein modification of the geometry comprises modification of a size of at least one of the nano-crystals.

7. The method of claim 1 , wherein the nanocomposite is a magnetic material that is included as a sensing element in a magnetic field sensor.

8. The method of claim 1 , further comprising:
adjusting a composition of the nanocomposite; and
adjusting annealing parameters for use in the stress annealing;
wherein tuning the magnetic anisotropy comprises:
tuning, based on the adjusted composition and the adjusted annealing parameters, the magnetic anisotropy.

9. The method of claim 1 , wherein the nanocomposite includes 30 atomic % or less of Iron (Fe), 30 atomic % or less of and Nickel (Ni), and 50 atomic % or less of one or more metals selected from the group comprising boron (B), carbon (C), phosphorous (P), silicon (Si), chromium (Cr), tantalum (Ta), niobium (Nb), vanadium (V), copper (Cu), aluminum (Al), molybdenum (Mo), manganese (Mn), tungsten (W), cobalt (Co) and zirconium (Zr).

10. The method of claim 1 , wherein the nano-crystals comprise crystalline grains less than approximately 10 nanometers in average diameter embedded within an amorphous matrix.

11. The method of claim 1 , wherein a Curie temperature of the nanocomposite is at least 600° C., and wherein the nanocomposite is configured for operating in temperatures up to at least 400° C.

12. The method of claim 1 , wherein the induced magnetic anisotropy is tunable up to 29 kilojoules per cubic meter.

13. The method of claim 1 , wherein the given stress value is below 350 megapascals (MPa).

14. The method of claim 1 , wherein the permeability value is less than 90.

15. The method of claim 1 , wherein the permeability value less than 80.

16. The method of claim 1 , wherein the permeability value less than 70.

17. The method of claim 1 , wherein the permeability value less than 60.

Assignees

• Univ Carnegie Mellon

Inventors

• Leary Alex M
• Ohodnicki Paul R
• Mchenry Michael E
• Keylin Vladimir
• Huth Joseph
• Kernion Samuel J

Classifications

• H01F41/0226

  from amorphous ribbons · CPC title

• H01F1/15333 Primary

  containing nanocrystallites, e.g. obtained by annealing · CPC title

• G01R33/02 Primary

  Measuring direction or magnitude of magnetic fields or magnetic flux (G01R33/20 takes precedence) · CPC title

• G01R33/0052

  Manufacturing aspects; Manufacturing of single devices, i.e. of semiconductor magnetic sensor chips (devices based on galvano-magnetic effect or the like H10N50/85) · CPC title