Lubricant compositions for direct injection engine

Patent metadata

Field	Value
Publication number	US-11608478-B2
Application number	US-202017010932-A
Country	US
Kind code	B2
Filing date	Sep 3, 2020
Priority date	Mar 25, 2015
Publication date	Mar 21, 2023
Grant date	Mar 21, 2023

Abstract

The invention is directed to a method for reducing low speed pre-ignition events in a spark-ignited direct injection internal combustion engine by supplying to the sump a lubricant composition which contains an oil of lubricating viscosity and an ashless dispersant. The ashless dispersant may be selected from succinimide compounds prepared from aliphatic or aromatic amines.

First claim

What is claimed:

1. A method for reducing low speed pre-ignition events in a spark-ignited direct injection internal combustion engine comprising supplying to the engine a lubricant composition comprising:
a base oil of lubricating viscosity;
0.5 to 2.2 wt % of a borated polyisobutylene based succinimide dispersant;
0.1 to 3 wt % of at least one ashless antioxidant; and
0.2 to 1 wt % of a magnesium detergent selected from one or more of an overbased alkylbenzene sulfonate detergent and a magnesium sulfur-free phenate detergent.

2. The method of claim 1 , wherein the engine is operated under a load with a brake mean effective pressure (BMEP) of greater than or equal to 10 bars.

3. The method of claim 1 , wherein the engine is operated at speeds less than or equal to 3,000 rpm.

4. The method of claim 1 , wherein the engine is fueled with a liquid hydrocarbon fuel, a liquid non-hydrocarbon fuel, or mixtures thereof.

5. The method of claim 4 , wherein the engine is fueled by natural gas, liquefied petroleum gas (LPG), compressed natural gas (CNG), or mixtures thereof.

6. The method of claim 1 , wherein the polyisobutylene succinimide compound is prepared from an amine comprising one or more of aliphatic polyamines, aromatic amines, polyether amines, and mixtures thereof.

7. The method of claim 1 , further comprising from 0.1 to 5 wt % of a boron-free ashless dispersant.

8. The method of claim 7 , wherein the boron-free ashless dispersant is a polyisobutylene succinimide dispersant prepared from a polyisobutylene having an average number molecular weight (M n ) of from 500 to 5000.

9. The method of claim 1 , wherein the at least one ashless antioxidant is a sulfurized olefin.

10. The method of claim 1 , wherein the at least one ashless antioxidant includes two or more antioxidants where each antioxidant is present in the lubricating composition in an amount of at least 0.1 wt %.

11. The method of claim 10 , wherein the total amount of antioxidant present in the lubricating composition is from 0.5 to 5 wt %.

12. The method of claim 11 , wherein each antioxidant is present in an amount of 0.25 to 3 wt %.

13. The method of claim 1 , wherein the lubricant composition further comprises at least one other additive selected from a metal containing overbased detergent, a phosphorus-containing anti-wear additive, a friction modifier, and a polymeric viscosity modifier.

14. The method of claim 1 , wherein the lubricating composition comprises at least 50 weight % of Group II base oil, Group III base oil, or mixtures thereof.

Assignees

• Lubrizol Corp

Inventors

• Mosier Patrick E
• Dietz Jeffry G
• Sammut Alexander
• Galic Raguz Mary
• Gieselman Matthew D

Classifications

• C10N2030/43

  Sulfur free or low sulfur content compositions · CPC title

• C10N2030/40

  Low content or no content compositions · CPC title

• C10N2060/14

  by boron or a compound containing boron · CPC title

• C10M2215/064

  Di- and triaryl amines · CPC title

• C10M2207/026

  with tertiary alkyl groups · CPC title