Positive temperature coefficient film, positive temperature coefficient electrode, positive temperature coefficient separator, and battery comprising the same

Patent metadata

Field	Value
Publication number	US-11605837-B2
Application number	US-202117340871-A
Country	US
Kind code	B2
Filing date	Jun 7, 2021
Priority date	Sep 16, 2013
Publication date	Mar 14, 2023
Grant date	Mar 14, 2023

Abstract

Provided herein is a positive temperature coefficient film comprising an inorganic positive temperature coefficient compound. Also provided herein are a positive temperature coefficient electrode, a positive temperature coefficient separator, and a positive temperature coefficient lithium secondary battery, each of which comprises the positive temperature coefficient film.

First claim

What is claimed is:

1. A positive temperature coefficient (PTC) film comprising a barium titanate and a polyamide-imide, a first layer of the PTC film being disposed on a first surface of a first electroactive layer comprising a battery cell.

2. The positive temperature coefficient film of claim 1 , wherein the inorganic PTC compound is in the form of nanoparticles.

3. The positive temperature coefficient film of claim 1 , wherein the crosslinked polymer is formed in the presence of the barium titanate.

4. The positive temperature coefficient film of claim 1 , further comprising a polyimide and a polypropylene.

5. The positive temperature coefficient film of claim 4 , further comprising a polypropylene.

6. The positive temperature coefficient film of claim 1 , comprising no less than about 50% by weight of the barium titanate and no greater than about 50% by weight of the polyamide-imide.

7. The positive temperature coefficient film of claim 6 , comprising no less than about 70% by weight of the barium titanate and no greater than about 30% by weight of the polyamide-imide.

8. The positive temperature coefficient film of claim 1 , further comprising a conductive material.

9. The positive temperature coefficient film of claim 8 , wherein the conductive material is carbon black.

10. The positive temperature coefficient film of claim 8 , comprising no less than about 50% by weight of the barium titanate, no greater than about 50% by weight of the polyamide-imide, and no greater than about 5% by weight of the conductive material.

11. The positive temperature coefficient film of claim 9 , comprising no less than about 70% by weight of the barium titanate, no greater than about 30% by weight of the polyamide-imide, and no greater than about 2% by weight of the conductive material.

12. The positive temperature coefficient film of claim 8 , further comprising a filler.

13. The positive temperature coefficient film of claim 12 , wherein the filler is a polymer.

14. The positive temperature coefficient film of claim 12 , wherein the filler is polyvinylidene fluoride or styrene butadiene rubber.

15. The positive temperature coefficient film of claim 12 , comprising no less than about 50% by weight of the barium titanate, no greater than about 50% by weight of the polyamide-imide, no greater than about 5% by weight of the conductive material, and no greater than about 10% by weight of the filler.

16. The positive temperature coefficient film of claim 12 , comprising no less than about 70% by weight of the barium titanate, no greater than about 30% by weight of the polyamide-imide, no greater than about 2% by weight of the conductive material, and no greater than about 10% by weight of the filler.

17. The positive temperature coefficient film of claim 1 , comprising no less than about 70% by weight of the barium titanate, no greater than about 30% by weight of the polyamide-imide, and no greater than about 2% of carbon black.

18. The positive temperature coefficient film of claim 1 , comprising no less than about 70% by weight of the barium titanate, no greater than about 30% of a polypropylene, no greater than about 2% of carbon black, and no greater than about 10% of a polyvinylidene fluoride.

19. The positive temperature coefficient film of claim 1 , comprising no less than about 70% by weight of the barium titanate, no greater than about 30% by weight of a polypropylene, and no greater than about 10% by weight of a polyvinylidene fluoride.

20. The positive temperature coefficient film of claim 1 , comprising no less than about 70% by weight of the barium titanate, no greater than about 30% by weight of a carboxymethyl cellulose, no greater than 2% by weight of carbon black, and no greater than about 10% by weight of a styrene butadiene rubber.

21. The positive temperature coefficient film of claim 1 , wherein the film is formed by crosslinking a precursor of the polyamide-imide in the presence of the barium titanate.

22. The positive temperature coefficient film of claim 1 , wherein the positive temperature coefficient film is formed using water as a solvent.

23. The positive temperature coefficient film of claim 1 , wherein a second layer of the positive temperature coefficient film is disposed on a second surface of a current collector coupled with the first electroactive layer, and wherein the first electroactive layer is interposed between the first layer of the positive temperature coefficient film and the second layer of the positive temperature coefficient film to prevent a direct contact between the first electroactive layer and a second electroactive layer.

24. A battery cell, comprising a first electrode, a second electrode, a separator, and an electrolyte, at least one of the first electrode, the second electrode, the separator, and the electrolyte comprising a positive temperature coefficient (PTC) film including a barium titanate and a polyamide-imide.

Assignees

• American Lithium Energy Corp

Inventors

• Fan Jiang
• Wu Dengguo

Classifications

• C09D127/16

  Homopolymers or copolymers of vinylidene fluoride · CPC title

• H01M4/525

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title

• C09K21/00

  Fireproofing materials (for use in a particular application, see the relevant places, e.g. fireproofing of wood B27K, of polymers C08, of textiles D06M, of paper D21H; fireproof paints C09D5/18) · CPC title

• C08K2003/2206

  of calcium, strontium or barium · CPC title

• H01M10/613

  Cooling or keeping cold · CPC title