Metal hydroxide based ionic liquid composition

Patent metadata

Field	Value
Publication number	US-11602737-B2
Application number	US-202016840375-A
Country	US
Kind code	B2
Filing date	Apr 4, 2020
Priority date	Nov 5, 2015
Publication date	Mar 14, 2023
Grant date	Mar 14, 2023

Abstract

The present disclosure relates to an ionic liquid composition and a process for its preparation. The process of the present disclosure is simple, single pot and efficient process for preparing the ionic liquid composition which is effective in a Friedel Craft reaction like, alkylation reaction, trans-alkylation, and acylation.
The present disclosure envisages an ionic liquid composition comprising at least one metal hydroxide; at least one metal halide; and at least one solvent. Also envisaged is a process for preparing an ionic liquid composition. The process comprises mixing in a reaction vessel, at least one metal hydroxide and at least one metal halide in the presence of at least one solvent under a nitrogen atmosphere and continuous stirring followed by cooling under continuous stirring to obtain the ionic liquid composition.

First claim

What is claimed is:

1. A process for preparing an ionic liquid composition, said process comprising the following steps:
using a single reaction vessel;
using at least one metal hydroxide;
using at least one metal halide;
using at least one solvent;
mixing at least one said metal hydroxide and at least one said metal halide in at least one said solvent under continuous stirring at a temperature in the range of 80 to 120° C. to obtain the ionic liquid composition in the form of ionic liquid clathrate;
wherein said solvent is selected from the group consisting of benzene, and toluene; and
wherein said ionic liquid clathrate is represented by Formula (I):
M1⋅M2⋅M3⋅ . . . ⋅Mn⋅solvent (Formula (I))
wherein M1 is at least one metal hydroxide;
M2, M3, . . . , Mn are metal halides;
n is in the range of 2 to 20; and
the dot (⋅) between M1, M2, M3, Mn and solvent represents at least one coordinate covalent bond and weak van der waal's force,
wherein the at least one said metal hydroxide is selected from the group consisting of aluminum hydroxide, chromium hydroxide, iron hydroxide, cobalt hydroxide, nickel hydroxide, cupric hydroxide, tin hydroxide, and lead hydroxide, and
wherein the at least one said metal halide is selected from the group consisting of aluminum chloride, ferric chloride, aluminum bromide, titanium tetrachloride, cupric chloride, magnesium chloride, copper chloride, zinc chloride, cuprous chloride, and chromium chloride.

2. The process as claimed in claim 1 , wherein said ionic liquid clathrate is a chemical substance consisting of a lattice of the metal hydroxide and the metal halide that traps or contains molecules of solvent.

3. The process as claimed in claim 1 , wherein said ionic liquid clathrate comprising the metal hydroxide.

4. The process as claimed in claim 1 , wherein said ionic liquid composition comprises:
said metal hydroxide in an amount in the range of 3% to 40% by weight of the composition,
said metal halide in an amount in the range of 8% to 80% by weight of the composition; and
said at least one solvent in an amount in the range of 10% to 70% by weight of the composition.

5. The process as claimed in claim 1 , wherein the metal of at least one said metal hydroxide and the metal of at least one said metal halide are same or are different.

6. The process as claimed in claim 1 , wherein said ionic liquid composition has a viscosity ranging from 3 cP to 500 cP and density ranging from 1.00 to 2.50.

7. The process as claimed in claim 1 , wherein 1 mole of aluminium hydroxide is heated with at least 1.5 moles of aluminium chloride in a benzene at a temperature of 80° C. to obtain the ionic liquid composition.

Assignees

• Reliance Industries Ltd

Inventors

• Dukhande Vibhuti
• Uppara Parasu Veera
• Aduri Pavankumar
• Raje Vivek Prabhakar
• Salvi Prathmesh Pradeep
• Kotra Viswanath
• Sakhalkar Mangesh
• Ratnaparkhi Uday Meghashyam

Classifications

• B01J27/132

  with chromium, molybdenum, tungsten or polonium · CPC title

• B01J31/02

  containing organic compounds or metal hydrides · CPC title

• C07C2/68 Primary

  with halides · CPC title

• B01J23/14

  of germanium, tin or lead · CPC title

• B01J23/72

  Copper · CPC title