Separation and recovery method of polyarlene sulfide

Patent metadata

Field	Value
Publication number	US-11597800-B2
Application number	US-201917049242-A
Country	US
Kind code	B2
Filing date	Oct 18, 2019
Priority date	Oct 19, 2018
Publication date	Mar 7, 2023
Grant date	Mar 7, 2023

Abstract

The present disclosure relates to a method of more efficiently separating and recovering a polyarylene sulfide exhibiting excellent strength, heat resistance, flame retardancy, and processability when processed into a molded product after polymerization.

First claim

The invention claimed is:

1. A separation and recovery method comprising:
introducing a mixed slurry comprising polyarylene sulfide particles, alkali metal halide particles and an amide-based compound into a decanter centrifugal separator,
operating the decanter centrifugal separator at a speed of 1000 rpm to 2500 rpm such that the polyarylene sulfide particles are first settled and separated from the mixed slurry, and then the alkali metal particles are settled and removed from the mixed slurry,
wherein the polyarylene sulfide particles in the mixed slurry have a particle size of 100 micrometers to 2000 micrometers, and wherein the alkali metal halide particles in the mixed slurry have a particle size of 5 micrometers to 30 micrometers.

2. The separation and recovery method according to claim 1 , wherein the mixed slurry is a waste liquid produced in a synthesizing or washing process of the polyarylene sulfide.

3. The separation and recovery method according to claim 1 , wherein the polyarylene sulfide particles in the mixed slurry have a density of 1 g/cm 3 to 1.5 g/cm 3 .

4. The separation and recovery method according to claim 1 , wherein the alkali metal halide particles comprise at least one selected from the group consisting of sodium chloride and sodium iodide.

5. The separation and recovery method according to claim 1 , wherein the alkali metal halide particles have a density of 1.9 g/cm 3 to 3 g/cm 3 .

6. The separation and recovery method according to claim 1 , wherein the amide-based compound comprises at least one selected from the group consisting of N,N-dimethylformamide, N,N-dimethylacetamide, N-methyl-2-pyrrolidone (NMP), N-cyclohexyl-2-pyrrolidone, N-methyl-ε-caprolactam, 1,3-dialkyl-2-imidazolidinone, tetramethyl urea, and hexamethyl phosphate triamide.

7. The separation and recovery method according to claim 1 , wherein the mixed slurry further comprises at least one selected from the group consisting of sodium hydroxide, sodium acetate, sodium sulfide, sodium hydrosulfide, and p-dichlorobenzene.

8. A preparation method of a polyarylene sulfide, comprising:
dehydrating a hydrosulfide of an alkali metal and a hydroxide of an alkali metal in a mixed solvent of water and an amide-based compound to prepare a sulfur source comprising a sulfide of an alkali metal and the mixed solvent;
adding a dihalogenated aromatic compound and an amide-based compound to a reactor containing the sulfur source, and performing a polymerization reaction, thus forming a mixed slurry comprising polyarylene sulfide particles, alkali metal halide particles, and the amide-based compound;
introducing the mixed slurry into a decanter centrifugal separator, and
operating the decanter centrifugal separator at a speed of 1000 rpm to 2500 rpm, such that the polyarylene sulfide particles are first settled and separated from the mixed slurry, and then the alkali metal particles are settled and removed from the mixed slurry, wherein the polyarylene sulfide particles in the mixed slurry have a particle size of 100 micrometers to 2000 micrometers, and wherein the alkali metal halide particles in the mixed slurry have a particle size of 5 micrometers to 30 micrometers.

9. The separation and recovery method according to claim 1 , wherein the polyarylene sulfide particles in the mixed slurry have a particle size of 150 micrometers to 1800 micrometers, and wherein the alkali metal halide particles in the mixed slurry have a particle size of 6 micrometers to 28 micrometers.

10. The separation and recovery method according to claim 8 , wherein the polyarylene sulfide particles in the mixed slurry have a particle size of 150 micrometers to 1800 micrometers, and wherein the alkali metal halide particles in the mixed slurry have a particle size of 6 micrometers to 28 micrometers.

Assignees

• Lg Chemical Ltd

Inventors

• Kim Hansol
• Han Joong Jin
• Jo Sanghwan

Classifications

• C08G75/0204

  Polyarylenethioethers · CPC title

• C08G75/0281 Primary

  Recovery or purification · CPC title

• C08G75/00 Primary

  Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule · CPC title

• C08G75/0209

  derived from monomers containing one aromatic ring · CPC title

• C08G75/0254

  using metal sulfides · CPC title