Iridium alloy catalyst having reversible catalytic activity and preparation method thereof

Patent metadata

Field	Value
Publication number	US-11588157-B2
Application number	US-202117197893-A
Country	US
Kind code	B2
Filing date	Mar 10, 2021
Priority date	Mar 10, 2020
Publication date	Feb 21, 2023
Grant date	Feb 21, 2023

Abstract

Proposed is an iridium alloy catalyst having reversible catalytic activity for an oxygen evolution reaction (OER), a hydrogen evolution reaction (HER), and a hydrogen oxidation reaction (HOR) by including an iridium alloy including iridium (Ir) and nickel (Ni). The iridium alloy catalyst according to the present disclosure is rapidly converted to an iridium alloy catalyst in an oxide form and an iridium alloy catalyst in a metallic form according to applied voltage by controlling its crystallinity. Thus, even in case an oxide layer is formed after the OER, the oxidation layer disappears during the HER and HOR and the properties of an iridium metal catalyst remain, thereby maintaining HER/HOR performance.

First claim

What is claimed is:

1. An iridium alloy catalyst having reversible catalytic activity for an oxygen evolution reaction, a hydrogen evolution reaction, and a hydrogen oxidation reaction, the iridium alloy catalyst comprising:
an iridium alloy including iridium (Ir) and nickel (Ni).

2. The iridium alloy catalyst of claim 1 , wherein the iridium alloy is an alloy including 1 to 100 parts by weight of nickel based on 100 parts by weight of iridium.

3. The iridium alloy catalyst of claim 1 , wherein the iridium alloy catalyst is a catalyst in which the iridium alloy is supported on a carbon-based support, and
the iridium alloy catalyst includes 5 to 100 parts by weight of the iridium alloy based on 100 parts by weight of the carbon-based support.

4. The iridium alloy catalyst of claim 1 , wherein the iridium alloy catalyst has a particle size of 0.5 to 10 nm measured by a transmission electron microscope (TEM).

5. The iridium alloy catalyst of claim 1 , wherein the iridium alloy catalyst is rapidly converted to an iridium alloy catalyst in an oxide form and an iridium alloy catalyst in a metallic form according to applied voltage,
the iridium alloy catalyst in the metallic form catalyzes the hydrogen evolution reaction and the hydrogen oxidation reaction,
and the iridium alloy catalyst in the oxide form catalyzes the oxygen evolution reaction.

6. The iridium alloy catalyst of claim 1 , wherein the iridium alloy catalyst is used as a catalyst for an anode of a fuel cell.

7. The iridium alloy catalyst of claim 1 , wherein the iridium alloy catalyst is used as a catalyst for an electrode of a water electrolysis cell.

8. A water electrolysis cell, comprising the iridium alloy catalyst of claim 1 .

9. A method of preparing an iridium alloy catalyst, the method comprising:
dispersing a carbon support, an iridium salt, and a nickel salt in water;
carrying out drying to obtain powder;
pulverizing the powder; and
carrying out heat treatment to obtain an iridium alloy catalyst,
wherein the heat treatment is carried out at a temperature of 400 to 1000° C. under an inert condition while introducing a reducing gas.

10. A fuel cell, comprising the iridium alloy catalyst of claim 1 as a catalyst for an anode.

Assignees

• Korea Inst Sci & Tech

Inventors

• Oh Hyung Suk
• Lee Woong Hee
• Min Byoung Koun
• Hwang Yun Jeong
• Lee Ung
• Lee Dong Ki
• Won Da Hye
• Koh Jai Hyun

Classifications

• C25B1/01

  Products · CPC title

• C25B11/054 Primary

  Electrodes comprising electrocatalysts supported on a carrier · CPC title

• C25B1/00 Primary

  Electrolytic production of inorganic compounds or non-metals · CPC title

• B22F1/142

  Thermal or thermo-mechanical treatment · CPC title

• C25B11/065

  Carbon · CPC title