Fluid loss additive for low-Portland or non-Portland cements

Patent metadata

Field	Value
Publication number	US-11584877-B2
Application number	US-202017022975-A
Country	US
Kind code	B2
Filing date	Sep 16, 2020
Priority date	Sep 16, 2020
Publication date	Feb 21, 2023
Grant date	Feb 21, 2023

Abstract

A cement composition can include: water; cement, wherein less than 75 w/w % of the total amount of the cement is Portland cement; and a fluid loss additive, wherein the fluid loss additive comprises a polymer network having at least one branching point formed with a monomer and a cross-linking agent that comprises at least three active functional groups. The cement can also be a non-Portland cement. The monomer can be a vinyl ester-based monomer that is polymerized with the cross-linking agent to form the polymer network. The cement composition can be used in an oil and gas operation.

First claim

What is claimed is:

1. A method of cementing in a subterranean formation comprising:
introducing a cement composition into the subterranean formation, the cement composition comprising:
(i) cement, wherein less than 75 w/w % of the total amount of cement is Portland cement;
(ii) water; and
(iii) a fluid loss additive, wherein the fluid loss additive consists essentially of a polymer network having at least one branching point formed with a vinyl ester-based monomer and a cross-linking agent that comprises at least three active functional groups; and
allowing the cement composition to set.

2. The method according to claim 1 , wherein the water is selected from the group consisting of freshwater, brackish water, and saltwater, in any combination thereof in any proportion.

3. The method according to claim 1 , wherein the cement is selected from the group consisting of Portland cements, gypsum cements, high alumina content cements, slag cements, high magnesia content cements, pozzolan, fly ash, lime, slaked lime, sorels cements, and combinations thereof.

4. The method according to claim 1 , wherein less than 30 w/w % of the total amount of cement is Portland cement.

5. The method according to claim 1 , wherein the vinyl ester-based monomer is selected from vinyl acetate, vinyl propionate, vinyl propionate, vinyl valerate, vinyl caprate, vinyl laurate, vinyl stearate, vinyl benzoate, or vinyl pivalate.

6. The method according to claim 1 , wherein the vinyl ester-based monomer is co-polymerized with a second monomer selected from: a-olefin monomers; methyl (meth)acrylate, (meth)acrylic acid alkyl ester monomers; unsaturated amide monomers; unsaturated carboxylic acid monomers; alkyl ester monomers of unsaturated carboxylic acids; unsaturated carboxylic acid anhydrides; salts of unsaturated carboxylic acids; glycidyl group-containing monomers; 2-acrylamido-2-methylpropane sulfone including sulfonic acid group-containing monomers; phosphoric acid group-containing monomers; or alkyl vinyl ether monomers.

7. The method according to claim 1 , wherein the cross-linking agent is selected from propanediol divinyl ether, triallyl ethers, triallyl phosphate, triallyl isocyanurate (TTT), pentaerythritol triacrylate, 1,1,1-trimethylolpropane triacrylate, 1,1,1-trimethylolpropane trimethacrylate, dipentaerythritol pentaacrylate, pentaerythritol tetraacrylate, triallyl cyanurate, butanediol divinyl ether, tetraallyl pentaerythritol, tetraallyl orthosilicate, N˜1˜,N˜1˜,N˜2˜,N˜2˜-Tetraallyl-N′˜1˜,N′˜2˜-bis(4-methylphenyl)ethanediimidamide, tetraallyl 1,2,3,4-cyclopentanetetracarboxylate, tetraallylsilane, tetraallyl pyromellitate, pentaerythritol tetraallyl ether, N,N,N′,N′-tetraallyl-2,6-pyridinedicarboxamide, 1,2,3,5,5-Pentaallyl-1,3-cyclopentadiene, poly(allyl glycidyl ether)-b-poly(ethylene oxide)-b-poly(allylglycidyl ether), or poly(allyl glycidyl ether)-stat-poly(alkyl glycidyl ether)-block-poly(ethylene glycol)-block-poly(allyl glycidyl ether)-stat-poly(alkyl glycidyl ether).

8. The method according to claim 1 , wherein the mole ratio of the cross-linking agent to monomer is in the range of 0.005:100 to 10:100.

9. The method according to claim 1 , wherein a copolymerization amount of a monomer residue from the cross-linking agent is in the range of 0.001 to 1.0 mol % based on 100 mol % of the structural unit derived from the vinyl ester-based monomer.

10. The method according to claim 1 , wherein the viscosity average degree of polymerization of the polymer network is in the range of 1,000 to 10,000.

11. The method according to claim 1 , wherein the fluid loss additive is in a concentration in the range of 0.01% to 30% by weight of the cement.

12. The method according to claim 1 , wherein the cement composition has an API fluid loss of less than 200 mL/30 min at a temperature up to 250° F. and a pressure differential of 1,000 psi.

13. The method according to claim 1 , wherein the cement composition has an API fluid loss of less than 100 mL/30 min at a temperature up to 250° F. and a pressure differential of 1,000 psi.

14. The method according to claim 1 , wherein the cement composition has a density in the range of 4 to 20 pounds per gallons.

15. The method according to claim 1 , further comprising combining the cement, the water, and the fluid loss additive together prior to introduction into the subterranean formation, and wherein the fluid loss additive is in dry form that is added to the cement and water on the fly.

16. The method according to claim 1 , further comprising combining the cement, the water, and the fluid loss additive together prior to introduction into the subterranean formation, and wherein the fluid loss additive is in a liquid suspension form when added to the cement and water.

Assignees

• Halliburton Energy Services Inc

Inventors

• Pearl Jr William Cecil
• Lewis Samuel

Classifications

• C04B28/10

  Lime cements or magnesium oxide cements · CPC title

• C04B24/2623

  Polyvinylalcohols; Polyvinylacetates · CPC title

• E21B33/13 Primary

  Methods or devices for cementing, for plugging holes, crevices or the like · CPC title

• C09K8/487 Primary

  Fluid loss control additives; Additives for reducing or preventing circulation loss · CPC title

• C04B28/06

  Aluminous cements (monolithic refractories or refractory mortars C04B35/66) · CPC title