Assembly and method for interchangeably holding an electrochemical substrate

Patent metadata

Field	Value
Publication number	US-11579115-B2
Application number	US-201916421550-A
Country	US
Kind code	B2
Filing date	May 24, 2019
Priority date	May 24, 2019
Publication date	Feb 14, 2023
Grant date	Feb 14, 2023

Abstract

An electrochemical substrate holder assembly, including: a first housing and a second housing; wherein the first housing and the second housing collectively define an interior space; a first gasket coupled to the first housing and adapted to contact a first side of a substrate; and a second gasket coupled to the second housing and adapted to contact a second side of the substrate; wherein the first gasket and the second gasket are collectively adapted to hold the substrate within the interior space. The first housing defines a first port adapted to receive a first electrical lead to electrically contact the first side of the substrate. The second housing defines a second port adapted to allow a fluid to pass there through to fluidly contact at least the second side of the substrate. The second housing is adapted to receive one or more of a second and third electrical lead.

First claim

What is claimed is:

1. An electrochemical substrate holder and substrate assembly, comprising:
a first housing;
a second housing coupled to the first housing and disposed in a thermally insulating block;
wherein the first housing and the second housing are made of a metallic, conductive material and collectively define an interior space in which a substrate is held;
wherein an externally threaded portion of the first housing is threaded into an internally threaded portion of the second housing, and an external portion of the first housing and the second housing each are hexagonal in shape and adapted for engagement with a wrench;
the substrate having a first side and a second side, the substrate being a solid foil or a solid disc and configured for electrochemical testing thereof of at least one of surface corrosion, pitting and crystal growth;
a first gasket coupled to the first housing and adapted to contact and seal the first side of the substrate, wherein the first gasket comprises an electrically insulating material; and
a second gasket coupled to the second housing and adapted to contact and seal the second side of the substrate, wherein the second gasket comprises an electrically insulating material;
wherein the first gasket and the second gasket are each made of a material stable at a temperature of 600 degrees C. and are collectively adapted to hold the substrate within the interior space collectively defined by the first housing and the second housing, and electrically insulate the substrate from the first housing and the second housing, and wherein the substrate is configured to be submerged in and electrochemically tested in an electrolyte bath;
wherein the first housing defines a first port adapted to receive a first electrical lead there through to electrically contact the first side of the substrate through the first gasket, wherein the first electrical lead is disposed within an insulating ceramic sheath and is coupled to the first housing via an insulated compression fitting and configured to be compressed against the substrate; and
wherein the second housing defines a second port adapted to allow a fluid to pass there through to fluidly contact the second side of the substrate through the second gasket, and the second housing is adapted to receive a second electrical lead and a third electrical lead, and the assembly is adapted to make electrical contact between the first electrical lead, the second electrical lead, the third electrical lead and the substrate; and the second housing includes a heating element configured to heat the substrate and the bath, thereby forming the electrochemical substrate holder and substrate assembly;
and wherein the first housing and the second housing, with the enclosed substrate therein are adapted to be submerged in the electrolyte bath with the substrate adapted to be exposed to the electrolyte bath through the second port; and
wherein the assembly is adapted for use in a high temperature system of 200 to 600 degrees C.

2. The electrochemical substrate holder and substrate assembly of claim 1 , wherein the first housing and second housing are each manufactured from one or more of stainless steel, a nickel alloy, and aluminum.

3. The electrochemical substrate holder and substrate assembly of claim 1 , wherein the first gasket and the second gasket are each manufactured from one or more of polytetrafluoroethylene, a ceramic fiber, a fluorphlogopite mica in a borosilicate glass matrix, silica, magnesia, alumina, potassium oxide, boron oxide, and fluorine.

4. The electrochemical substrate holder and substrate assembly of claim 1 , wherein the first gasket and the second gasket each comprise an annular structure.

5. The electrochemical substrate holder and substrate assembly of claim 1 , wherein the substrate comprises one of a planar foil, a planar disc, a concave foil, a concave disc, a convex foil, and a convex disc.

6. The electrochemical substrate holder and substrate assembly of claim 1 , wherein the substrate comprises one or more of an alkali metal, an alkaline earth, a non-metal, a metalloid, a ferrous metal, a lanthanide, an actinide, an alloy, a refractory metal, a conductive polymer, and a biological/organic moiety-functionalized substrate.

7. A method of performing an electrochemical test on a substrate, comprising:
providing a first housing;
providing a second housing;
coupling the second housing to the first housing by threading an externally threaded portion of the first housing into an internally threaded portion of the second housing, wherein an external portion of the first housing and the second housing each are hexagonal in shape and adapted for engagement with a wrench, and the second housing is disposed in a thermally insulating block;
wherein the first housing and the second housing are made of a metallic, conductive material and collectively define an interior space in which a substrate is held;
providing the substrate, the substrate having a first side and a second side, the substrate being a solid foil or a solid disc and, configured for electrochemical testing thereof of at least one of surface corrosion, pitting and crystal growth;
providing a first gasket coupled to the first housing and adapted to contact and seal the first side of the substrate, wherein the first gasket comprises an electrically insulating material;
providing a second gasket coupled to the second housing and adapted to contact and seal the second side of the substrate, wherein the second gasket comprises an electrically insulating material;
wherein the first gasket and the second gasket are each made of a material stable at a temperature of 600 degrees C. and are collectively adapted to hold the substrate within the interior space collectively defined by the first housing and the second housing, and electrically insulate the substrate from the first housing and the second housing;
forming an assembly by disposing the substrate between the first gasket and the second gasket within the interior space collectively defined by the first housing and the second housing, wherein the substrate is submerged in and electrochemically tested in an electrolyte bath for at least one of surface corrosion, pitting and crystal growth;
wherein the first housing defines a first port adapted to receive a first electrical lead there through to electrically contact the first side of the substrate through the first gasket, wherein the first electrical lead is disposed within an insulating ceramic sheath and is coupled to the first housing via an insulated compression fitting and compressed against the substrate; and
wherein the second housing defines a second port adapted to allow a fluid to pass there through to fluidly contact the second side of the substrate through the second gasket, and the second housing receives a second electrical lead and a third electrical lead, and the assembly is adapted to make electrical contact between the first electrical lead, the second electrical lead, the third electrical lead and the substrate: and the second housing includes a heating element configured to heat the substrate and the bath;
wherein the first housing and the second housing, with the enclosed substrate therein are submerged in the electrolyte bath with the substrate exposed to the electrolyte bath through the second port; and wherein the assembly is adapted for use in a high temperature system of 200 to 600 degrees C.

8. The method of claim 7 , further comprising introducing the fluid into a portion of the interior space collectively defined by the first housing and the second housing on the second side of the substrate.

9. The method of claim 7 , further comprising applying an electrical voltage/cu

Assignees

• Cons Nuclear Security Llc

Inventors

• Freiderich John W
• Boyd Tasha L
• Green Benjamin D

Classifications

• G01N27/416 Primary

  Systems (G01N27/27 takes precedence) · CPC title

• G01N27/28 Primary

  Electrolytic cell components · CPC title