High-strength hot-dip galvanized steel sheet having excellent surface quality and spot weldability, and manufacturing method therefor
US-2018371570-A1 · Dec 27, 2018 · US
US11578378B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11578378-B2 |
| Application number | US-201816754589-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 19, 2018 |
| Priority date | Oct 24, 2017 |
| Publication date | Feb 14, 2023 |
| Grant date | Feb 14, 2023 |
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Method for the manufacture of a galvannealed steel sheet includes the following steps: A) the provision of a pre-coated steel sheet coated with a first coating comprising iron and nickel, such steel sheet having the following chemical composition in weight percent 0.10<C<0.40%, 1.5<Mn<3.0%, 0.7<Si<2.0%, 0.05<Al<1.0%, 0.75<(Si+Al)<3.0% and on a purely optional basis, one or more elements such as Nb≤0.5%, B≤0.005%, Cr≤1.0%, Mo≤0.50%, Ni≤1.0%, Ti≤0.5%, the remainder of the composition making up of iron and inevitable impurities resulting from the elaboration, B) the thermal treatment of such pre-coated steel sheet at a temperature between 600 to 1000° C., C) the hot-dip coating of the steel sheet obtained in step B) with a second coating based on zinc and D) an alloying treatment to form a galvannealed steel sheet.
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The invention claimed is: 1. A method for the manufacture of a galvannealed steel sheet comprising the following steps: providing a pre-coated steel sheet coated with a first coating comprising iron and nickel, such steel sheet having the following chemical composition in weight percent: 0.10<C<0.40%, 1.5<Mn<3.0%, 0.7<Si<2.0%, 0.05≤Al<1.0%, 0.75<(Si+Al)<3.0%, and on a purely optional basis, one or more elements such as Nb≤0.5%, B≤0.005%, Cr≤1.0%, Mo≤0.50%, Ni≤1.0%, Ti≤0.5%, a remainder of the composition making up of iron and inevitable impurities resulting from processing; thermally treating the pre-coated steel sheet at a temperature between 600 to 1000° C.; hot-dip coating of the steel sheet obtained by the thermally treating step with a second coating based on zinc; and providing an alloying treatment to form a galvannealed steel sheet, wherein the first coating includes from 10% to 75% by weight of iron. 2. The method as recited in claim 1 wherein the first coating includes from 25.0 to 65.0% by weight of iron. 3. The method as recited in claim 2 wherein the first coating includes from 40 to 60% of weight of iron. 4. The method as recited in claim 1 wherein the first coating includes from 25 to 90% by weight of nickel. 5. The method as recited in claim 4 wherein the first coating includes from 35 to 75% by weight of nickel. 6. The method as recited in claim 5 wherein the first coating includes from 40 to 60% by weight of nickel. 7. The method as recited in claim 1 wherein the first coating consists of iron and nickel. 8. The method as recited in claim 1 wherein the first coating has a thickness equal or above 0.5 μm. 9. The method as recited in claim 8 wherein the first coating has a thickness between 0.8 and 5.0 μm. 10. The method as recited in claim 9 wherein the first coating has a thickness between 1.0 and 2.0 μm. 11. The method as recited in claim 1 wherein the second coating includes above 70% by weight of zinc. 12. The method as recited in claim 11 wherein the second coating includes above 80% by weight of zinc. 13. The method as recited in claim 12 wherein the second coating includes above 85% by weight of zinc. 14. The method as recited in claim 1 wherein the second coating consists of zinc. 15. The method as recited in claim 1 wherein the thermally treating step is a continuous annealing. 16. The method as recited in claim 1 wherein the thermally treating step is performed in an atmosphere comprising from 1 to 10% of H 2 at a dew point between −30 and −60° C. 17. The method as recited in claim 1 wherein the alloying treatment is performed by heating the coated steel sheet obtained after the thermally treating step at a temperature between 460 and 550° C. 18. The method as recited in claim 1 wherein the first coating consists of iron and from 25% to 90% by weight of nickel.
Zinc or cadmium or alloys based thereon · CPC title
Two or more thermal pretreatments · CPC title
Adjusting the composition of the atmosphere · CPC title
Cooling or quenching · CPC title
Plates; Strips · CPC title
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