Systems and processes for molten media pyrolysis

Patent metadata

Field	Value
Publication number	US-11577955-B2
Application number	US-201916540300-A
Country	US
Kind code	B2
Filing date	Aug 14, 2019
Priority date	Aug 30, 2018
Publication date	Feb 14, 2023
Grant date	Feb 14, 2023

Abstract

Systems and methods for molten media pyrolysis for the conversion of methane into hydrogen and carbon-containing particles are disclosed. The systems and methods include the introduction of seed particles into the molten media to facilitate the growth of larger, more manageable carbon-containing particles. Additionally or alternatively, the systems and methods can include increasing the residence time of carbon-containing particles within the molten media to facilitate the growth of larger carbon-containing particles.

First claim

The invention claimed is:

1. A process for molten media pyrolysis, comprising:
introducing methane gas into a reaction vessel comprising molten media, the reaction vessel having a bottom surface, wherein the molten media is present in a first layer, and wherein a first side of the first layer contacts the bottom surface;
converting at least a portion of the methane gas into hydrogen and carbon-containing particles by exposing the methane gas to the molten media;
removing at least a portion of the molten media from the first layer;
introducing the at least a portion of the molten media into a region within the reaction vessel that is opposite from the bottom surface, wherein the at least a portion of the molten media transfers to the first layer, thereby creating a molten media current directed toward the bottom surface of the reaction vessel; and
isolating carbon-containing particles having an average characteristic dimension of about 0.2 mm or more from the molten media, the characteristic dimension of a particle being defined as the diameter of the smallest bounding sphere that can contain a particle, wherein isolating carbon-containing particles having an average characteristic dimension of about 0.2 mm or more from the molten media comprises removing particles via a carbon particle exit conduit coupled to the reaction vessel adjacent a top portion of the reaction vessel, the removing comprising utilizing a screw feeder coupled to the reaction vessel, the carbon particle exit conduit comprising the screw feeder.

2. The process according to claim 1 , wherein the removing the at least a portion of the molten media from the first layer comprises introducing the least a portion of the molten media into a circulation conduit in fluid communication with the first layer of molten media.

3. The process according to claim 1 , wherein the molten media comprises a molten metal, molten salt, or a combination thereof.

4. The process according to claim 1 , wherein the molten media comprises a molten metal, the molten metal comprising iron, aluminum, nickel, lead, bismuth, tin, or a combination thereof.

5. The process according to claim 4 , wherein the molten media comprises a first layer of the molten metal and a second layer of a molten salt, the first layer of the molten metal being positioned between the second layer of the molten salt and the bottom surface of the reaction vessel.

6. The process according to claim 1 , wherein the isolating carbon-containing particles having an average characteristic dimension of about 0.2 mm or more comprises isolating carbon-containing particles having an average characteristic dimension of about 0.4 mm or more.

7. A process for molten media pyrolysis, comprising:
introducing methane gas into a partially separated volume within a reaction vessel, the reaction vessel and the partially separated volume within the reaction vessel comprising molten media;
converting the methane gas into hydrogen and carbon-containing particles, the carbon-containing particles comprising carbon-containing particles having an average characteristic dimension of 0.2 mm or more, the characteristic dimension of a particle being defined as the diameter of the smallest bounding sphere that can contain a particle; and
removing at least a portion of the carbon-containing particles having an average characteristic dimension of 0.2 mm or more,
wherein the reaction vessel is a loop reactor, wherein the partially separated volume of the reaction vessel is a first side portion of first and second side portions connecting the top portion of the reaction vessel to a bottom portion that is adjacent the bottom surface of the reaction vessel,
wherein removing at least a portion of the carbon-containing particles having an average characteristic dimension of 0.2 mm or more comprises removing particles via a carbon particle exit conduit coupled to the reaction vessel adjacent the top portion, and
wherein the removing at least a portion of the carbon-containing particles having an average characteristic dimension of 0.2 mm or more comprises utilizing a screw feeder coupled to the reaction vessel, the carbon particle exit conduit comprising the screw feeder.

8. The process according to claim 7 , wherein the partially separated volume within the reaction vessel comprises a side wall, wherein at least a portion of the side wall comprises perforations adapted to allow molten media and carbon-containing particles to travel through the perforations.

9. The process according to claim 7 , wherein the methane feed per unit reactor volume per time is 0.1 kg/m 3 /min-10 kg/m 3 /min.

10. The process according to claim 7 , wherein the molten media comprises a molten metal, a molten salt, or a combination thereof.

11. The process according to claim 10 , wherein the molten media comprises a molten metal present in a first layer in the volume of the reaction vessel and a molten salt present in a second layer in the volume of the reaction vessel, wherein the reaction vessel comprises a bottom surface, and wherein the first layer of the molten metal is positioned between the second layer of the molten salt and the bottom surface.

12. The process according to claim 11 , further comprising removing at least a portion of the molten salt from the volume of the reaction vessel; exposing the at least a portion of the molten salt to thermal energy outside the volume of the reaction vessel; and returning the at least a portion of the molten salt to the volume of the reaction vessel.

13. The process according to claim 10 , wherein the molten metal comprises iron, nickel, lead, bismuth, tin, or a combination thereof; b) wherein the molten salt comprises MgCl 2 , NaCl, or a combination thereof; or c) a combination of a) and b).

14. A system for molten media pyrolysis, comprising:
a reaction vessel comprising at least one partially separated volume within the reaction vessel, the reaction vessel and the at least one partially separated volume comprising molten media, wherein the at least one partially separated volume is coupled to a bottom surface of the reactor vessel and extends toward an opposing top portion of the reaction vessel; and
a methane gas source coupled to the at least one partially separated volume within the reaction vessel and adapted to supply methane to the at least one partially separated volume within the reaction vessel,
wherein the reaction vessel is a loop reactor, wherein the at least one partially separated volume of the reaction vessel is a first side portion of first and second side portions connecting the top portion of the reaction vessel to a bottom portion that is adjacent the bottom surface of the reaction vessel, and
wherein the system further comprises a carbon particle exit conduit coupled to the reaction vessel adjacent the top portion, the carbon particle exit conduit comprising a screw feeder.

15. The system of claim 14 , wherein the molten media comprises a molten metal, molten salt, or a combination thereof.

16. The system of claim 14 , further comprising one or more thermal elements coupled to an external surface of the reaction vessel.

17. The system of claim 16 , wherein the one or more thermal elements are coupled to an external surface of the first side portion of the reaction vessel.

18. The system of claim 14 , further comprising a hydrogen gas exit conduit coupled to the top portion of the reaction vessel.

Assignees

• Exxonmobil Technology & Engineering Company

Inventors

• Gupta Ramesh
• Raman Sumathy
• Caram Hugo S
• Dankworth David C

Classifications

• C01B3/34 Primary

  by reaction of hydrocarbons with gasifying agents · CPC title

• B01J19/1875

  internally, i.e. the mixture circulating inside the vessel such that the upwards stream is separated physically from the downwards stream(s) · CPC title

• C01B2203/0805

  Methods of heating the process for making hydrogen or synthesis gas · CPC title

• B01J19/006

  Baffles · CPC title

• B01J2219/00159

  controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling · CPC title