Separation apparatus and method of operating separation apparatus

Patent metadata

Field	Value
Publication number	US-11577205-B2
Application number	US-202016912838-A
Country	US
Kind code	B2
Filing date	Jun 26, 2020
Priority date	Jul 19, 2019
Publication date	Feb 14, 2023
Grant date	Feb 14, 2023

Abstract

A housing of a separation apparatus includes therein a zeolite membrane complex. A sheath includes therein the housing. A fluid supplied to the inside of the housing has a temperature higher than the temperature around the sheath. A second exhaust port is used to exhaust a permeated substance that has permeated through the zeolite membrane complex in the fluid to the outside of the housing. The permeated substance exhausted from the housing can be led into an exterior space between the sheath and the housing through the second exhaust port and can be exhausted through an exterior exhaust port. At least part of the zeolite membrane complex is included in an inter-port space surrounded by the sheath, the second exhaust port, and the exterior exhaust port. This structure reduces energy required for fluid separation performed under high temperatures.

First claim

The invention claimed is:

1. A separation apparatus comprising:
a separation membrane complex including a porous support and a separation membrane formed on said support;
a housing including therein said separation membrane complex;
a sheath including therein said housing; and
a supply part that supplies a fluid having a temperature higher than a temperature around said sheath to an inside of said housing,
wherein said housing includes:
a first exhaust port through which a non-permeated substance in said fluid is exhausted to an outside of said housing, the non-permeated substance being a substance other than a permeated substance that has permeated through said separation membrane complex; and
a second exhaust port through which said permeated substance in said fluid is exhausted to the outside of said housing,
either of said permeated substance and said non-permeated substance exhausted from said housing can be led into an exterior space through either of said second exhaust port and said first exhaust port, respectively, serving as a lead-in port, the exterior space being a space inside said sheath and between said sheath and said housing,
said sheath includes an exterior exhaust port through which said either of said permeated substance and said non-permeated substance, led into said exterior space through said lead-in port, is exhausted, and
at least part of said separation membrane complex is included in a space surrounded by said sheath, said lead-in port, and said exterior exhaust port.

2. The separation apparatus according to claim 1 , wherein
said exterior space exists at least in a direction of a normal to a main surface of said separation membrane.

3. The separation apparatus according to claim 1 , wherein
said housing includes:
a tube-shaped part having an opening at least at one end;
a flange part extending outward from said tube-shaped part around said opening; and
a lid part fixed to said flange part while covering said opening to seal said opening.

4. The separation apparatus according to claim 1 , wherein
50 percent or more of said separation membrane complex by volume is included in said space surrounded by said sheath, said lead-in port, and said exterior exhaust port.

5. The separation apparatus according to claim 1 , wherein
said either of said permeated substance and said non-permeated substance led into said exterior space is said permeated substance.

6. The separation apparatus according to claim 1 , further comprising:
a heating part that heats said fluid before said fluid is supplied to said housing.

7. The separation apparatus according to claim 1 , wherein
said fluid supplied from said supply part has a temperature higher than or equal to 70° C.

8. The separation apparatus according to claim 1 , further comprising:
a thermal insulation part arranged around said sheath to thermally insulate at least part of an outer surface of said sheath.

9. The separation apparatus according to claim 1 , wherein
said separation membrane is a zeolite membrane.

10. The separation apparatus according to claim 9 , wherein
a maximum number of membered rings in a zeolite constituting said zeolite membrane is 8 or less.

11. The separation apparatus according to claim 9 , wherein
said fluid contains one or more types of substances among hydrogen, helium, nitrogen, oxygen, water, steam, carbon monoxides, carbon dioxides, nitrogen oxides, ammonia, sulfur oxides, hydrogen sulfides, sulfur fluorides, mercury, arsine, hydrocyanic acids, carbonyl sulfides, C1 to C8 hydrocarbons, organic acids, alcohol, mercaptans, ester, ether, ketone, and aldehyde.

12. A method of operating the separation apparatus according to claim 1 , the method comprising:
a) supplying said fluid having a higher temperature than a temperature around said sheath to an inside of said housing;
b) leading either of said permeated substance in said fluid and said non-permeated substance in said fluid into said exterior space through either of said second exhaust port and said first exhaust port, respectively, serving as a lead-in port; and
c) exhausting said either of said permeated substance and said non-permeated substance from said exterior space, the exhausting substance passing through at least part of said exterior space, the exterior space existing in a direction of a normal to a main surface of said separation membrane.

Assignees

• Ngk Insulators Ltd

Inventors

• Noda Kenichi

Classifications

• B01D69/1213

  Laminated layers · CPC title

• B01D69/108

  Inorganic support material · CPC title

• B01D2313/221

  Heat exchangers · CPC title

• B01D71/0281 Primary

  Zeolites · CPC title

• B01D65/003

  Membrane bonding or sealing · CPC title