Asbestos waste destruction and valorization method

Patent metadata

Field	Value
Publication number	US-11577112-B2
Application number	US-201816640126-A
Country	US
Kind code	B2
Filing date	Aug 21, 2018
Priority date	Aug 24, 2017
Publication date	Feb 14, 2023
Grant date	Feb 14, 2023

Abstract

A method for destructing and valorizing an asbestos waste including the steps of: determining the asbestos mineralogical group contained in the waste, performing a treatment on the waste which includes of: an acid treatment when the waste comprises only a chrysotile, a base treatment when the waste comprises only an amphibole, the acid treatment followed by the base treatment when the asbestos waste includes a mixture of a chrysotile and an amphibole, and valorizing at least one of the products obtained on completion of the performing of the treatment. An embodiment also concerns a treatment of a chrysotile waste through an acid treatment followed by a thermal treatment.

First claim

The invention claimed is:

1. A method for destructing and valorizing an asbestos waste, comprising:
a) determining asbestos mineralogical group(s) contained in said waste, said group comprising a chrysotile and an amphibole,
b) performing at least one treatment on said asbestos waste, said treatment being:
an acid treatment when the asbestos waste comprises only a chrysotile, said acid treatment comprising in the immersion of the asbestos waste in a strong acid solution, at a temperature of at most 100° C., so as to obtain an acid solution and a solid comprising a mesoporous silica,
a base treatment when the asbestos waste comprises only an amphibole, said base treatment consisting in the immersion of the asbestos waste in a solution of a strong base in a hermetically sealed medium so as to obtain a base solution containing dissolved silica,
said acid treatment followed by said base treatment when the asbestos waste comprises a mixture of a chrysotile and an amphibole, so as to obtain after said acid treatment an acid solution and a solid mixture containing a mesoporous silica and the unaltered amphibole, said solid mixture being separated from the acid solution to be subjected to said base treatment so as to obtain a base solution containing dissolved silica, and
c) valorizing at least one of the products obtained on completion of step b) of the treatment.

2. The destruction and valorization method according to claim 1 , wherein the asbestos waste is an asbestos cement waste or a gypsum-based asbestos flocking.

3. The destruction and valorization method according to claim 1 , wherein the acid treatment when the asbestos waste comprises only a chrysotile is followed by a thermal treatment comprising a heating of the mesoporous silica at a temperature of at least 600° C.

4. The destruction and valorization method according to claim 1 , wherein when an acid treatment has been performed, step c) comprises using the mesoporous silica for the entrapment or the filtering of molecules and/or as a silicon precursor for the synthesis of a zeolite.

5. The destruction and valorization method according to claim 4 , wherein when the acid solution is a nitric acid solution, the mesoporous silica is used to synthesize a nitrate-cancrinite type zeolite of formula Na8[Al6Si6O24](NO3)2-4H2O.

6. The destruction and valorization method according to claim 1 , wherein when an acid treatment has been performed, step c) comprises selectively extracting or isolating ions present in the acid solution obtained on completion of the acid treatment.

7. The destruction and valorization method according to claim 1 , wherein when a base treatment has been performed, step c) comprises in using the base solution obtained on completion of the base treatment for the production of a hydrated calcium silicate type material and/or for the synthesis of a zeolite.

8. The destruction and valorization method according to claim 1 , wherein the acid solution contains at least one strong monoacid selected from nitric acid and hydrochloric acid.

9. The destruction and valorization method according to claim 1 , wherein the strong base of the base solution is selected from soda and potash.

Assignees

• Univ Montpellier
• Centre Nat Rech Scient
• Enscm—Ecole Nat Superieure De Chimie

Inventors

• Talbi Gaël
• Cambon Olivier
• Cambon Martine

Classifications

• B09B2101/35

  Asbestos · CPC title

• B09B3/70 Primary

  Chemical treatment, e.g. pH adjustment or oxidation (involving an extraction step B09B3/80) · CPC title

• C01B39/50

  Zeolites wherein inorganic bases or salts occlude channels in the lattice framework, e.g. sodalite, cancrinite, nosean, hauynite {(ultramarine C09C1/32)} · CPC title

• C01B33/24

  Alkaline-earth metal silicates · CPC title

• A62D2101/41

  Inorganic fibres, e.g. asbestos · CPC title