Sulfide solid electrolyte and method of producing the same
US-2018269527-A1 · Sep 20, 2018 · US
US11575154B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11575154-B2 |
| Application number | US-202117320964-A |
| Country | US |
| Kind code | B2 |
| Filing date | May 14, 2021 |
| Priority date | Dec 27, 2017 |
| Publication date | Feb 7, 2023 |
| Grant date | Feb 7, 2023 |
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The present invention relates to a nitrogen-doped sulfide-based solid electrolyte for all-solid batteries. The a nitrogen-doped sulfide-based solid electrolyte for all-solid batteries includes a compound with an argyrodite-type crystal structure represented by the following Formula 1:LiaPSbNcXd [Formula 1]wherein 6≤a≤7, 3≤b≤6, 0≤c≤1, 0≤d≤2, andeach X is the same or different halogen atom selected from the group consisting of chlorine (Cl), bromine (Br), and iodine (I).
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What is claimed is: 1. A solid electrolyte for all-solid batteries comprising: a compound represented by the following Formula 5: Li 6 PS 5−2d N d X 1+d [Formula 5] wherein in Formula 5, 0<d≤1; and each X is the same or different halogen atom selected from the group consisting of chlorine (Cl), bromine (Br), and iodine (I), wherein the compound has an argyrodite-type crystal structure. 2. An all-solid battery comprising: a cathode; an anode; and a solid electrolyte layer interposed between the cathode and the anode, wherein at least one of the cathode, the anode and the solid electrolyte layer comprises the solid electrolyte of claim 1 . 3. A method of manufacturing a solid electrolyte for all-solid batteries comprising: providing a mixture of Li 2 S, P 2 S 5 , LiX, and Li 3 N; grinding the mixture; and heat treating the mixture to obtain a compound having an argyrodite-type crystal structure, wherein each X is the same or different halogen atom selected from the group consisting of chlorine (CI), bromine (Br), and iodine (I), wherein the compound is represented by the following Formula 5: Li 6 PS 5−2d N d X 1+d [Formula 5] wherein in Formula 5, 0<d≤1; and each X is the same or different halogen atom selected from the group consisting of chlorine (Cl), bromine (Br), and iodine (I). 4. A vehicle comprising an all-solid battery of claim 2 .
Manufacturing or production processes characterised by the final manufactured product · CPC title
Lithium compounds · CPC title
Solid materials · CPC title
Sulfides, tellurides or selenides · CPC title
Nitrides, e.g. oxynitrides, carbonitrides, oxycarbonitrides, lithium nitride, magnesium nitride · CPC title
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