Method and apparatus for pyrolyzing an electrode

Patent metadata

Field	Value
Publication number	US-11575115-B2
Application number	US-201916511438-A
Country	US
Kind code	B2
Filing date	Jul 15, 2019
Priority date	Jul 15, 2019
Publication date	Feb 7, 2023
Grant date	Feb 7, 2023

Abstract

An electrode heat treatment device and associated method for fabricating an electrode are described, and include forming a workpiece, including coating a current collector with a slurry. The workpiece is placed on a first spool, and the first spool including the workpiece is placed in a sealable chamber, wherein the sealable chamber includes the first spool, a heat exchange work space, and a second spool. An inert environment is created in the sealable chamber. The workpiece is subjected to a multi-step continuous heat treatment operation in the inert environment, wherein the multi-step continuous heat treatment operation includes continuously transferring the workpiece through the heat exchange work space between the first spool and the second spool and controlling the heat exchange work space to an elevated temperature.

First claim

What is claimed is:

1. A method for fabricating an electrode, comprising:
forming a workpiece, including coating a current collector with a slurry;
placing the workpiece on a first spool;
placing the first spool including the workpiece in a sealable chamber, wherein the sealable chamber includes the first spool, a heat exchange work space, and a second spool;
creating an inert environment in the sealable chamber; and
subjecting the workpiece to a multi-step continuous heat treatment operation in the inert environment;
wherein the multi-step continuous heat treatment operation includes continuously transferring the workpiece through the heat exchange work space between the first spool and the second spool and controlling the heat exchange work space to an elevated temperature;
wherein continuously transferring the workpiece through the heat exchange work space between the first spool and the second spool and controlling the heat exchange work space to an elevated temperature comprises:
continuously transferring the workpiece through the heat exchange work space from the first spool to the second spool and controlling the heat exchange work space to a first elevated temperature for a first period of time; and then
continuously transferring the workpiece through the heat exchange work space from the second spool to the first spool and controlling the heat exchange work space to a second elevated temperature for a second period of time;
wherein the second elevated temperature is greater than the first elevated temperature.

2. The method of claim 1 , wherein the slurry includes silicon particles, a polymeric binder, and carbon fibers.

3. The method of claim 1 , wherein the first elevated temperature and the first period of time are associated with a time-temperature relation to effect a chemical reaction in the workpiece.

4. The method of claim 3 , wherein the time-temperature relation to effect the chemical reaction in the workpiece comprises a first temperature range between 180° C. and 400° C. for a period of time between 15 to 180 minutes when the coating includes a polymeric binder fabricated from polyacrylonitrile.

5. The method of claim 1 , wherein the second elevated temperature and the second period of time are associated with a time-temperature relation to effect carbonization of the workpiece.

6. The method of claim 1 , wherein the time-temperature relation to effect carbonization of the workpiece comprises a second temperature range from 450° C. to 750° C. for at least 30 minutes when the coating includes a polymeric binder fabricated from polyacrylonitrile.

7. The method of claim 1 , wherein the first elevated temperature and the first period of time are associated with a time-temperature relation to effect a chemical reaction in of the workpiece, and wherein the second elevated temperature and the second period of time are associated with a time-temperature relation to effect carbonization of the workpiece.

8. The method of claim 1 , wherein the workpiece is arranged as a sheet.

9. The method of claim 1 , further comprising dividing the workpiece into a plurality of electrode elements subsequent to subjecting the workpiece to the multi-step continuous heat treatment operation in the inert environment.

10. The method of claim 1 , further comprising subjecting the workpiece to a drying process prior to subjecting the workpiece to the multi-step continuous heat treatment operation in the inert environment.

11. The method of claim 10 , wherein the drying process includes subjecting the workpiece to a temperature environment in a range between 60° C. and 150° C.

12. The method of claim 1 , wherein creating the inert environment in the sealable chamber comprises initially evacuating the sealable chamber, and then flowing pressurized nitrogen gas into the sealable chamber while subjecting the workpiece to the multi-step continuous heat treatment operation in the inert environment.

13. An electrode heat treatment device, comprising:
first and second spool housings;
a heat exchange work space interposed between the first and second spool housings, wherein the heat exchange work space and the first and second first spool housings form a sealable chamber;
a furnace arranged to encompass the heat exchange work space to transfer heat thereto; and a controller, the controller being operatively connected to the first and second spool housings and the furnace;
the first spool housing being fluidly coupled to a vacuum pump and a container containing pressurized inert gas; and
the second spool housing being fluidly coupled to an atmospheric outlet;
wherein the first spool housing includes a first spool;
wherein the second spool housing includes a second spool; and
wherein the controller has an executable program that when executed performs a multi-step continuous heat treatment operation to act on a workpiece formed by coating a current collector with a slurry in an inert environment, the multi-step continuous heat treatment operation including:
placing the workpiece on the first spool;
placing the first spool including the workpiece in the sealable chamber, wherein the sealable chamber includes the first spool, the heat exchange work space, and the second spool;
creating an inert environment in the sealable chamber; and
continuously transferring the workpiece through the heat exchange work space between the first spool and the second spool and controlling the heat exchange work space to an elevated temperature;

wherein continuously transferring the workpiece through the heat exchange work space between the first spool and the second spool and controlling the heat exchange work space to an elevated temperature comprises:
continuously transferring the workpiece through the heat exchange work space from the first spool to the second spool and controlling the heat exchange work space to a first elevated temperature for a first period of time; and then
continuously transferring the workpiece through the heat exchange work space from the second spool to the first spool and controlling the heat exchange work space to a second elevated temperature for a second period of time;
wherein the second elevated temperature is greater than the first elevated temperature.

14. The electrode heat treatment device of claim 13 , wherein continuously transferring the workpiece through the heat exchange work space between the first spool and the second spool and controlling the heat exchange work space to an elevated temperature comprises:
continuously transferring the workpiece through the heat exchange work space from the first spool to the second spool and controlling the heat exchange work space to a first elevated temperature for a first period of time; and then
continuously transferring the workpiece through the heat exchange work space from the second spool to the first spool and controlling the heat exchange work space to a second elevated temperature for a second period of time;
wherein the second elevated temperature is greater than the first elevated temperature.

15. The electrode heat treatment device of claim 13 , wherein the furnace arranged to encompass the heat exchange work space to transfer heat thereto comprises a first portion operating at the first elevated temperature, and a second portion operating at the second elevated temperature, and
wherein continuously transferring the workpiece through the heat exchange work space between the first spool and the second spool and controlling the heat exchange work space to the elevated temperature comprises:
continuously transferring the workpiece thr

Assignees

• Gm Global Tech Operations Llc

Inventors

• Halalay Ion C
• Rober Kevin B
• Jimenez Niccolo
• Balogh Michael P
• Holiness-Stalling Teresa U
• K Raghunathan

Classifications

• H01M4/0471 Primary

  involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis · CPC title

• H01M4/0404 Primary

  by coating on electrode collectors · CPC title

• C04B2235/606

  Drying · CPC title

• H01M4/1393

  of electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title