Gas sensor comprising composite structure including graphene and metal particle bonded to each other and method for manufacturing same

Patent metadata

Field	Value
Publication number	US-11573196-B2
Application number	US-201816764068-A
Country	US
Kind code	B2
Filing date	Apr 19, 2018
Priority date	Nov 15, 2017
Publication date	Feb 7, 2023
Grant date	Feb 7, 2023

Abstract

Disclosed is a gas sensor. The gas sensor comprises: a substrate; a thermoelectric layer which is disposed on the substrate and has a metal nanowire; a first electrode and a second electrode disposed to be spaced apart from each other on the thermoelectric layer; and a catalyst layer which is disposed on the first electrode and has a composite structure in which a metal particle is bonded to a carbon structure.

First claim

The invention claimed is:

1. A gas sensor comprising:
a substrate;
a thermoelectric layer disposed on the substrate and including a metal nanowire, wherein the metal nanowire included in the thermoelectric layer has a concentration greater than 60 wt % and less than 85 wt %;
a first electrode and a second electrode spaced apart from each other on the thermoelectric layer; and
a catalyst layer disposed on the first electrode and having a composite structure in which a metal particle is bonded to a carbon structure.

2. The gas sensor of claim 1 , wherein
the catalyst layer reacts with a target gas, in which heat is generated in the catalyst layer after the catalyst layer reacts with the target gas;
the generated heat causes a temperature difference between a first area of the thermoelectric layer in which the first electrode is disposed and a second area of the thermoelectric layer in which the second electrode is disposed; and
the temperature difference between the first and second areas causes a potential difference between the first area and the second area.

3. The gas sensor of claim 1 , wherein the metal nanowire includes at least one of a tellurium nanowire, a Bi x Te y nanowire, a Bi x Se y nanowire, an Sb x Te y nanowire, and a PbTe 1-x Se x nanowire (x>0, y>0).

4. The gas sensor of claim 1 , wherein a ratio by weight (wt %) between the carbon structure and the metal particle in the catalyst layer is 1:1.

5. The gas sensor of claim 4 , wherein the carbon structure includes graphene and the metal particle includes a platinum particle.

6. The gas sensor of claim 1 , wherein the carbon structure and the metal particle form a covalent bond to each other.

7. The gas sensor of claim 1 , wherein the first electrode and the second electrode are positioned at a same level based on a top surface of the substrate.

8. A method for manufacturing a gas sensor, the method comprising:
preparing a substrate;
forming a thermoelectric layer including metal nanowires on the substrate, wherein forming the thermoelectric layer includes heat-treating the thermoelectric layer at a temperature of 300° C. for more than 50 minutes and less than 70 minutes;
forming a first electrode and a second electrode spaced apart from each other on the thermoelectric layer; and
forming a catalyst layer having a composite structure, in which a metal particle is bonded to a carbon structure, on the first electrode.

9. The method of claim 8 , wherein the forming of the thermoelectric layer includes:
preparing the metal nanowires;
preparing metal paste by mixing the metal nanowires with a polymer-containing binder and a solvent;
forming the thermoelectric layer by providing the metal paste onto the substrate; and
heat-treating the thermoelectric layer.

10. The method of claim 9 , wherein at least some of the metal nanowires in the thermoelectric layer are melted or vaporized due to the heat treating, so that the metal nanowires are networked.

11. The method of claim 8 , wherein the forming of the catalyst layer includes:
preparing a mixed solution containing the carbon structure;
oxidizing the carbon structure in the mixed solution;
providing a metal precursor to the oxidized carbon structure;
preparing the composite structure in which the metal particle is bonded to the carbon structure, by reducing the carbon structure provided with the metal precursor; and
providing the composite structure onto the first electrode.

12. A method for manufacturing a gas sensor, the method comprising:
preparing a substrate;
forming a thermoelectric layer including metal nanowires on the substrate, wherein the thermoelectric layer is formed by providing a metal paste onto the substrate, wherein the metal paste is prepared by mixing the metal nanowires with a polymer-containing binder and a solvent, and wherein the binder includes PVP and the solvent includes at least one of DEG and DEGBE;
forming a first electrode and a second electrode spaced apart from each other on the thermoelectric layer; and
forming a catalyst layer having a composite structure, in which a metal particle is bonded to a carbon structure, on the first electrode.

Assignees

• Iucf Hyu Erica Campus

Inventors

• Choa Yong Ho
• Hwang Tae-Yeon
• Song Yo Seb
• Kim Se Il
• Go Gwang Myeong

Classifications

• G01N27/12

  of a solid body in dependence upon absorption of a fluid; of a solid body in dependence upon reaction with a fluid {, for detecting components in the fluid} · CPC title

• G01N27/4075 Primary

  Composition or fabrication of the electrodes and coatings thereon, e.g. catalysts · CPC title

• G01N27/127 Primary

  comprising nanoparticles · CPC title

• G01N33/005 Primary

  H2 · CPC title

• G01N25/32

  using thermoelectric elements · CPC title