Hybrid electrochemical cell

Patent metadata

Field	Value
Publication number	US-11569538-B2
Application number	US-202017080352-A
Country	US
Kind code	B2
Filing date	Oct 26, 2020
Priority date	Jun 16, 2014
Publication date	Jan 31, 2023
Grant date	Jan 31, 2023

Abstract

Disclosed is a hybrid electrochemical cell with a first conductor having at least one portion that is both a first capacitor electrode and a first battery electrode. The hybrid electrochemical cell further includes a second conductor having at least one portion that is a second capacitor electrode and at least one other portion that is a second battery electrode. An electrolyte is in contact with both the first conductor and the second conductor. In some embodiments, the hybrid electrochemical cell further includes a separator between the first conductor and the second conductor to prevent physical contact between the first conductor and the second conductor, while facilitating ion transport between the first conductor and the second conductor.

First claim

What is claimed is:

1. A hybrid electrochemical cell comprising:
(a) a first conductor having at least one portion that is both a first capacitor electrode and a first battery electrode;
(b) a second conductor having at least one portion that is a second capacitor electrode and at least one other portion that is a second battery electrode, wherein the second battery electrode comprises a metal oxide, wherein the second capacitor electrode comprises an interconnected corrugated carbon-based network (ICCN) having a three-dimensional (3D) structure, wherein the metal oxide is deposited throughout the 3D structure of the ICCN; and
(c) an electrolyte in contact with both the first conductor and the second conductor.

2. The hybrid electrochemical cell of claim 1 further comprising a separator between the first conductor and the second conductor that is configured in a manner to prevent or reduce physical contact between the first conductor and the second conductor and that facilitates ion transport between the first conductor and the second conductor.

3. The hybrid electrochemical cell of claim 1 wherein the hybrid electrochemical cell comprises lithium-ion material or chemistry.

4. The hybrid electrochemical cell of claim 3 wherein the first conductor is negative and is embedded with lithium ions.

5. The hybrid electrochemical cell of claim 3 wherein the first conductor comprises a graphite negative electrode.

6. The hybrid electrochemical cell of claim 3 wherein the first battery electrode comprises hard carbon, silicon alloy, or composite alloy.

7. The hybrid electrochemical cell of claim 1 wherein the metal oxide comprises lithium cobalt oxide, lithium manganese oxide, lithium nickel oxide, lithium nickel manganese cobalt oxide, lithium nickel cobalt aluminum oxide, or lithium titanium oxide.

8. The hybrid electrochemical cell of claim 1 wherein the second capacitor electrode and the second battery electrode are connected internally in parallel on one cell.

9. The hybrid electrochemical cell of claim 8 wherein the second capacitor electrode provides buffering to prevent or reduce high rate charge and discharge of the hybrid electrochemical cell.

10. The hybrid electrochemical cell of claim 3 wherein the second capacitor electrode comprises an electric double layer capacitor electrode in which charge is stored in double layers.

11. The hybrid electrochemical cell of claim 1 wherein the second capacitor electrode comprising the interconnected corrugated carbon-based network comprises a plurality of expanded and interconnected carbon layers that include a corrugated carbon layer.

12. The hybrid electrochemical cell of claim 11 wherein each expanded and interconnected carbon layer comprises at least one corrugated carbon sheet that is one atom thick.

13. The hybrid electrochemical cell of claim 11 wherein each expanded and interconnected carbon layer comprises a plurality of corrugated carbon sheets.

14. A hybrid electrochemical cell comprising:
(a) a first conductor having at least one portion that is both a first capacitor electrode and a first battery electrode;
(b) a second conductor having at least one portion that is a second capacitor electrode and at least one other portion that is a second battery electrode, wherein the second battery electrode comprises a metal, wherein the second capacitor electrode comprises an interconnected corrugated carbon-based network (ICCN) having a three-dimensional (3D) structure, wherein the metal is deposited throughout the 3D structure of the ICCN; and
(c) an electrolyte in contact with both the first conductor and the second conductor.

15. The hybrid electrochemical cell of claim 14 , wherein the hybrid electrochemical cell comprises nickel-cadmium (Ni—Cd) and/or nickel-metal hydride (Ni—MH) chemistries.

16. The hybrid electrochemical cell of claim 14 , wherein the first conductor is positive and comprises nickel oxyhydroxide (NiOOH).

17. The hybrid electrochemical cell of claim 14 wherein the second capacitor electrode comprising the interconnected corrugated carbon-based network comprises a plurality of expanded and interconnected carbon layers that include a corrugated carbon layer.

18. The hybrid electrochemical cell of claim 17 wherein each expanded and interconnected carbon layer comprises at least one corrugated carbon sheet that is one atom thick.

19. The hybrid electrochemical cell of claim 17 wherein each expanded and interconnected carbon layer comprises a plurality of corrugated carbon sheets.

20. The hybrid electrochemical cell of claim 14 , wherein the metal comprises lanthanum nickel or palladium.

Assignees

• Univ California

Inventors

• El-Kady Maher F
• Kaner Richard B

Classifications

• H01G11/52

  Separators · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01G11/46

  Metal oxides · CPC title

• H01G11/06 Primary

  with one of the electrodes allowing ions to be reversibly doped thereinto, e.g. lithium ion capacitors [LIC] · CPC title

• H01M4/13

  Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof · CPC title