Ternary positive electrode material with low gas generation and high capacity

Patent metadata

Field	Value
Publication number	US-11569510-B2
Application number	US-202117518744-A
Country	US
Kind code	B2
Filing date	Nov 4, 2021
Priority date	Jun 28, 2019
Publication date	Jan 31, 2023
Grant date	Jan 31, 2023

Abstract

This disclosure relates to the field of electrochemistry, and in particular, to a positive electrode material. The positive electrode material of this disclosure includes a substrate, with a formula of the substrate being Li x Ni y Co z M k Me p O r A m , where 0.95≤x≤1.05, 0.50≤y≤0.95, 0≤z≤0.2, 0≤k≤0.4, 0≤p≤0.05, 1≤r≤2, 0≤m≤2, m+r≤2; a coating layer is disposed on the subs hate, where the coating layer includes a coating element; and absorbance of nickel leachate per unit mass of the positive electrode material w≤0.7.

First claim

What is claimed is:

1. A positive electrode material, comprising a substrate,
wherein a molecular formula of the substrate is Li x Ni y Co z M k Me p O r A m ,
where 0.95≤x≤1.05, 0.70≤y≤0.90, 0.05≤z≤0.15, 0.05≤k≤0.2, 0≤p≤0.05, 1≤r≤2, 0≤m≤2, m+r≤2,
M is selected from Mn and/or Al, Me is selected from one or more of Zr, Zn, Cu, Cr, Mg, Fe, V, Ti, Sr, Sb, Y, W, and Nb, and A is selected from one or more of N, F, S, and Cl;
wherein a coating layer is disposed on the substrate, the coating layer comprises a coating element that is selected from one or more of Al, Zr, Ba, Zn, Ti, Co, W, Y, Si, Sn, B, and P;
wherein absorbance of nickel leachate per unit mass of the positive electrode material w≤0.7;
wherein a theoretical specific surface area BET 1 of the positive electrode material and an actual specific surface area BET 2 of the positive electrode material satisfies the following condition:
0.3≤(BET 2 −BET 1 )/BET 1 ≤5.5;

wherein, BET 1 =6/(ρ×D v 50);
ρ is actual density of the positive electrode material, measured in g/cm 3 ; and
D v50 is a particle size of the positive electrode material under a cumulative volume distribution percentage reaching 50%, measured in μm;
a coating element content per unit volume Mv in the positive electrode material is 0.4 mg/cm 3 to 15 mg/cm 3 ; and
in residual lithium on a surface of the positive electrode material, Li 2 CO 3 is less than 3000 ppm, and LiOH is less than 5000 ppm.

2. The positive electrode material according to claim 1 , wherein when the substrate comprises secondary particles composed of primary particles, the actual specific surface area BET 2 of the positive electrode material is 0.1 m 2 /g to 1.0 m 2 /g, and D v 50 is 5 μm to 18 μm.

3. The positive electrode material according to claim 1 , wherein the substrate comprises single crystal or single-crystal-like particles, the actual specific surface area BET 2 of the positive electrode material is 0.5 m 2 /g to 1.5 m 2 /g, and D v 50 is 1 μm to 6 μm.

4. The positive electrode material according to claim 1 , wherein the coating element content per unit volume My in the positive electrode material is 0.8 mg/cm 3 to 10 mg/cm 3 .

5. The positive electrode material according to claim 1 , wherein the coating layer comprises an inner coating layer, the inner coating layer is located on surfaces of at least some primary particles inside the substrate, and the inner coating layer comprises a coating element, wherein the coating element of the inner coating layer is selected from one or more of Al, Zr, Ba, Zn, Ti, Co, W, Y, Si, Sn, B, and P.

6. The positive electrode material according to claim 1 , wherein the coating layer comprises an outer coating layer, the outer coating layer is located on a surface of the substrate, and the outer coating layer comprises a coating element, wherein the coating element of the outer coating layer is selected from one or more of Al, Zr, Ba, Zn, Ti, Co, W, Y, Si, Sn, B, and P.

7. The positive electrode material according to claim 6 , wherein the outer coating layer comprises a continuous and/or discontinuous coating layer.

8. The positive electrode material according to claim 6 , wherein the outer coating layer comprises a continuous first coating layer and a discontinuous second coating layer.

9. The positive electrode material according to claim 8 , wherein the second coating layer and the first coating layer comprise different coating elements.

10. The positive electrode material according to claim 1 , wherein in the molecular formula of the substrate, 0≤p≤0.03.

11. The positive electrode material according to claim 1 , wherein in the residual lithium on the surface of the positive electrode material, Li 2 CO 3 content is less than LiOH content.

12. An electrochemical energy storage apparatus, comprising the positive electrode material according to claim 1 .

Assignees

• Contemporary Amperex Technology Co Ltd

Inventors

• Du Rui
• Wang Sihui
• Liu Yongchao
• Luo Chi
• Zhao Deyu
• Liu Na

Classifications

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title

• H01M4/525

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title

• H01M4/628 Primary

  Inhibitors, e.g. gassing inhibitors, corrosion inhibitors · CPC title

• H01M4/366 Primary

  as layered products · CPC title

• H01M2004/028

  Positive electrodes · CPC title