Polyurethane layer for a light directing article

Patent metadata

Field	Value
Publication number	US-11567239-B2
Application number	US-202017114821-A
Country	US
Kind code	B2
Filing date	Dec 8, 2020
Priority date	Jul 7, 2015
Publication date	Jan 31, 2023
Grant date	Jan 31, 2023

Abstract

The disclosed aliphatic thermoplastic polyurethane composition is well suited for use in thin, flexible light directing articles to impart flexibility, toughness, or protection to the light directing articles that contain optically active elements. The disclosed aliphatic thermoplastic polyurethanes have improved thermostability at higher temperatures. Specifically, the disclosed aliphatic thermoplastic polyurethanes have a cross-over temperature greater than 110° C. In one embodiment, the cross-over temperature is greater than 130° C. In one embodiment, the cross-over temperature is less than 170° C. and a Tg greater than 35° C. and less than 70° C.

First claim

What is claimed is:

1. A light directing article comprising:
a plurality of optically active elements; and
a body layer adjacent to the plurality of optically active elements;
wherein the body layer comprises an aliphatic thermoplastic polyurethane that has a cross-over temperature greater than 110° C. and less than 170° C. and a glass transition temperature (Tg) greater than 35° C. and less than 70° C., and
wherein the aliphatic thermoplastic polyurethane is the reaction product of a short chain polyol, a long chain polyol, multifunctional polyol and a diisocyanate.

2. The light directing article of claim 1 wherein the optically active elements comprise beads or microstructured elements, wherein the microstructured elements are either (i) the reaction product of a polymerizable resin or (ii) solidified thermoplastic resin.

3. The light directing article of claim 1 , wherein the microstructured elements are longitudinally extending prisms or cube-corner elements.

4. The light directing article of claim 1 , comprising an adhesion promoting surface treatment between the major surface and the body layer, adhesion promoting surface treatment selected from a prime layer, corona treatment, or a combination thereof.

5. The light directing article of claim 1 , wherein the aliphatic thermoplastic polyurethane has a light transmissibility of at least 70 percent of the intensity of the light incident.

6. The light directing article of claim 1 , wherein the aliphatic thermoplastic polyurethane is branched.

7. The light directing article of claim 1 , wherein the branched aliphatic thermoplastic polyurethane comprise a block structure comprising a hard segment covalently bonded to a soft segment.

8. The light directing article of claim 1 , wherein the branched aliphatic thermoplastic polyurethane has a hard segment content ranging from 50 percent to 75 percent by weight.

9. The light directing article of claim 1 , where in the long chain polyol has a molecular weight greater than 185 g/mol.

10. The light directing article claim 1 , wherein the long chain polyol is selected from the group consisting of: aliphatic polyester polyols, polycaprolactone polyols, polycarbonate polyols, polyether polyols, polyolefin polyols, and copolymers and mixtures thereof.

11. The light directing article of claim 1 , where in the short chain polyol has a molecular weight less than 185 g/mol.

12. The light directing article of claim 1 , wherein the short chain polyol is selected from the group consisting of: butanediols, hexanediol, cyclohexane dimethanol, and copolymers and mixtures thereof.

13. The light directing article of claim 1 , wherein the multifunctional polyol is selected from the group consisting of: trifunctional glycerol, trimethylolpropane, 1,2,6-hexanetriol, 1,2,4-butanetriol, and triethanolamine, and copolymers and mixtures thereof.

14. The light directing article of claim 1 , wherein the diisocyanate is selected from the group consisting of: dicyclohexylmethane diisocyanate, isophorone diisocyanate, hexamethylene diisocyanate, trimethylhexamethylene diisocyanate, and copolymers and mixtures thereof.

15. The light directing article of claim 1 , wherein the aliphatic thermoplastic polyurethane has a Shore D hardness of at least 50 and less than 85, a weight average molecular weight ranging from 30,000 g/mol to 800,000 g/mol, a glass transition temperature that is greater than 35° C. and less than 70° C., and a cross-over temperature of at least 110° C.

Assignees

• 3M Innovative Properties Company

Inventors

• Thakkar Bimal V
• Jennen Jay M
• Hamann Robert D
• Braun Ryan M
• Watkins Robert F
• Rule Joseph D
• Jones Todd D
• Ho Charlie C

Classifications

• G02B5/12 Primary

  Reflex reflectors · CPC title

• C08J2375/06

  from polyesters · CPC title

• G02B26/0825

  the reflecting element being a flexible sheet or membrane, e.g. for varying the focus (flexible mirrors for cosmetic use A45D42/24) · CPC title

• G02B5/124

  plural reflecting elements forming part of a unitary plate or sheet · CPC title

• G02B1/14 Primary

  Protective coatings, e.g. hard coatings · CPC title