Corrosion resistance tester for coated metal material

Patent metadata

Field	Value
Publication number	US-11566996-B2
Application number	US-201916729851-A
Country	US
Kind code	B2
Filing date	Dec 30, 2019
Priority date	Jan 18, 2019
Publication date	Jan 31, 2023
Grant date	Jan 31, 2023

Abstract

A corrosion resistance tester for a coated metal material including a surface treatment film on a metal substrate includes: a container placed on the surface treatment film, and having a bottom surface in contact with the surface treatment film, the container including a plurality of water-containing electrolyte material holders that open through the bottom surface; the water-containing electrolyte material contained in each of the water-containing electrolyte material holders of the container, and being in contact with an associated one of a plurality of separate measurement target portions of the surface treatment film; a plurality of electrodes being each in contact with the water-containing electrolyte material contained in an associated one of the water-containing electrolyte material holders; an external circuit connecting the electrodes together; and a conduction means configured to conduct electricity to the metal substrate through the electrodes and the external circuit.

First claim

What is claimed is:

1. A corrosion resistance tester for a coated metal material including a surface treatment film on a metal substrate, the tester comprising:
a container placed on the surface treatment film, and having a bottom surface in contact with the surface treatment film, the container including a plurality of water-containing electrolyte material holders that open through the bottom surface;
the water-containing electrolyte material contained in each of the water-containing electrolyte material holders of the container, and being in contact with an associated one of a plurality of separate measurement target portions of the surface treatment film;
a plurality of electrodes being each in contact with the water-containing electrolyte material contained in an associated one of the water-containing electrolyte material holders;
an external circuit connecting the electrodes together; and
a galvanostat configured to conduct electricity to the metal substrate through the electrodes and the external circuit, wherein
the galvanostat conducts electricity to the metal substrate so that swelling of the surface treatment film progresses at at least one of the measurement target portions.

2. The corrosion resistance tester of claim 1 , wherein
the bottom surface of the container is flat, and each of the water-containing electrolyte material holders has an opening formed through the bottom surface, and is configured as a through-hole passing through the container in a direction perpendicular to the bottom surface.

3. The corrosion resistance tester of claim 2 , wherein
the metal substrate is a steel plate, and the container includes magnets near the bottom surface, the magnets being respectively disposed near the openings of the through-holes.

4. The corrosion resistance tester of claim 1 , further comprising:
a first heating element disposed on a periphery of the container to cover peripheries of the water-containing electrolyte material holders; and
a temperature controller connected to the first heating element to control a temperature of the first heating element.

5. The corrosion resistance tester of claim 4 , further comprising:
a second heating element disposed on a surface of the coated metal material remote from the container, wherein
the temperature controller controls the temperature of the first heating element and a temperature of the second heating element within a range from 30° C. to 100° C.

6. The corrosion resistance tester of claim 1 , wherein
the container includes:
a bottom portion made of silicone resin, the bottom portion forming the bottom surface of the container; and
a body made of an insulative resin material, the body extending in a direction away from the bottom surface of the bottom portion.

7. The corrosion resistance tester of claim 1 , wherein
each of the measurement target portions includes an artificial defect passing through the surface treatment film to reach the metal substrate, and
the galvanostat conducts electricity to the metal substrate, using at least one of the artificial defects and at least another one of the artificial defects as an anode site and a cathode site, respectively, so that, at the cathode site, the swelling of the surface treatment film progresses.

8. The corrosion resistance tester of claim 7 , wherein
a distance between the artificial defects is longer than or equal to 2 cm.

9. The corrosion resistance tester of claim 7 , wherein
the artificial defect serving as the cathode site has a size ranging from 0.1 mm to 5 mm.

10. The corrosion resistance tester of claim 1 , wherein
the galvanostat conducts electricity to the metal substrate at a current value from 10 μA to 10 mA.

11. The corrosion resistance tester of claim 1 , wherein
the water-containing electrolyte material is mud containing water, a supporting electrolyte, and a clay mineral.

12. The corrosion resistance tester of claim 11 , wherein
the clay mineral is a layered silicate mineral or zeolite.

13. The corrosion resistance tester of claim 1 , wherein
the surface treatment film is a resin coat.

14. A method of testing a corrosion resistance of a coated metal material including a surface treatment film on a metal substrate, the method comprising:
placing a container on the surface treatment film, the container having a bottom surface in contact with the surface treatment film, the container including a plurality of water-containing electrolyte material holders that open through the bottom surface;
making each of the water-containing electrolyte material holders of the container contain the water-containing electrolyte material to bring the water-containing electrolyte material into contact with a plurality of separate measurement target portions of the surface treatment film;
bringing a plurality of electrodes into contact with the water-containing electrolyte material contained in an associated one of the water-containing electrolyte material holders; and
energizing the metal substrate through the electrodes and an external circuit connecting the electrodes together, wherein
energizing the metal substrate is performed so that swelling of the surface treatment film progresses at at least one of the measurement target portions.

15. The method of claim 14 , wherein
each of the measurement target portions includes an artificial defect passing through the surface treatment film to reach the metal substrate, and
energizing the metal substrate is performed, using at least one of the artificial defects and at least another one of the artificial defects as an anode site and a cathode site, respectively so that, at the cathode site, the swelling of the surface treatment film progresses.

16. The method of claim 15 , wherein
a distance between the artificial defects is longer than or equal to 2 cm.

17. The method of claim 15 , wherein
the artificial defect serving as the cathode site has a size ranging from 0.1 mm to 5 mm.

18. The method of claim 14 , wherein
the water-containing electrolyte material is mud containing water, a supporting electrolyte, and a clay mineral.

19. The method of claim 18 , wherein
the clay mineral is a layered silicate mineral or zeolite.

20. The method of claim 14 , wherein
the surface treatment film is a resin coat.

Assignees

• Mazda Motor

Inventors

• Asada Teruaki
• Sasaki Katsunobu
• Shigenaga Tsutomu

Classifications

• G01N17/00

  Investigating resistance of materials to the weather, to corrosion, or to light · CPC title

• C23F13/02

  cathodic; Selection of conditions, parameters or procedures for cathodic protection, e.g. of electrical conditions · CPC title

• G01N17/02 Primary

  Electrochemical measuring systems for weathering, corrosion or corrosion-protection measurement · CPC title

• G01N17/04

  Corrosion probes · CPC title

• C23F13/04

  Controlling or regulating desired parameters · CPC title