Preparation method of coating material, coating material, catalyst and three-way catalytic converter

Patent metadata

Field	Value
Publication number	US-11566340-B2
Application number	US-202016833756-A
Country	US
Kind code	B2
Filing date	Mar 30, 2020
Priority date	Sep 30, 2019
Publication date	Jan 31, 2023
Grant date	Jan 31, 2023

Abstract

Provided is a preparation method of a coating material. The method includes: using an aluminum salt and a silicon source as precursors; and performing hydrothermal crystallization and calcination treatments successively under an action of a template agent to obtain the coating material, wherein the template agent is used to cause the coating material to form a porous spherical structure. In the embodiments of the present disclosure, the preparation process of the coating material is simple and the cost is low, and the specific surface area of the prepared coating material is large.

First claim

What is claimed is:

1. A preparation method of a coating material, comprising:
mixing an aluminum salt solution, a silicon source, and a template agent to obtain a silicon aluminum composite solution, wherein a pH of the silicon aluminum composite solution ranges from 1 to 3;
using an aluminum salt and the silicon source as precursors; and
performing hydrothermal crystallization and calcination treatments successively under an action of the template agent to obtain the coating material, wherein the hydrothermal crystallization treatment is performed in a hydrothermal reactor with a duration between 6 hours and 24 hours;
comprises polyvinyl alcohol and methyl cellulose, and is used to cause the coating material to form a porous spherical structure.

2. The method according to claim 1 , wherein the method comprises:
performing the hydrothermal crystallization treatment on the silicon aluminum composite solution to obtain a spherical solid product; and
performing the calcination treatment on the solid product to remove the template agent in the solid product, so as to obtain the porous spherical coating material.

3. The method according to claim 1 , further comprising:
adjusting the pH of the silicon aluminum composite solution and stirring the silicon aluminum composite solution.

4. The method according to claim 1 , wherein the silicon source is a liquid organic silicon source, and is mixed, in a dropwise manner, with a solution containing the template agent and the aluminum salt.

5. The method according to claim 4 , wherein the silicon source is at least one selected from a group consisting of tetraethyl orthosilicate, tetramethyl orthosilicate and tetraisopropyl orthosilicate.

6. The method according to claim 2 , wherein performing the hydrothermal crystallization treatment on the silicon aluminum composite solution to obtain the spherical solid product comprises:
performing the hydrothermal crystallization treatment on the silicon aluminum composite solution to obtain a solid-liquid mixture; and
performing suction filtration and washing treatments on the solid-liquid mixture to obtain the spherical solid product.

7. The method according to claim 1 , wherein the hydrothermal crystallization treatment is performed in the hydrothermal reactor under a temperature between 100° C. and 200° C.

8. The method according to claim 1 , wherein a mass ratio of the aluminum salt, the template agent and the silicon source is 1:0.2 to 3:1.5 to 20.

9. The method according to claim 1 , wherein a temperature of the calcination treatment is between 450° C. and 800° C., and a duration of the calcination treatment is between 4 hours and 10 hours.

10. The method according to claim 1 , wherein the method comprises:
dissolving polyvinyl alcohol into the aluminum salt solution and stirring until the polyvinyl alcohol is dissolved; and
adding methyl cellulose and stirring until the methyl cellulose is dissolved to obtain a solution containing the template agent and the aluminum salt.

11. The method according to claim 1 , wherein a mass ratio of the polyvinyl alcohol to the methyl cellulose is 0.1 to 2:1.

Assignees

• Boe Technology Group Co Ltd

Inventors

• Yao Hongbao

Classifications

• C30B33/02

  Heat treatment (C30B33/04, C30B33/06 take precedence) · CPC title

• C30B7/10 Primary

  by application of pressure, e.g. hydrothermal processes · CPC title

• C09D1/00

  Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances · CPC title

• C30B29/34

  Silicates · CPC title

• F01N3/2803

  characterised by structure, by material or by manufacturing of catalyst support · CPC title