Indigo-derivatives as irreversible color changeable dyes for textile materials and process for dyeing textile materials
US-2017362771-A1 · Dec 21, 2017 · US
US11566136B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11566136-B2 |
| Application number | US-202016984556-A |
| Country | US |
| Kind code | B2 |
| Filing date | Aug 4, 2020 |
| Priority date | Aug 5, 2019 |
| Publication date | Jan 31, 2023 |
| Grant date | Jan 31, 2023 |
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The present invention relates to novel 3-oxindole derivatives, to a process for their preparation and to the use of said derivatives as dyes for manufacturing pH sensitive textiles and as indicators in titration methods. The invention also relates to a method to manufacture pH sensitive textiles and to textiles so obtained.
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The invention claimed is: 1. A compound of formula (I) wherein R 1 , R 2 , R 3 and R 4 are, each independently, selected from a hydrogen atom, an alkyl group, an alkoxy group, a hydroxy group and a halogen atom, and salts and/or solvates thereof. 2. The compound according to claim 1 , wherein R 1 , R 2 , R 3 and R 4 are all a hydrogen atom. 3. A process for the preparation of a compound of formula (I) or a salt and/or solvate thereof, which comprises reacting a t-Boc-protected indigo of formula (II) wherein R 1 , R 2 , R 3 and R 4 are as defined in claim 1 , with sodium amide in an organic solvent, adding an acid to obtain an acidic pH, isolating the compounds of formula (I) and, optionally, converting it into one of its salts. 4. The process of claim 3 , wherein said solvent is an alcohol. 5. A compound selected from compounds (IIIA) and (IIIB) in the presence of a counter-ion, wherein R 1 , R 2 , R 3 and R 4 are defined as in claim 1 . 6. A method for dyeing textile materials which comprises applying one or more compounds of formula (I) according to claim 1 , onto a textile material. 7. The method of claim 6 , wherein said one or more compounds of formula (I) are solubilized in an aqueous solvent or solvent mixture. 8. The method of claim 7 , wherein the aqueous solvent or the solvent mixture is a water/alcohol mixture.
Other indole-indigos · CPC title
linked by a chain containing hetero atoms as chain links · CPC title
Indigo · CPC title
producing a change of colour · CPC title
Other synthetic dyes of known constitution · CPC title
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