Production method for prepreg, prepreg tape, and fiber reinforced composite material, and coating device

Patent metadata

Field	Value
Publication number	US-11566117-B2
Application number	US-201917266396-A
Country	US
Kind code	B2
Filing date	Aug 20, 2019
Priority date	Aug 22, 2018
Publication date	Jan 31, 2023
Grant date	Jan 31, 2023

Abstract

A method of producing a prepreg is described, in which a matrix resin is applied to a reinforcing fiber sheet in which the sheet can continuously run without clogging due to generated fuzz even at a high running speed and where the reinforcing fiber sheet can be efficiently impregnated with the matrix resin. A method of producing a prepreg includes allowing a reinforcing fiber sheet to pass substantially vertically downward through the inside of a coating section storing a matrix resin to apply the matrix resin to the reinforcing fiber sheet; and then applying a resin film to a primary impregnate prepreg withdrawn from the coating section.

First claim

The invention claimed is:

1. A method of producing a prepreg, comprising:
allowing a reinforcing fiber sheet to pass substantially vertically downward through the inside of a coating section storing a matrix resin to apply said matrix resin to said reinforcing fiber sheet; and then
applying a resin film to a primary impregnate prepreg withdrawn from said coating section;
wherein said coating section comprises a liquid pool and a narrowed section which are in communication with each other;
wherein said liquid pool has a portion whose cross-sectional area decreases continuously along a running direction of said reinforcing fiber sheet, and
wherein said narrowed section has a slit-like cross-section and a gap, wherein increased liquid pressure allows the reinforcing fiber sheet to be automatically aligned with the center of the gap, so that the reinforcing fiber sheet is not directly abraded against the wall surfaces of the narrowed section, and said slit-like cross-section has a smaller cross-sectional area than the top side of said liquid pool.

2. The method according to claim 1 , wherein said resin film comprises particles therein.

3. The method according to claim 1 , comprising a step of carrying out an additional-impregnation process after the step of applying said resin film.

4. The method according to claim 1 , comprising:
a step of carrying out an additional-impregnation process on said primary impregnate prepreg; and
a step of applying said resin film after said step of carrying out said additional-impregnation process.

5. The method according to claim 1 , comprising carrying out the resin film application and said additional-impregnation process simultaneously on said primary impregnate prepreg.

6. A method of producing a prepreg, comprising:
allowing a reinforcing fiber sheet to pass substantially vertically downward through the inside of a coating section storing a matrix resin;
applying said matrix resin to said reinforcing fiber sheet to obtain a primary impregnate prepreg; and
providing a surface thereof with particles having an average particle size of 0.1 μm or more and 500 μm or less by at least one method selected from the group consisting of the following [1] to [4]:
[1] a method of causing said particles to fall onto a running base material by their own weight,
[2] a method of causing a base material to pass through a space in which said particles are diffused,
[3] a method using electrostatic coating, and
[4] a method using a gas stream mixed with particles; wherein said coating section comprises a liquid pool and a narrowed section which are in communication with each other,
wherein said liquid pool has a portion whose cross-sectional area decreases continuously along a running direction of said reinforcing fiber sheet, and
wherein said narrowed section has a slit-like cross-section and a gap, wherein increased liquid pressure allows the reinforcing fiber sheet to be automatically aligned with the center of the gap, so that the reinforcing fiber sheet is not directly abraded against the wall surfaces of the narrowed section, and said slit-like cross-section has a smaller cross-sectional area than the top side of said liquid pool.

7. The method according to claim 1 , wherein a vertical height of the portion whose cross-sectional area decreases continuously in said liquid pool is 10 mm or more.

8. The method according to claim 1 , wherein a relationship between a width (L) of the lower portion of said liquid pool in the width direction of said reinforcing fiber sheet and the width (W) of said reinforcing fiber sheet immediately under said narrowed section satisfies the following Formula (1):
L≤W+ 10 (mm)  (1).

9. The method according to claim 1 , wherein said coating section comprises, in said liquid pool, a width regulation mechanism for regulating a width of said reinforcing fiber sheet, and wherein the relationship between the width (W) of said reinforcing fiber sheet immediately under said narrowed section and a width (L2) regulated by said width regulation mechanism at a lower end of said width regulation mechanism satisfies the following Formula (2):
L 2≤ W+ 10 (mm)  (2).

10. A method of producing a prepreg, comprising further carrying out an additional-impregnation process on said prepreg obtained by the method according to claim 4 .

11. A method of producing a prepreg tape, comprising:
obtaining a prepreg by the method according to claim 1 ; and then
slitting said prepreg.

12. A method of producing a fiber reinforced composite material, comprising:
obtaining a prepreg by the method according to claim 1 ; and
then molding said prepreg.

13. A method of producing a fiber reinforced composite material, comprising: obtaining a prepreg tape by the method according to claim 11 ; and then
molding said prepreg tape.

Assignees

• Toray Industries

Inventors

• Ochi Takashi
• Nishino So
• Aoki Junichi
• Kono Yoshikazu
• Suzuki Tamotsu
• IKUSHIMA Takashi

Classifications

• B29C70/20

  oriented in a single direction, e.g. roofing or other parallel fibres {(B29C70/083, B29C70/226 take precedence)} · CPC title

• B29C70/50

  for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC] · CPC title

• C08J7/06

  with compositions not containing macromolecular substances · CPC title

• B29B15/125 Primary

  by dipping · CPC title

• C08J5/24 Primary

  Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs · CPC title