Microstructured fiber interface coatings for composites

Patent metadata

Field	Value
Publication number	US-11565977-B2
Application number	US-201916678852-A
Country	US
Kind code	B2
Filing date	Nov 8, 2019
Priority date	Nov 8, 2019
Publication date	Jan 31, 2023
Grant date	Jan 31, 2023

Abstract

Disclosed is a coated ceramic fiber including a silicon carbide coating layer adjacent to the ceramic fiber and a silicon dioxide coating layer adjacent to the silicon carbide coating layer, wherein the silicon dioxide coating layer forms micro cracks after a crystal structure transformation. The coated ceramic fiber may be included in a composite material having a ceramic matrix.

First claim

What is claimed is:

1. A coated ceramic fiber comprising:
a silicon carbide coating layer adjacent to the ceramic fiber, a portion of the silicon carbide layer oxidized to form amorphous silicon dioxide, and
a silicon dioxide coating layer adjacent to the silicon carbide coating layer, the silicon dioxide coating layer including the amorphous silicon dioxide,
an additional coating layer adjacent to the silicon dioxide coating layer;
wherein the silicon dioxide coating layer forms micro cracks after a crystal structure transformation;
wherein the additional coating layer does not include silicon carbide; and
wherein the silicon dioxide coating layer includes silicon dioxide in β cristobalite form which forms micro cracks after transforming to α cristobalite form.

2. The coated ceramic fiber of claim 1 , wherein the silicon dioxide coating layer has a thickness of 50 nm to 10,000 nm.

3. The coated ceramic fiber of claim 1 , wherein the silicon carbide coating layer has a thickness of 1000 nm to 20,000 nm.

4. A composite material comprising:
a ceramic matrix material and a plurality of ceramic fibers embedded within the ceramic matrix material;
wherein the plurality of ceramic fibers comprise a multi-layer interface coating and the multi-layer interface coating comprises a silicon carbide coating layer adjacent to the plurality of ceramic fibers, a portion of the silicon carbide layer oxidized to form amorphous silicon dioxide, and
a silicon dioxide coating layer deposited onto the silicon carbide coating layer, the silicon dioxide coating layer including the amorphous silicon dioxide,
an additional coating layer adjacent to the silicon dioxide coating layer;
wherein the silicon dioxide coating layer forms micro cracks after a crystal structure transformation;
wherein the additional coating layer does not include silicon carbide; and
wherein the silicon dioxide coating layer includes silicon dioxide in β cristobalite form which forms micro cracks after transforming to α cristobalite form.

5. The composite material of claim 4 , wherein the silicon dioxide coating layer has a thickness of 50 nm to 10,000 nm.

6. The composite material of claim 4 , wherein the silicon carbide coating layer has a thickness of 1000 nm to 20,000 nm.

7. The coated ceramic fiber of claim 1 , wherein the additional coating layer comprises zirconium or zirconium boride or combinations thereof.

8. The composite material of claim 4 , wherein the additional coating layer comprises zirconium or zirconium boride or combinations thereof.

9. A method for forming a multi-layer interface coating onto a ceramic fiber comprising:
depositing a silicon carbide coating layer onto the fiber,
oxidizing a portion of the silicon carbide coating layer to form an amorphous silicon dioxide coating layer, and
depositing an additional coating layer on the silicon dioxide coating layer; and
crystallizing the amorphous silicon dioxide layer to beta cristobalite;
wherein the additional coating layer does not include silicon carbide; and
wherein the beta cristobalite forms micro cracks in the silicon dioxide coating layer after transforming to a cristobalite form.

Assignees

• United Technologies Corp
• Raytheon Tech Corp

Inventors

• Jackson Richard Wesley
• She Ying
• Srinivasan Gajawalli V

Classifications

• C04B35/62897

  Coatings characterised by their thickness · CPC title

• C04B35/62884

  by gas phase techniques · CPC title

• C04B2235/5232

  Silica or silicates other than aluminosilicates, e.g. quartz · CPC title

• C04B35/62863

  Silicon carbide · CPC title

• C23C16/325

  Silicon carbide · CPC title