Bitumen nanocomposites and uses thereof

Patent metadata

Field	Value
Publication number	US-11565972-B2
Application number	US-201716327839-A
Country	US
Kind code	B2
Filing date	Aug 25, 2017
Priority date	Aug 25, 2016
Publication date	Jan 31, 2023
Grant date	Jan 31, 2023

Abstract

Provided are bitumen nanocomposites. The bitumen nanocomposites have one or more clay, one or more polymer composition, and bitumen. A polymer composition can have one or more polymer and one or more crumb rubber. A polymer may have one or more maleic anhydride group. The bitumen nanocomposites can be used in, for example, road surfacing products and roofing products.

First claim

The invention claimed is:

1. A bitumen clay nanocomposite comprising:
0.5 to 5% by weight based on the total weight of the composition of a clay in the bitumen clay nanocomposite, wherein the clay comprises an organo-modified montmorillonite;
1 to 20% by weight based on the total weight of the composition of a polymer composition in the bitumen clay nanocomposite, wherein the polymer composition comprises 10 to 90% by weight of irregularly shaped crumb rubber having an average particle size of 100 microns to 1,000 microns and 10 to 90% by weight of one or more styrenic polymer and/or styrenic copolymer in the polymer composition; and
70 to 98.5% by weight based on the total weight of the composition of a bitumen in the bitumen clay nanocomposite,

wherein the bitumen clay nanocomposite exhibits no observable phase separation for at least 24 hours.

2. The bitumen clay nanocomposite of claim 1 , wherein the bitumen clay nanocomposite exhibits no observable phase separation for at least 48 hours.

3. The bitumen clay nanocomposite of claim 1 , wherein the bitumen clay nanocomposite exhibits no observable phase separation for at least 60 hours.

4. The bitumen clay nanocomposite of claim 1 , wherein the bitumen clay nanocomposite exhibits no observable phase separation for at least 5 days.

5. The bitumen clay nanocomposite of claim 1 , wherein the bitumen clay nanocomposite has a complex modulus greater than 450 Pa measured at 0.1 rad/sec at 60° C. or a complex modulus of 110,000 Pa or greater measured at 100 rad/sec at 60° C.

6. The bitumen clay nanocomposite of claim 1 , wherein the bitumen clay nanocomposite has a rutting factor of 20, 000 [G*/sin(delta)]/Pa or greater measured at 10 rad/sec at 60° C.

7. The bitumen clay nanocomposite of claim 1 , wherein the polymer composition is present at 1 to 5% by weight.

8. The bitumen clay nanocomposite of claim 1 , wherein the bitumen clay nanocomposite comprises 1 to 3% by weight of the polymer composition.

9. The bitumen clay nanocomposite of claim 1 , wherein the styrenic polymer comprises 10 to 50 percent by weight styrenic moieties.

10. The bitumen clay nanocomposite of claim 8 , wherein the styrenic polymer comprises one or more maleic anhydride group.

11. The bitumen clay nanocomposite of claim 1 , wherein the styrenic polymer is a styrenic block copolymer.

12. The bitumen clay nanocomposite of claim 11 , wherein the styrenic block copolymer comprises one or more polybutadiene block, one or more polyisoprene block, one or more polyethylene block, one or more polybutylene block, one or more polypropylene block, or a combination thereof.

13. The bitumen clay nanocomposite of claim 11 , wherein the styrenic block copolymer has one or more maleic anhydride group covalently bonded thereto.

14. The bitumen clay nanocomposite of claim 1 , wherein the bitumen clay nanocomposite comprises 1-3% by weight of the polymer composition.

15. The bitumen clay nanocomposite of claim 1 , wherein the one or more styrenic polymer and/or styrenic copolymer comprises styrene-butadiene-styrene triblock.

16. A road surfacing product comprising one or more bitumen clay nanocomposite of claim 1 ; and one or more mineral aggregates comprising sand, stone, or both.

17. The road surfacing product of claim 16 , wherein the road surfacing product is an asphalt.

18. A roofing product or waterproofing product comprising one or more bitumen clay nanocomposite claim 1 .

19. A bitumen clay nanocomposite consisting of:
0.5 to 5% by weight based on the total weight of the composition of a clay in the bitumen clay nanocomposite, wherein the clay comprises an organo-modified montmorillonite;
1 to 20% by weight based on the total weight of the composition of a polymer composition in the bitumen clay nanocomposite, wherein the polymer composition comprises 10 to 90% by weight of irregularly shaped crumb rubber having an average particle size of 100 microns to 1,000 microns and 10-90% by weight of one or more styrenic polymer and/or styrenic copolymer in the polymer composition; and
70 to 98.5% by weight based on the total weight of the composition of a bitumen in the bitumen clay nanocomposite,

wherein the bitumen clay nanocomposite exhibits no observable phase separation for at least 24 hours.

20. A bitumen clay nanocomposite consisting of:
0.5 to 5% by weight based on the total weight of the composition of a clay in the bitumen clay nanocomposite;
1 to 20% by weight based on the total weight of the composition of a polymer composition in the bitumen clay nanocomposite, wherein the polymer composition comprises 10 to 90% by weight of crumb rubber and 10 to 90% by weight of one or more styrenic polymer and/or styrenic copolymer in the polymer composition; and
70 to 98.5% by weight based on the total weight of the composition of a bitumen in the bitumen clay nanocomposite,

wherein the bitumen clay nanocomposite exhibits no observable phase separation for at least 24 hours.

Assignees

• Univ Cornell

Inventors

• Kosma Vasiliki
• Giannelis Emmanuel P

Classifications

• C04B2111/0075

  for road construction · CPC title

• C04B2111/27

  Water resistance, i.e. waterproof or water-repellent materials · CPC title

• C04B18/22

  Rubber {, e.g. ground waste tires} · CPC title

• C04B14/104

  Bentonite, e.g. montmorillonite · CPC title

• C08L53/02

  of vinyl-aromatic monomers and conjugated dienes · CPC title