Method of making a microporous material

Patent metadata

Field	Value
Publication number	US-11563256-B2
Application number	US-201715723639-A
Country	US
Kind code	B2
Filing date	Oct 3, 2017
Priority date	Dec 7, 2004
Publication date	Jan 24, 2023
Grant date	Jan 24, 2023

Abstract

A method for producing a microporous material comprising the steps of: providing an ultrahigh molecular weight polyethylene (UHMWPE); providing a filler; providing a processing plasticizer; adding the filler to the UHMWPE in a mixture being in the range of from about 1:9 to about 15:1 filler to UHMWPE by weight; adding the processing plasticizer to the mixture; extruding the mixture to form a sheet from the mixture; calendering the sheet; extracting the processing plasticizer from the sheet to produce a matrix comprising UHMWPE and the filler distributed throughout the matrix; stretching the microporous material in at least one direction to a stretch ratio of at least about 1.5 to produce a stretched microporous matrix; and subsequently calendering the stretched microporous matrix to produce a microporous material which exhibits improved physical and dimensional stability properties over the stretched microporous matrix.

First claim

What is claimed is:

1. A method for producing a battery with a battery separator, the battery separator is a microporous material, comprising the steps of:
making the battery separator by
mixing ultra high molecular weight polyethylene (UHMWPE), siliceous filler and processing plasticizer together to form a mixture, having a weight ratio of siliceous filler to UHMWPE of from 1:9 to 15:1 by weight; wherein the siliceous filler constitutes from about 5 percent to about 95 percent by weight of the microporous material and wherein the ratio of siliceous filler to processing plasticizer is 1:15 to 3:1 by weight;
extruding said mixture to form a sheet;
calendering said sheet;
extracting all or part of said processing plasticizer from said sheet to produce a matrix comprising UHMWPE and said particulate siliceous filler, the siliceous filler being distributed throughout said matrix, to produce a microporous matrix sheet;
stretching said microporous matrix sheet in at least one stretching direction to a stretch ratio of at least about 1.5 to produce a stretched microporous matrix sheet; and
calendering said stretched microporous matrix sheet under conditions to form pores having a diameter from 0.01 micrometers to 0.1 micrometers, and
placing the battery separator in the battery.

2. The method of claim 1 wherein the siliceous filler constitutes from about 45 percent to about 95 percent by weight of the microporous material.

3. The method of claim 1 wherein the siliceous filler constitutes from about 55 percent to about 80 percent by weight of the microporous material.

4. The method of claim 1 wherein the siliceous filler constitutes from about 61.1 percent to about 80 percent by weight of the microporous material.

5. The method of claim 1 wherein the siliceous filler is selected from silica, precipitated silica, silica gel, or fumed silica.

6. The method of claim 1 wherein the siliceous filler is silica.

7. The method of claim 1 wherein the ratio of siliceous filler to UHMWPE is about 2.6.

8. The method of claim 1 where said microporous matrix sheet is stretched in at least one direction to a stretch ratio from about 1.5 to 15.

9. The method of claim 1 where said UHMWPE is mixed with a high density (HD) polyethylene to produce a polyolefin mixture, where said polyolefin mixture has at least 50% UHMWPE by weight; where said siliceous filler to said polyolefin mixture is in a range of from 1:9 to 15:1 siliceous filler to polyolefin mixture by weight and where said matrix comprises UHMWPE and HD polyethylene and said particulate siliceous filler distributed throughout said matrix.

10. A method for producing a battery with a battery separator, the battery separator is a microporous material, comprising the steps of:
making the battery separator by
mixing ultra high molecular weight polyethylene (UHMWPE), siliceous filler and processing plasticizer together to form a mixture, having a weight ratio of siliceous filler to UHMWPE of from 1:9 to 15:1 by weight; wherein the siliceous filler constitutes from about 5 percent to about 95 percent by weight of the microporous material;
extruding said mixture to form a sheet;
calendering said sheet;
extracting all or part of said processing plasticizer from said sheet to produce a matrix comprising UHMWPE and said particulate siliceous filler, the siliceous filler being distributed throughout said matrix, to produce a microporous matrix sheet;
stretching said microporous matrix sheet in at least one stretching direction to a stretch ratio of at least about 1.5 to produce a stretched microporous matrix sheet; and
calendering said stretched microporous matrix sheet under conditions so that the resulting microporous matrix sheet pores with a diameter from 0.01 micrometers to 0.1 micrometers, and placing the battery separator in the battery.

11. The method of claim 10 wherein the siliceous filler constitutes from about 45 percent to about 95 percent by weight of the microporous material.

12. The method of claim 10 wherein the siliceous filler constitutes from about 55 percent to about 80 percent by weight of the microporous material.

13. The method of claim 10 wherein the siliceous filler constitutes from about 61.1 percent to about 80 percent by weight of the microporous material.

14. The method of claim 10 wherein the siliceous filler is selected from silica, precipitated silica, silica gel, or fumed silica.

15. The method of claim 10 wherein the siliceous filler is silica.

16. The method of claim 10 wherein the ratio of siliceous filler to UHMWPE is about 2.6.

17. The method of claim 10 where said microporous matrix sheet is stretched in at least one direction to a stretch ratio from about 1.5 to 15.

18. The method of claim 10 where said UHMWPE is mixed with a high density (HD) polyethylene to produce a polyolefin mixture, where said polyolefin mixture has at least 50% UHMWPE by weight; where said siliceous filler to said polyolefin mixture is in a range of from 1:9 to 15:1 siliceous filler to polyolefin mixture by weight and where said matrix comprises UHMWPE and HD polyethylene and said particulate siliceous filler distributed throughout said matrix.

19. The method of claim 1 wherein in addition to the siliceous filler, a particulate water-insoluble filler is also present.

20. The method of claim 19 wherein the particulate water-insoluble filler is one or more selected from carbon black, activated carbon, carbon fibers, charcoal, graphite, titanium oxide, iron oxide, copper oxide, zinc oxide, lead oxide, tungsten, antimony oxide, zirconia, magnesia, alumina, molybdenum disulfide, zinc sulfide, barium sulfate, strontium sulfate, calcium carbonate, and magnesium carbonate.

21. The method of claim 20 wherein the particulate water-insoluble filler includes carbon material.

22. The method of claim 21 wherein the carbon material is at least one of carbon black, activated carbons, and carbon fibers.

23. The method of claim 1 wherein the battery separator is a lead acid battery separator, and the battery separator is placed in a lead acid battery.

24. The method of claim 10 wherein the battery separator is a lead acid battery separator, and the battery separator is placed in a lead acid battery.

25. The method of claim 10 , wherein in addition to the siliceous filler, a particulate water-insoluble filler is also present.

Assignees

• Daramic Llc
• Celgard Llc

Inventors

• Miller Eric H
• Yaritz Joseph G
• Demeuse Mark T
• Whear J Kevin

Classifications

• B29L2031/3468

  Batteries, accumulators or fuel cells (battery cases B29L2031/7146) · CPC title

• B01D67/003

  by selective elimination of components, e.g. by leaching · CPC title

• H01M50/431

  Inorganic material · CPC title

• C08J2323/06

  Polyethene · CPC title

• C08L2203/20

  use in electrical or conductive gadgets · CPC title