Low temperature electrolytes for solid oxide cells having high ionic conductivity

Patent metadata

Field	Value
Publication number	US-11560636-B2
Application number	US-201916504451-A
Country	US
Kind code	B2
Filing date	Jul 8, 2019
Priority date	Feb 10, 2010
Publication date	Jan 24, 2023
Grant date	Jan 24, 2023

Abstract

Methods for forming a metal oxide electrolyte improve ionic conductivity. Some of those methods involve applying a first metal compound to a substrate, converting that metal compound to a metal oxide, applying a different metal compound to the metal oxide, and converting the different metal compound to form a second metal oxide. That substrate may be in nanobar form that conforms to an orientation imparted by a magnetic field or an electric field applied before or during the converting. Electrolytes so formed can be used in solid oxide fuel cells, electrolyzers, and sensors, among other applications.

First claim

We claim:

1. A method for forming a metal oxide electrolyte, comprising:
applying a metal compound to a first material in nanobar form; and
converting at least some of the metal compound to form a metal oxide,
thereby forming the metal oxide electrolyte;
wherein the metal oxide electrolyte has an ionic conductivity greater than the bulk ionic conductivity of the first material and of the metal oxide;
wherein the first material in nanobar form is present in the metal oxide electrolyte conforming to an orientation, and the orientation is caused by a magnetic field applied before, during, or before and during the converting.

2. The method of claim 1 , wherein the nanobar form is chosen from nanorods, single-walled nanotubes, multiwalled nanotubes, and combinations thereof.

3. The method of claim 1 , wherein the magnetic field is chosen from static magnetic fields, variable magnetic fields, uniform magnetic fields, non-uniform magnetic fields, and combinations thereof.

4. The method of claim 1 , wherein the first material in nanobar form comprises strontium titanate, and the metal oxide comprises yttria-stabilized zirconia.

5. A method for forming a metal oxide electrolyte, comprising:
applying a metal compound to a first material in nanobar form; and
converting at least some of the metal compound to form a metal oxide,
thereby forming the metal oxide electrolyte;
wherein the metal oxide electrolyte has an ionic conductivity greater than the bulk ionic conductivity of the first material and of the metal oxide;
wherein the first material in nanobar form is present in the metal oxide electrolyte conforming to an orientation, and the orientation is caused by an electric field applied before, during, or before and during the converting.

6. The method of claim 5 , wherein the nanobar form is chosen from nanorods, single-walled nanotubes, multiwalled nanotubes, and combinations thereof.

7. The method of claim 5 , wherein the electric field is chosen from static electric fields, variable electric fields, uniform electric fields, non-uniform electric fields, and combinations thereof.

8. The method of claim 5 , wherein the first material in nanobar form comprises strontium titanate, and the metal oxide comprises yttria-stabilized zirconia.

Assignees

• Fcet Inc
• Ut Battelle Llc

Inventors

• Budaragin Leonid V
• Deininger Mark A
• Pozvonkov Michael M
• Spears Ii D Morgan
• Fisher Paul D
• Ludtka Gerard M
• Pasto Arvid E

Classifications

• H01M8/004

  Cylindrical, tubular or wound · CPC title

• H01M2300/0071

  Oxides · CPC title

• H01M8/1007

  with both reactants being gaseous or vaporised (H01M8/12 takes precedence) · CPC title

• H01M8/1016

  characterised by the electrolyte material (H01M8/12 takes precedence) · CPC title

• C25B13/04 Primary

  characterised by the material · CPC title