Electrochemical production of carbon monoxide and/or syngas

Patent metadata

Field	Value
Publication number	US-11560633-B2
Application number	US-201916964237-A
Country	US
Kind code	B2
Filing date	Jan 18, 2019
Priority date	Feb 15, 2018
Publication date	Jan 24, 2023
Grant date	Jan 24, 2023

Abstract

An electrolysis system and an electrolysis method wherein the electrolysis system includes a pressure-electrolytic cell and a throttle in the catholyte line, by which the catholyte flow can be divided into a gas and liquid phase. In this way, (by-)products of the electrolysis can be recycled, while the electrolytic cell can be operated effectively at a high pressure.

First claim

The invention claimed is:

1. An electrolysis method for production of carbon monoxide and/or synthesis gas using an electrolysis system, wherein the electrolysis system comprises: a pressure electrolysis cell, an anolyte outlet configured to deliver a gas-laden anolyte stream out of the pressure electrolysis cell, a catholyte inlet that leads into the pressure electrolysis cell, a catholyte outlet configured to deliver a gas-laden catholyte stream out of the pressure electrolysis cell, and a product gas outlet configured to deliver carbon monoxide or a synthesis gas out of the pressure electrolysis cell, wherein the catholyte outlet opens into a catholyte conduit comprising a throttle device and then a phase separator that divides the catholyte conduit into a catholyte gas conduit and a catholyte liquid conduit, the method comprising:
introducing reactants into the pressure electrolysis cell and reducing at a cathode,
delivering the gas-laden catholyte stream from the catholyte outlet, and
reducing a pressure on the gas-laden catholyte stream in order to form a gas phase in the gas-laden catholyte stream.

2. The electrolysis method as claimed in claim 1 , further comprising:
separating the gas phase in the gas-laden catholyte stream from a liquid phase in the gas-laden catholyte stream into a catholyte gas stream and a catholyte liquid stream respectively via the phase separator, and
feeding the catholyte gas stream into a recycle compressor.

3. The electrolysis method as claimed in claim 2 , further comprising bringing the catholyte liquid stream to a pressure above 2 bar and then combining the catholyte liquid stream with an anolyte stream that has been freed of oxygen.

4. The electrolysis method as claimed in claim 3 , further comprising freeing the gas-laden anolyte stream exiting the anolyte outlet of oxygen by means of a gas-liquid separation to produce the anolyte stream that has been freed of oxygen.

5. The electrolysis method as claimed in claim 4 , further comprising combining the anolyte stream that has been freed of oxygen with the catholyte liquid stream to give an electrolyte stream that is fed into the pressure electrolysis cell.

6. The electrolysis method as claimed in claim 5 ,
wherein an entire gas phase that forms at the cathode is introduced back into the pressure electrolysis cell.

7. The electrolysis method as claimed in claim 6 , further comprising, guiding the gas-laden catholyte stream directly into the phase separator after the pressure on the gas-laden catholyte stream is reduced.

8. The electrolysis method as claimed in claim 7 ,
wherein waste heat from the electrolysis is removed via the electrolyte stream.

Assignees

• Siemens Energy Global Gmbh & Co Kg
• Linde Gmbh

Inventors

• Hentschel Benjamin
• Peschel Andreas
• Hanebuth Marc
• Schmid Günter
• Taroata Dan

Classifications

• C25B9/19

  with diaphragms · CPC title

• C25B15/08

  Supplying or removing reactants or electrolytes; Regeneration of electrolytes · CPC title

• C25B1/23

  Carbon monoxide or syngas · CPC title

• C25B15/087

  Recycling of electrolyte to electrochemical cell · CPC title

• C25B1/04 Primary

  by electrolysis of water · CPC title