Process for production of a solid material containing isomaltulose crystals and trehalulose

Patent metadata

Field	Value
Publication number	US-11560580-B2
Application number	US-201816485554-A
Country	US
Kind code	B2
Filing date	Feb 7, 2018
Priority date	Feb 15, 2017
Publication date	Jan 24, 2023
Grant date	Jan 24, 2023

Abstract

A process for producing a solid material comprising isomaltulose crystals and trehalulose, including: A) contacting an enzyme complex with a sucrose-containing solution; B) isomerizing at least a part of the sucrose to isomaltulose and trehalulose; C) separating off the enzyme complex to obatin a solution including isomaltulose, trehalulose and water; D) partially removing the water by evaporation to obtain a concentrated solution; E) bringing the concentrated solution to a temperature range of 30° C. to 63° C. and subsequently inducing isomaltulose crystallization in this temperature range followed by cooling, thereby obtaining a solid material including isomaltulose crystals and trehalulose.

First claim

The invention claimed is:

1. A process for producing a solid material comprising isomaltulose crystals and trehalulose, the process comprising:
A) contacting an enzyme complex with a sucrose-comprising solution, wherein the enzyme complex is capable of catalyzing a reaction of converting sucrose to isomaltulose and trehalulose;
B) isomerizing at least a part of the sucrose in the sucrose-comprising solution to isomaltulose and trehalulose;
C) separating off the enzyme complex, thereby obtaining a solution comprising isomaltulose, trehalulose and water;
D) partially removing the water from the solution by evaporation at a first temperature, thereby obtaining a concentrated solution with a solid content of 86 wt % to 92 wt %, based on a total weight of the concentrated solution; and
E) bringing the concentrated solution to a second temperature, which is within a temperature range of 55° C. to 60° C. and is different from the first temperature, and subsequently inducing isomaltulose crystallization in the temperature range of 55° C. to 60° C. followed by cooling, thereby obtaining the solid material comprising isomaltulose crystals and trehalulose.

2. The process of claim 1 , wherein the sucrose-comprising solution of A) has a sucrose concentration of 20-80% by weight, based on a total weight of the sucrose-comprising solution.

3. The process of claim 1 , wherein the enzyme complex comprises at least one sucrose glucosylmutase of the enzyme class EC 5.4.99.11.

4. The process of claim 1 , wherein the isomerizing in B) is conducted at a pH in a range from 3.5 to 9.5.

5. The process of claim 1 , wherein in C), the enzyme complex and solid impurities are separated off from the solution comprising isomaltulose, trehalulose and water by filtration, sedimentation or centrifugation.

6. The process of claim 1 , wherein in D), the first temperature is within a temperature range of from 63° C. to 68° C., and the partial removing of the water is carried out in a pressure range of from 130 mbar to 160 mbar.

7. The process of claim 1 , wherein the isomaltulose crystallization is induced by at least one selected from the group consisting of addition of isomaltulose seed crystals, shearing forces, agitation, friction, radiation and ultrasound.

8. The process of claim 1 , wherein the solid material comprising isomaltulose crystals and trehalulose comprises isomaltulose in an amount of 70 to 90 wt %, trehalulose in an amount of 5 to 25 wt %, glucose in an amount of 0.1 to 5 wt %, fructose in an amount of 0.1 to 5 wt %, and sucrose in an amount of 0.05 to 4 wt %, relative to a total dry weight of the solid material.

9. The process of claim 1 , wherein the isomaltulose crystallization is induced without addition of isomaltulose seed crystals.

10. The process of claim 1 , wherein the isomaltulose crystals are in the form of crystalline strands.

11. The process of claim 1 , wherein in C), the enzyme complex and solid impurities are separated off from the isomaltulose by sedimentation by storage over a period from 2 days to 60 days until the enzyme complex and solid impurities sink to a bottom of the solution comprising isomaltulose, trehalulose and water.

Assignees

• Evonik Operations Gmbh

Inventors

• Hellmers Frank
• Schlegel-Kachel Sibylle
• Oehrlein Johannes
• Wolter Jan

Classifications

• C12P19/12

  Disaccharides · CPC title

• C12Y504/99011

  Isomaltulose synthase (5.4.99.11) · CPC title

• C12P19/24 Primary

  produced by the action of an isomerase, e.g. fructose · CPC title

• C12P19/44

  Preparation of O-glycosides, e.g. glucosides {(polysaccharides and not substituted disaccharides C12P19/04, C12P19/12)} · CPC title

• C07H3/04

  Disaccharides · CPC title