Thermally stable macromolecular compound and petroleum composition including the same

Patent metadata

Field	Value
Publication number	US-11560526-B2
Application number	US-201916293878-A
Country	US
Kind code	B2
Filing date	Mar 6, 2019
Priority date	Mar 6, 2018
Publication date	Jan 24, 2023
Grant date	Jan 24, 2023

Abstract

In one embodiment, an alkylphenol copolymer is disclosed wherein the copolymer comprises at least one alkylphenol monomer and the alkylphenol copolymer exhibits the following: an oscillation displacement Θ of greater than 0 at a temperature of −5° C. in a first oscillation temperature sweep and an oscillation displacement Θ in a second oscillation temperature sweep within 25% of the oscillation displacement Θ in the first oscillation temperature sweep at a temperature of −5° C. In a further embodiment, a petroleum composition is disclosed wherein the composition comprises a petroleum source and a macromolecular compound wherein the macromolecular compound exhibits the following: an oscillation displacement Θ of greater than 0 at a temperature of −10° C. in a first oscillation temperature sweep, and an oscillation displacement Θ in a second oscillation temperature sweep within 25% of the oscillation displacement Θ in the first oscillation temperature sweep at a temperature of −10° C.

First claim

What is claimed is:

1. An alkylphenol copolymer comprising at least two different alkylphenol monomers, wherein the alkylphenol copolymer exhibits the following:
an oscillation displacement Θ of greater than 0 at a temperature of −5° C. in a first oscillation temperature sweep, and
an oscillation displacement Θ in a second oscillation temperature sweep within 25% of the oscillation displacement Θ in the first oscillation temperature sweep at a temperature of −5° C.,
wherein the first oscillation temperature sweep starts at 30° C. and ends at either −20° C. or an oscillation displacement Θ of 0 and is conducted with a stress of 0.4 Pa at an angular frequency of 0.25 rad/s and each subsequent oscillation temperature sweep starts at 25° C. and ends at either −20° C. or an oscillation displacement Θ of 0 and is conducted with a stress of 0.4 Pa at an angular frequency of 0.25 rad/s,
wherein at least one of the at least two different alkylphenol monomers as the following repeating unit (B):

wherein,
y is an integer from 1 to 200; and
R 2 includes a straight or branched C 22 -C 40 alkyl.

2. The alkylphenol copolymer of claim 1 , wherein the oscillation displacement Θ in the second oscillation temperature sweep is within 20% of the oscillation displacement Θ in the first oscillation temperature sweep.

3. The alkylphenol copolymer of claim 1 , wherein the oscillation displacement Θ in the second oscillation temperature sweep is within 5% of the oscillation displacement Θ in the first oscillation temperature sweep.

4. The alkylphenol copolymer of claim 1 , wherein the oscillation displacement Θ in a third oscillation temperature sweep is within 25% of the oscillation displacement Θ in the first oscillation temperature sweep at a temperature of −5° C.

5. The alkylphenol copolymer of claim 1 , wherein the oscillation displacement Θ in a fourth oscillation temperature sweep is within 25% of the oscillation displacement Θ in the first oscillation temperature sweep at a temperature of −5° C.

6. The alkylphenol copolymer of claim 1 , wherein the oscillation displacement Θ in the second oscillation temperature sweep is within 25% of the oscillation displacement Θ in the first oscillation temperature sweep at a temperature of −10° C.

7. The alkylphenol copolymer of claim 1 , wherein the oscillation displacement Θ in the first oscillation temperature sweep is greater than 0 at a temperature of −20° C.

8. The alkylphenol copolymer of claim 1 , wherein the oscillation displacement Θ in the first oscillation temperature sweep is greater than 0 at a temperature of −40° C.

9. The alkylphenol copolymer of claim 1 , wherein the other of the at least two different alkylphenol monomers of the alkylphenol copolymer comprises the following repeating unit (A):

wherein,
x is an integer from 1 to 200; and
R 1 includes a straight or branched C 1 -C 40 alkyl.

10. The alkylphenol copolymer of claim 1 , wherein the other of the at least two different alkylphenol monomers of the alkylphenol copolymer comprises the following repeating unit (A):

wherein,
x is an integer from 1 to 200; and
R 1 includes a straight or branched C 1 -C 15 alkyl.

11. The alkylphenol copolymer of claim 1 , wherein the oscillation displacement Θ in the second oscillation temperature sweep is within 10% of the oscillation displacement Θ in the first oscillation temperature sweep.

12. The alkylphenol copolymer of claim 1 , wherein the oscillation displacement Θ in the second oscillation temperature sweep is within 25% of the oscillation displacement Θ in the first oscillation temperature sweep at a temperature of −15° C.

13. The alkylphenol copolymer of claim 1 , wherein the oscillation displacement Θ in a third oscillation temperature sweep is within 25% of the oscillation displacement Θ in the first oscillation temperature sweep at a temperature of −10° C. and wherein the oscillation displacement Θ in a fourth oscillation temperature sweep is within 25% of the oscillation displacement Θ in the first oscillation temperature sweep at a temperature of −10° C.

14. The alkylphenol copolymer of claim 1 , wherein the alkylphenol copolymer is a block copolymer.

15. The alkylphenol copolymer of claim 1 , wherein the alkylphenol copolymer exhibits an asphaltene dispersancy parameter of about 500 or less as determined at a non-volatile residue percentage of 15% and/or wherein the alkylphenol copolymer exhibits a percent asphaltene dispersancy of about 80% or more as determined at a non-volatile residue percentage of 15%.

16. The alkylphenol copolymer of claim 1 , wherein the alkylphenol copolymer exhibits a Cold Finger paraffinic wax inhibition of about 60% or more.

17. The alkylphenol copolymer of claim 1 , wherein the oscillation temperature sweeps are conducted in a composition consisting essentially of the alkylphenol copolymer and a hydrocarbon solvent at a non-volatile residue concentration of 15%.

Assignees

• Si Group Inc

Inventors

• Chichak Kelly S
• Doane Joseph T
• Christofel Brian
• Shanklin Elliott W

Classifications

• C10G2300/206

  Asphaltenes · CPC title

• C08G8/08

  of formaldehyde, e.g. of formaldehyde formed in situ · CPC title

• C10L1/195

  obtained by reactions involving only carbon-to-carbon unsaturated bonds · CPC title

• C07C39/15

  with all hydroxy groups on non-condensed rings {, e.g. phenylphenol} · CPC title

• C10G2300/80

  Additives · CPC title