Transfer hydrogenation of heavy hydrocarbons with hydrogen-donor solvents

US11560519B2 · US · B2

Patent metadata
FieldValue
Publication numberUS-11560519-B2
Application numberUS-202217654076-A
CountryUS
Kind codeB2
Filing dateMar 9, 2022
Priority dateJul 14, 2017
Publication dateJan 24, 2023
Grant dateJan 24, 2023

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  1. Title

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  2. Abstract

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  5. First independent claim

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Abstract

Official abstract text for this publication.

Processes for converting the coal-derived heavy-oil fraction of syncrude to polyols are described. The processes involve mixing a feed stream comprising the coal-derived heavy-oil fraction with an alcohol and aqueous sulfuric acid, heating the mixture, reacting the coal-derived heavy-oil fraction with ozone, and reacting the ozonated heavy-oil fraction with glycerin to form the polyol. In some cases, the ozonated heavy-oil fraction can be neutralized before reacting the ozonated heavy-oil fraction with the glycerin.

First claim

Opening claim text (preview).

The invention claimed is: 1. A process for making a polyol comprising: mixing a feed stream comprising a coal-derived heavy-oil fraction from syncrude with an alcohol and aqueous sulfuric acid to form a mixture; heating the mixture; reacting the coal-derived heavy-oil fraction in the heated mixture with ozone to form an ozonated heavy-oil fraction; reacting the ozonated heavy-oil fraction with glycerin to form the polyol; and optionally neutralizing the ozonated heavy-oil fraction before reacting the ozonated heavy-oil fraction with the glycerin. 2. The process of claim 1 wherein the alcohol comprises hexanol. 3. The process of claim 1 further comprising: removing heat while reacting the coal-derived heavy-oil fraction in the heated mixture with ozone. 4. The process of claim 1 wherein the ozone is injected into a tank containing the heated mixture. 5. The process of claim 1 wherein the ozone is contacted with the heated mixture in a countercurrent bubble tray column. 6. The process of claim 1 further comprising: diluting the ozone with nitrogen. 7. The process of claim 1 further comprising: removing the alcohol from the polyol. 8. The process of claim 7 wherein the alcohol is removed by flash evaporation. 9. The process of claim 1 wherein the mixture is heated by the coal-derived heavy-oil fraction. 10. A process for making a polyol comprising: mixing a feed stream comprising a coal-derived heavy-oil fraction from syncrude with an alcohol and aqueous sulfuric acid to form a mixture; heating the mixture; reacting the coal-derived heavy-oil fraction in the heated mixture with ozone to form an ozonated heavy-oil fraction; removing heat while reacting the coal-derived heavy-oil fraction in the heated mixture with ozone; neutralizing the ozonated heavy-oil fraction to form a neutralized ozonated heavy-oil fraction; and reacting the neutralized ozonated heavy-oil fraction with glycerin to form the polyol. 11. The process of claim 10 wherein the alcohol comprises hexanol. 12. The process of claim 10 wherein the ozone is injected into a tank containing the heated mixture. 13. The process of claim 10 wherein the ozone is contacted with the heated mixture in a countercurrent bubble tray column. 14. The process of claim 10 further comprising: diluting the ozone with nitrogen. 15. The process of claim 10 further comprising: removing the alcohol from the polyol. 16. The process of claim 15 wherein the alcohol is removed by flash evaporation. 17. The process of claim 10 wherein the mixture is heated by the coal-derived heavy-oil fraction.

Assignees

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Classifications

  • by distillation · CPC title

  • Solvents · CPC title

  • Hydrogenation of the aromatic hydrocarbons · CPC title

  • including at least one step of thermal cracking in the absence of hydrogen · CPC title

  • C10G1/065Primary

    in the presence of a solvent · CPC title

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What does patent US11560519B2 cover?
Processes for converting the coal-derived heavy-oil fraction of syncrude to polyols are described. The processes involve mixing a feed stream comprising the coal-derived heavy-oil fraction with an alcohol and aqueous sulfuric acid, heating the mixture, reacting the coal-derived heavy-oil fraction with ozone, and reacting the ozonated heavy-oil fraction with glycerin to form the polyol. In some …
Who is the assignee on this patent?
Battelle Memorial Institute
What technology area does this patent fall under?
Primary CPC classification C10G1/065. Mapped technology areas include Chemistry & Metallurgy.
When was this patent published?
Publication date Tue Jan 24 2023 00:00:00 GMT+0000 (Coordinated Universal Time) (B2). Legal status and post-grant events are not shown on this page.
What related patents are in patentsdb?
We list 4 related publications on this page (citations in our corpus or others sharing the same primary CPC).