Lignin to liquid fuels and polyols using biomass-derived solvents
US-11268034-B2 · Mar 8, 2022 · US
US11560519B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11560519-B2 |
| Application number | US-202217654076-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 9, 2022 |
| Priority date | Jul 14, 2017 |
| Publication date | Jan 24, 2023 |
| Grant date | Jan 24, 2023 |
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Processes for converting the coal-derived heavy-oil fraction of syncrude to polyols are described. The processes involve mixing a feed stream comprising the coal-derived heavy-oil fraction with an alcohol and aqueous sulfuric acid, heating the mixture, reacting the coal-derived heavy-oil fraction with ozone, and reacting the ozonated heavy-oil fraction with glycerin to form the polyol. In some cases, the ozonated heavy-oil fraction can be neutralized before reacting the ozonated heavy-oil fraction with the glycerin.
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The invention claimed is: 1. A process for making a polyol comprising: mixing a feed stream comprising a coal-derived heavy-oil fraction from syncrude with an alcohol and aqueous sulfuric acid to form a mixture; heating the mixture; reacting the coal-derived heavy-oil fraction in the heated mixture with ozone to form an ozonated heavy-oil fraction; reacting the ozonated heavy-oil fraction with glycerin to form the polyol; and optionally neutralizing the ozonated heavy-oil fraction before reacting the ozonated heavy-oil fraction with the glycerin. 2. The process of claim 1 wherein the alcohol comprises hexanol. 3. The process of claim 1 further comprising: removing heat while reacting the coal-derived heavy-oil fraction in the heated mixture with ozone. 4. The process of claim 1 wherein the ozone is injected into a tank containing the heated mixture. 5. The process of claim 1 wherein the ozone is contacted with the heated mixture in a countercurrent bubble tray column. 6. The process of claim 1 further comprising: diluting the ozone with nitrogen. 7. The process of claim 1 further comprising: removing the alcohol from the polyol. 8. The process of claim 7 wherein the alcohol is removed by flash evaporation. 9. The process of claim 1 wherein the mixture is heated by the coal-derived heavy-oil fraction. 10. A process for making a polyol comprising: mixing a feed stream comprising a coal-derived heavy-oil fraction from syncrude with an alcohol and aqueous sulfuric acid to form a mixture; heating the mixture; reacting the coal-derived heavy-oil fraction in the heated mixture with ozone to form an ozonated heavy-oil fraction; removing heat while reacting the coal-derived heavy-oil fraction in the heated mixture with ozone; neutralizing the ozonated heavy-oil fraction to form a neutralized ozonated heavy-oil fraction; and reacting the neutralized ozonated heavy-oil fraction with glycerin to form the polyol. 11. The process of claim 10 wherein the alcohol comprises hexanol. 12. The process of claim 10 wherein the ozone is injected into a tank containing the heated mixture. 13. The process of claim 10 wherein the ozone is contacted with the heated mixture in a countercurrent bubble tray column. 14. The process of claim 10 further comprising: diluting the ozone with nitrogen. 15. The process of claim 10 further comprising: removing the alcohol from the polyol. 16. The process of claim 15 wherein the alcohol is removed by flash evaporation. 17. The process of claim 10 wherein the mixture is heated by the coal-derived heavy-oil fraction.
by distillation · CPC title
Solvents · CPC title
Hydrogenation of the aromatic hydrocarbons · CPC title
including at least one step of thermal cracking in the absence of hydrogen · CPC title
in the presence of a solvent · CPC title
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