Dispersion liquid of colored resin fine particles for aqueous ink, and aqueous ink composition for writing instruments using same

Patent metadata

Field	Value
Publication number	US-11560489-B2
Application number	US-201816957599-A
Country	US
Kind code	B2
Filing date	Dec 21, 2018
Priority date	Dec 25, 2017
Publication date	Jan 24, 2023
Grant date	Jan 24, 2023

Abstract

Provided is a dispersion liquid of colored resin fine particles for an aqueous ink having excellent stability and a sufficient drawn line intensity; an aqueous ink composition for a writing instrument such as felt-tip pens, marking pens, and ballpoint pens using the dispersion liquid of the colored resin fine particle as a colorant; and a writing instrument loaded with the composition. The dispersion liquid of colored resin fine particles for an aqueous ink includes colored resin fine particles dispersed in water, the colored resin fine particles composed of at least a cyclohexyl (meth)acrylate monomer, and a basic dye or an oil-soluble dye, in which the content of the cyclohexyl (meth)acrylate monomer is 30% by mass or more, and the content of the basic dye or the oil-soluble dye is 15% by mass or more based on the total polymer component constituting the colored resin fine particles.

First claim

The invention claimed is:

1. A dispersion liquid of colored resin fine particles for an aqueous ink, comprising:
colored resin fine particles dispersed in water, wherein
the colored resin fine particles are composed of at least a polymer formed from a cyclohexyl (meth)acrylate monomer, a hydrophobic vinyl monomer other than the cyclohexyl (meth)acrylate monomer, and an aqueous (meth)acrylate ester monomer, and
a basic dye or an oil-soluble dye, wherein
a content of the cyclohexyl (meth)acrylate monomer is 30% by mass or more based on a total polymer component constituting the colored resin fine particles, and
a content of the basic dye or the oil-soluble dye is 15% by mass or more based on the total polymer component.

2. The dispersion liquid of colored resin fine particles for an aqueous ink according to claim 1 , wherein the content of the cyclohexyl (meth)acrylate monomer is from 30% by mass to 95% by mass based on the total polymer component constituting the colored resin fine particles.

3. The dispersion liquid of colored resin fine particles for an aqueous ink according to claim 1 , wherein the colored resin fine particles have an average particle size from 20 to 300 nm.

4. An aqueous ink composition for a writing instrument, comprising the dispersion liquid of colored resin fine particles for an aqueous ink described in claim 1 , a water-soluble organic solvent, and water.

5. A writing instrument being loaded with the aqueous ink composition for a writing instrument described in claim 4 .

6. The dispersion liquid of colored resin fine particles for an aqueous ink according to claim 2 , wherein the colored resin fine particles have an average particle size from 20 to 300 nm.

7. An aqueous ink composition for a writing instrument, comprising the dispersion liquid of colored resin fine particles for an aqueous ink described in claim 2 , a water-soluble organic solvent, and water.

8. An aqueous ink composition for a writing instrument, comprising the dispersion liquid of colored resin fine particles for an aqueous ink described in claim 3 , a water-soluble organic solvent, and water.

9. A writing instrument being loaded with the aqueous ink composition for a writing instrument described in claim 7 .

10. A writing instrument being loaded with the aqueous ink composition for a writing instrument described in claim 8 .

11. The dispersion liquid of colored resin fine particles for an aqueous ink according to claim 1 , wherein
the hydrophobic vinyl monomer other than the cyclohexyl (meth)acrylate monomer is at least one selected from the group consisting of methyl (meth)acrylate, ethyl (meth)acrylate, propyl (meth)acrylate, isopropyl (meth)acrylate, n-butyl (meth)acrylate, isobutyl (meth)acrylate, t-butyl (meth)acrylate, hexyl (meth)acrylate, octyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, lauryl (meth)acrylate, palmityl (meth)acrylate, stearyl (meth)acrylate, behenyl (meth)acrylate, styrene, and methyl styrene.

12. The dispersion liquid of colored resin fine particles for an aqueous ink according to claim 1 , wherein
the aqueous monomer is at least one selected from the group consisting of glycerin monomethacrylate, sodium 2-sulfoethyl methacrylate, polyethylene glycol monomethacrylate, polypropylene glycol monomethacrylate, polyethylene glycol-polypropylene glycol monomethacrylate, polyethylene glycol-tetramethylene glycol-monomethacrylate, and propylene glycol-polybutylene glycol-monomethacrylate.

13. The dispersion liquid of colored resin fine particles for an aqueous ink according to claim 1 , further comprising a crosslinking agent in a content of from 0.1 to 25% by mass based on a total amount of the monomers.

Assignees

• Mitsubishi Pencil Co

Inventors

• Haga Hisato

Classifications

• B43K8/022

  with writing-points comprising fibres · CPC title

• C09D11/033

  characterised by the solvent · CPC title

• B43K7/02

  Ink reservoirs; Ink cartridges (B43K7/01 takes precedence) · CPC title

• C09D11/107 Primary

  from unsaturated acids or derivatives thereof · CPC title

• C09D11/17

  characterised by colouring agents · CPC title