Glass article having coating with interpenetrating polymer network
US-2017158553-A1 · Jun 8, 2017 · US
US11560331B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11560331-B2 |
| Application number | US-201916432995-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 6, 2019 |
| Priority date | Jun 8, 2018 |
| Publication date | Jan 24, 2023 |
| Grant date | Jan 24, 2023 |
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A coated glass substrate and a method of making the glass substrate is disclosed. The method comprises the following: providing a coating formulation on a glass substrate wherein the coating formulation comprises at least one polymerizable compound, a glass frit, and a non-crosslinked polymer and heating the coating formulation on the glass substrate. The coated glass substrate includes a coating provided on a surface of a glass substrate wherein the coating comprises a semi-interpenetrating polymer network including a non-crosslinked polymer and a glass frit. The coating exhibits a stud pull of about 275 psi or more.
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The invention claimed is: 1. A coated glass substrate comprising: a coating provided on a surface of a glass substrate, the coating comprising a semi-interpenetrating polymer network including a non-crosslinked polymer comprising an acrylate copolymer, a styrene polymer, a styrene copolymer, or a mixture thereof and a glass frit, wherein the coating exhibits a stud pull of about 275 psi or more. 2. The coated glass substrate of claim 1 , wherein the coating exhibits a stud pull of about 500 psi or more. 3. The coated glass substrate of claim 1 , wherein the coating exhibits a ΔE value of about 4 or less after being exposed to a copper-accelerated acetic acid-salt spray (“CASS”) in accordance with ASTM B368-09 (2014). 4. The coated glass substrate of claim 1 , wherein the coated glass substrate exhibits a Hoffman hardness of 15 or more. 5. The coated glass substrate of claim 1 , wherein the glass frit contains bismuth oxide or titanium dioxide. 6. The coated glass substrate of claim 1 , wherein the coating contains organic material in an amount of from about 1 wt. % to about 11 wt. %. 7. The coated glass substrate of claim 1 , wherein the non-crosslinked polymer comprises a linear polymer. 8. The coated glass substrate of claim 1 , wherein the non-crosslinked polymer comprises an acrylate copolymer. 9. The coated glass substrate of claim 8 , wherein the acrylate copolymer comprises an acrylate-styrene-acrylonitrile copolymer.
Organic continuous phases · CPC title
Decorative coatings · CPC title
containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase · CPC title
Mixtures of organic and inorganic materials, e.g. ormosils and ormocers · CPC title
by fritting glass powder · CPC title
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