Process and reactor comprising a plurality of catalyst receptacles

Patent metadata

Field	Value
Publication number	US-11560309-B2
Application number	US-202117501322-A
Country	US
Kind code	B2
Filing date	Oct 14, 2021
Priority date	Apr 17, 2015
Publication date	Jan 24, 2023
Grant date	Jan 24, 2023

Abstract

A reactor having a shell comprising one or more reactor tubes located within the shell, said reactor tube or tubes comprising a plurality of catalyst receptacles containing catalyst; means for providing a heat transfer fluid to the reactor shell such that the heat transfer fluid contacts the tube or tubes; an inlet for providing reactants to the reactor tubes; and an outlet for recovering products from the reactor tubes; wherein the plurality of catalyst receptacles containing catalyst within a tube comprises catalyst receptacles containing catalyst of at least two configurations.

First claim

What is claimed:

1. A reactor having a shell comprising:
one or more reactor tubes located within the shell, said reactor tube or tubes comprising a plurality of catalyst receptacles containing catalyst;
means for providing a heat transfer fluid to the reactor shell such that the heat transfer fluid contacts the tube or tubes;
an inlet for providing reactants to the reactor tubes; and
an outlet for recovering products from the reactor tubes;
wherein the plurality of catalyst receptacles containing catalyst within a tube comprises catalyst receptacles of at least two configurations,
wherein each of the catalyst receptacles comprise:
an annular container, said container having a perforated inner container wall defining an inner channel, a perforated outer container wall, a top surface closing the annular container and a bottom surface closing the annular container;
a surface closing the bottom of said inner channel formed by the inner container wall of the annular container;
a carrier outer wall extending from the bottom surface of said container to the top surface;
a seal extending from the container by a distance which extends beyond the carrier outer wall;
said carrier outer wall having apertures located below the seal.

2. The reactor according to claim 1 wherein at least one of the catalyst receptacles containing catalyst differs from at least one other of the receptacles in terms of length.

3. The reactor according to claim 1 wherein the catalyst receptacles containing catalyst allow, in use, the temperature of the reaction to be within 100° C. of the equilibrium temperature at a given conversion level.

4. The reactor according to claim 1 wherein there are three, four, five, six, seven, eight, nine, or ten different configurations of catalyst receptacles containing catalyst.

5. The reactor according to claim 1 wherein at least one of the catalyst receptacles containing catalyst differs from at least one other of the receptacles in terms of radial space.

6. The reactor according to claim 1 wherein the at least two configurations of catalyst receptacles comprises a change in the amount of catalyst loaded in the catalyst receptacle.

7. The reactor according to claim 6 wherein the change in the amount of catalyst loaded in the catalyst carried is achieved by altering the amount of catalyst loaded into the catalyst receptacle and filling the receptacle with inert material.

8. The reactor according to claim 6 wherein the change in the amount of catalyst loaded in the catalyst receptacle is achieved by altering the length of the receptacle.

9. The reactor according to claim 1 wherein the at least two configurations of catalyst receptacles comprises altering the diameter of the carrier such that when it is loaded into a tube, the annular space between the catalyst receptacle and the reaction tube into which it is to be inserted is altered.

10. A reactor system comprising a reactor according to claim 1 used in combination with one or more conventional adiabatic beds.

11. The reactor system according to claim 10 wherein the system is configured such that a bulk reaction can be carried out initially in a conventional adiabatic bed before being passed to a reactor of claim 1 .

12. A process for carrying out an equilibrium limited reaction comprising providing reactants to the reactor of claim 1 , allowing reaction to occur, and recovering product.

13. The process according to claim 12 wherein the process is the oxidation of sulphur dioxide to sulphur trioxide, the manufacture of ammonia, the synthesis of methanol from carbon monoxide and hydrogen, the water-gas shift reaction, the reverse water-gas shift.

14. A process for carrying out an equilibrium limited reaction comprising providing reactants to a reactor system according to claim 10 , allowing reaction to occur, and recovering product.

15. The process according to claim 14 wherein the process is the oxidation of sulphur dioxide to sulphur trioxide, the manufacture of ammonia, the synthesis of methanol from carbon monoxide and hydrogen, the water-gas shift reaction, the reverse water-gas shift.

16. A process for carrying out an equilibrium limited reaction comprising providing reactants to a reactor system according to claim 11 , allowing reaction to occur, and recovering product.

17. The process according to claim 16 wherein the process is the oxidation of sulphur dioxide to sulphur trioxide, the manufacture of ammonia, the synthesis of methanol from carbon monoxide and hydrogen, the water-gas shift reaction, the reverse water-gas shift.

18. The reactor according to claim 1 wherein at least one of the catalyst receptacles containing catalyst differs from at least one other of the receptacles in terms of the thickness of the respective annular containers of the receptacles.

19. The reactor according to claim 1 wherein at least one of the catalyst receptacles containing catalyst differs from at least one other of the receptacles in terms of cross-sectional shape.

Assignees

• Johnson Matthey Davy Technologies Ltd

Inventors

• Gray Julian Stuart

Classifications

• C01B17/74 Primary

  Preparation · CPC title

• B01J2208/00212

  Plates; Jackets; Cylinders · CPC title

• B01J8/067 Primary

  Heating or cooling the reactor (B01J8/062 takes precedence) · CPC title

• B01J8/025

  in a cylindrical shaped bed · CPC title

• B01J2208/00814

  the particulate material being provides in prefilled containers · CPC title