Method and plant for generation of synthesis gas

Patent metadata

Field	Value
Publication number	US-11560308-B2
Application number	US-201716467605-A
Country	US
Kind code	B2
Filing date	Nov 20, 2017
Priority date	Dec 9, 2016
Publication date	Jan 24, 2023
Grant date	Jan 24, 2023

Abstract

Method and plant for generating a synthesis gas which consists mainly of carbon monoxide and hydrogen and has been freed of acid gases, proceeding from a hydrocarbonaceous fuel, and air and steam, wherein low-temperature fractionation separates air into an oxygen stream, a tail gas stream and a nitrogen stream, wherein the tail gas stream and the nitrogen stream are at ambient temperature and the nitrogen stream is at elevated pressure, wherein the hydrocarbonaceous fuel, having been mixed with the oxygen stream and steam at elevated temperature and elevated pressure, is converted to a synthesis gas by a method known to those skilled in the art, and wherein acid gas is subsequently separated therefrom by low-temperature absorption in an absorption column, wherein the nitrogen stream generated in the fractionation of air is passed through and simultaneously cooled in an expansion turbine and then used to cool either the absorbent or the coolant circulating in the coolant circuit of the compression refrigeration plant.

First claim

The invention claimed is:

1. A composite plant for generation of synthesis gas, the composite plant comprising the following component plants:
a. a first component plant configured to fractionate air using an air fractionation plant that works by the principle of cryogenic rectification under elevated pressure, suitable for generating a stream of gaseous oxygen and a stream of gaseous nitrogen at elevated pressure and ambient temperature, and a tail gas stream;
b. a second component plant configured to convert a carbonaceous fuel with a gasifying agent to give a synthesis gas comprising mainly hydrogen and carbon monoxide, wherein first component plant and second component plant are connected such that the oxygen generated in component plant a) can be added to the gasifying agent used in component plant b),
c. a third component plant for removal of the acid gases carbon dioxide and hydrogen sulfide from the crude synthesis gas generated in second component plant by absorption at low temperature with a liquid absorbent, wherein the third component plant further comprises a compression refrigeration plant,
wherein the composite plant comprises an expansion turbine by means of which the nitrogen stream generated in the first component plant can be expanded and simultaneously cooled, and a heat exchanger for the heat exchange between said expanded nitrogen stream and the liquid absorbent used in the third component plant or with a coolant of the compression refrigeration plant,
wherein the composite plant further comprises a second heat exchanger for the heat exchange between the nitrogen stream generated in the first component plant before the nitrogen stream has been expanded and the same stream ( 19 ) after it has been expanded in the expansion turbine and after it has exchanged heat ( 17 ) with the liquid absorbent or collant.

2. A composite plant for generation of synthesis gas, the composite plant comprising the following component plants:
a. a first component plant configured to fractionate air using an air fractionation plant that works by the principle of cryogenic rectification under elevated pressure, suitable for generating a stream of gaseous oxygen and a stream of gaseous nitrogen at elevated pressure and ambient temperature, and a tail gas stream:
b. a second component plant configured to convert a carbonaceous fuel with a gasifying agent to give a synthesis gas comprising mainly hydrogen and carbon monoxide, wherein first component plant and second component plant are connected such that the oxygen generated in component plant a) can be added to the gasifying agent used in component plant b),
c. a third component plant for removal of the acid gases carbon dioxide and hydrogen sulfide from the crude synthesis gas generated in second component plant by absorption at low temperature with a liquid absorbent, wherein the third component plant further comprises a compression refrigeration plant,
wherein the composite plant comprises an expansion turbine by means of which the nitrogen stream generated in the first component plant can be expanded and simultaneously cooled, and a heat exchanger for the heat exchange between said expanded nitrogen stream and the liquid absorbent used in the third component plant or with a coolant of the compression refrigeration plant,
wherein the plant comprises a second turbine by means of which the nitrogen stream, after it has expanded in the first turbine and exchanged heat in the heat exchanger with the liquid absorbent or the coolant, can be expanded further, and in that this heat exchanger is designed such that simultaneous heat exchange between the liquid absorbent or the coolant therein, the nitrogen stream after it has expanded in the first turbine and the nitrogen stream after it has expanded in the second turbine, is possible.

3. A composite plant for generation of synthesis gas, the composite plant comprising the following component plants:
a. a first component plant configured to fractionate air using an air fractionation plant that works by the principle of cryogenic rectification under elevated pressure, suitable for generating a stream of gaseous oxygen and a stream of gaseous nitrogen at elevated pressure and ambient temperature, and a tail gas stream,
b. a second component plant configured to convert a carbonaceous fuel with a gasifying agent to give a synthesis gas comprising mainly hydrogen and carbon monoxide, wherein first component plant and second component plant are connected such that the oxygen generated in component plant a) can be added to the gasifying agent used in component plant b),
c. a third component plant for removal of the acid gases carbon dioxide and hydrogen sulfide from the crude synthesis gas generated in second component plant by absorption at low temperature with a liquid absorbent, wherein the third component plant further comprises a compression refrigeration plant,
wherein the composite plant comprises an expansion turbine by means of which the nitrogen stream generated in the first component plant can be expanded and simultaneously cooled, and a heat exchanger for the heat exchange between said expanded nitrogen stream and the liquid absorbent used in the third component plant or with a coolant of the compression refrigeration plant,
wherein the plant additionally comprises a compression turbine for compression of the tail gas stream which is driven by the expansion turbine that serves to expand the nitrogen stream, wherein the plant further comprises a heat exchanger for cooling the compressed tail gas stream with cooling water and an expansion turbine for expansion of the tail gas stream, and wherein the plant further comprises a heat exchanger having two pathways for the tail gas stream and one pathway for the nitrogen stream, and wherein the heat exchanger for the heat exchange between the nitrogen stream and the absorbent or the coolant additionally comprises a pathway for the tail gas stream.

4. The composite plant according to claim 3 , wherein the compression turbine and the expansion turbine are both mounted on a turbine axis.

Assignees

• Air Liquide

Inventors

• Chaubet Lucie
• Bonne Frederic
• Bouet Camille
• Schlichting Holger
• Wagner Marc

Classifications

• F25J2220/40

  Separating high boiling, i.e. less volatile components from air, e.g. CO2, hydrocarbons · CPC title

• C01B3/382 Primary

  Processes with two or more reaction steps, of which at least one is catalytic, e.g. steam reforming and partial oxidation · CPC title

• C10J2300/165

  integrated with a gas turbine or gas motor · CPC title

• F25J2260/44

  using nitrogen for cooling purposes · CPC title

• F25J2210/02

  Multiple feed streams, e.g. originating from different sources · CPC title