Microfluidic active mixing nozzle for three-dimensional printing of viscoelastic inks
US-2019105622-A1 · Apr 11, 2019 · US
US11559919B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11559919-B2 |
| Application number | US-201816630079-A |
| Country | US |
| Kind code | B2 |
| Filing date | Aug 8, 2018 |
| Priority date | Aug 9, 2017 |
| Publication date | Jan 24, 2023 |
| Grant date | Jan 24, 2023 |
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A method for the application of hydrous mineral binder compositions which contain fibres. An aqueous accelerator is mixed with the aqueous binder composition in a mixer shortly before the application. The method is very robust and makes it possible to quickly produce even large moulded bodies having a uniform surface and very good strength development properties.
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The invention claimed is: 1. A method for applying a fiber-containing building material, comprising providing a hydrous mineral binder composition, at least one aqueous accelerator for setting of the hydrous mineral binder composition, and fibers, feeding the hydrous mineral binder composition; to a continuous mixer comprising a drive, a mixing region comprising at least one inlet and at least one dynamic mixing element and a conveying region connected to the mixing region and comprising at least one conveying device and an outlet, the hydrous mineral binder composition being conveyed through the at least one inlet into the mixing region, feeding the fibers into the mixing region of the continuous mixer, feeding the at least one aqueous accelerator into the mixing region of the continuous mixer, mixing the at least one aqueous accelerator with the hydrous mineral binder composition and the fibers in the mixing region of the continuous mixer to provide an accelerated fiber-containing mineral binder composition, conveying the accelerated fiber-containing mineral binder composition by means of the conveying device to the outlet, and applying the accelerated fiber-containing mineral binder composition, wherein the dynamic mixing element comprises a stirring shaft having stirring elements, the stirring elements taking the form of pegs, and a distance between adjacent stirring elements being at least 60% of the length of the longest fibers. 2. The method as claimed in claim 1 , wherein the hydrous mineral binder composition comprises at least one hydraulic binder. 3. The method as claimed in claim 1 , wherein the fibers are selected from the group consisting of metal fibers, mineral fibers, natural fibers, polymeric fibers, and mixtures thereof. 4. The method as claimed claim 1 , wherein the fibers are flexible, having a flexural rigidity of not more than 20 N·mm 2 , the flexural rigidity in the case of flat fibers being based on the flexural direction requiring the least force for flexure. 5. The method as claimed in claim 1 , wherein the fibers a) are round and have a length of 5 mm to 100 mm, and a diameter of 5 μm to 500 μm, or b) are flat and have a length of 5 mm to 100 mm, a width of 5 μm to 2 mm, and a height of 5 μm to 300 μm. 6. The method as claimed in claim 1 , wherein one cubic meter of the fiber-containing hydrous mineral binder composition contains 0.4 to 25 liters of fibers, calculated with the apparent density of the fibers. 7. The method as claimed in claim 1 , wherein the fiber-containing hydrous mineral binder composition is a fresh mortar having a slump of at least 170 mm, determined according to DIN EN 1015-3 after the raising of the slump cone without lifts of the flow table. 8. The method as claimed in claim 1 , wherein the aqueous accelerator comprises at least one compound selected from the group consisting of amino alcohols, alkali metal and alkaline earth metal nitrates, alkali metal and alkaline earth metal nitrites, alkali metal and alkaline earth metal thiocyanates, alkali metal and alkaline earth metal halides, alkali metal and alkaline earth metal carbonates, glycerol, glycerol derivatives, glycols, glycol derivatives, aluminum salts, aluminum hydroxides, alkali metal and alkaline earth metal hydroxides, alkali metal and alkaline earth metal silicates, alkali metal and alkaline earth metal oxides, crystallization nuclei, and mixtures thereof. 9. The method as claimed in claim 1 , wherein the aqueous accelerator is metered in an amount in the range from 0.1 to 8 parts by weight, calculated as solid without water, based on 100 parts by weight of mineral binder. 10. The method as claimed in claim 1 , wherein the continuous mixer is mounted on a movable printing head. 11. The method as claimed in claim 1 , wherein the conveying device is a screw conveyor having turns, a distance between adjacent turns of the screw conveyor being at least 40% of the length of the longest fibers. 12. The method as claimed in claim 11 , wherein the distances between adjacent turns of the screw conveyor are of substantially equal size and/or in that the conveying device comprises two to four turns. 13. The method as claimed in claim 1 , wherein the fibers are provided in the hydrous mineral binder composition and/or in that the fibers are fed in the hydrous mineral binder composition to the mixer.
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