Active magnetic regenerative processes and systems employing hydrogen as heat transfer fluid and process

Patent metadata

Field	Value
Publication number	US-11555652-B2
Application number	US-202117548267-A
Country	US
Kind code	B2
Filing date	Dec 10, 2021
Priority date	Mar 28, 2017
Publication date	Jan 17, 2023
Grant date	Jan 17, 2023

Abstract

A system including:
an active magnetic regenerative refrigerator apparatus that includes a high magnetic field section in which a hydrogen heat transfer fluid can flow from a cold side to a hot side through at least one magnetized bed of at least one magnetic refrigerant, and a low magnetic field or demagnetized section in which the hydrogen heat transfer fluid can flow from a hot side to a cold side through the demagnetized bed; a first conduit fluidly coupled between the cold side of the low magnetic field or demagnetized section and the cold side of the high magnetic field section; and a second conduit fluid coupled to the first conduit, an expander and at least one liquefied hydrogen storage module.

First claim

What is claimed is:

1. A process for liquefying a hydrogen gas comprising:
introducing a hydrogen heat transfer fluid into an active magnetic regenerative refrigerator apparatus that comprises (i) a high magnetic field section in which the hydrogen heat transfer fluid flows from a cold side to a hot side through at least one magnetized bed of at least one magnetic refrigerant, (ii) a first no heat transfer fluid flow section in which the bed is demagnetized, (iii) a low magnetic or demagnetized field section in which the hydrogen heat transfer fluid flows from a hot side to a cold side through the demagnetized bed, and (iv) a second no heat transfer fluid flow section in which the bed is magnetized;
continuously introducing the hydrogen heat transfer fluid from the cold side of the low magnetic or demagnetized field section into the cold side of the high magnetic field section;
continuously separating a bypass portion of the cold hydrogen heat transfer fluid flowing from the cold side of the low magnetic field or demagnetized section into an expander; and
isenthalpically expanding the separated portion of the hydrogen heat transfer fluid to produce liquefied hydrogen.

2. The process of claim 1 , wherein the bypass portion constitutes 3 to 12% of the total hydrogen heat transfer fluid exiting the cold side of the low magnetic or demagnetized field section.

3. The process of claim 1 , wherein the magnetic refrigerant operates at or below its Curie temperature throughout an entire active magnetic regeneration cycle.

4. The process of claim 1 , wherein the process provides a figure of merit (FOM) of at least 0.5.

5. The process of claim 1 , wherein the active magnetic regenerative refrigerator apparatus includes a plurality of magnetic refrigerant layers.

6. The process of claim 1 , wherein the active magnetic regenerative refrigerator apparatus includes 1 to 16 layers of compositionally distinct magnetic refrigerant materials.

7. The process of claim 5 , wherein the active magnetic regenerative refrigerator apparatus includes up to 13 layers of compositionally distinct magnetic refrigerant materials.

8. The process of claim 1 , wherein the active magnetic regenerative refrigerator apparatus comprises a composition that includes at least one magnetic refrigerant material and at least one ortho H 2 to para H 2 catalyst.

9. The process of claim 8 , wherein the magnetic refrigerant material is in the form of particles having a largest cross section dimension of up to 250 μm.

10. The process of claim 8 , wherein the composition comprises magnetic refrigerant material particles having a largest cross section dimension of up to 250 μm, and a binder interspersed with the particles, wherein the ortho H 2 to para H 2 catalyst is bonded to the particles and/or the binder.

11. The process of claim 8 , wherein the composition comprises magnetic refrigerant material particles having a largest cross section dimension of up to 250 μm, and ortho H 2 to para H 2 catalyst particles having a largest cross section dimension of less than 5 μm.

12. The process of claim 9 , wherein the magnetic refrigerant material particles have a diameter of 150 to 250 μm.

13. The process of claim 9 , wherein the magnetic refrigerant material particles have a diameter of 100 to 250 μm.

14. The process of claim 10 , wherein the binder comprises at least one epoxy material.

15. The process of claim 1 , wherein the magnetic refrigerant material is selected from Gd, Gd 0.90 Y 0.10 , Gd 0.30 Tb 0.70 , Gd 0.69 Er 0.31 , Gd 0.02 Tb 0.98 , Gd 0.32 Dy 0.68 , Gd 0.66 Y 0.34 , Gd 0.39 Ho 0.61 , Gd 0.59 Y 0.41 , Gd 0.15 Dy 0.85 , Gd 0.42 Er 0.58 , Gd 0.27 Ho 0.73 , Gd 0.16 Ho 0.84 , Gd 0.34 Er 0.66 , Gd 0.23 Er 0.77 , (Ho 0.80 Gd 0.20 )Co 2 , Ho 0.90 Gd 0.10 Co 2 , Ho 0.95 Gd 0.05 Co 2 , Gd 0.5 Dy 0.5 Ni 2 , or Dy 0.75 Er 0.25 Al 2 .

16. The process of claim 1 , wherein the magnetic refrigerant material is Gd 0.83 Dy 0.17 , or (Gd x Er 1-x )Al 2 , wherein x is 0 or 1.

17. The process of claim 1 , wherein the magnetic refrigerant material is a material with a second order phase transition.

18. The process of claim 1 , wherein the liquefied hydrogen exiting the expander is at a temperature of 20 to 23 K and a pressure of 15 to 35 psia.

19. The process of claim 1 , wherein the hydrogen heat transfer fluid exiting the cold side of the low magnetic or demagnetized field section is at a temperature of 20 to 23 K and a pressure of 300 psia.

20. The process of claim 1 , further comprising continuously introducing the hydrogen heat transfer fluid from the hot side of the high magnetic field section into a heat exchanger and then into the hot side of the low magnetic or demagnetized field section.

21. The process of claim 20 , further comprising introducing hydrogen gas from a hydrogen gas source into the hydrogen heat transfer fluid flowing from the hot side of the high magnetic field section into the hot side of the low magnetic or demagnetized field section.

22. The process of claim 1 , wherein the hydrogen heat transfer fluid consists essentially of hydrogen.

23. The process of claim 5 , wherein each j th magnetic refrigerant layer includes a heat transfer fluid outlet and a heat transfer fluid inlet and the active magnetic regenerative refrigerator apparatus is in the shape of a circular wheel, the process further comprising diverting a portion of the heat transfer fluid flowing from the heat transfer fluid outlet from the j th heat transfer fluid layer in the hot-to-cold flow region via hermetic diversion flow channels around the circumference of the wheel into the cold-to-hot flow of the heat transfer fluid inlet to the j th layer in the cold-to-hot flow region with a controllable diversion valve to provide lesser flow for the next colder demagnetized layer and simultaneously provide flow into the next hotter magnetized layer.

Assignees

• Battelle Memorial Institute
• Emerald Energy Nw Llc

Inventors

• Holladay Jamie D
• Barclay John

Classifications

• F25J2290/44

  Particular materials used, e.g. copper, steel or alloys thereof or surface treatments used, e.g. enhanced surface · CPC title

• F25J2210/06

  Splitting of the feed stream, e.g. for treating or cooling in different ways · CPC title

• F25J1/001

  Hydrogen · CPC title

• F25J2205/86

  using electrical phenomena, e.g. Corona discharge, electrolysis or magnetic field · CPC title

• F25J2215/10

  Hydrogen · CPC title