Inorganic particle composite fiber, method for manufacturing same, and molded article

Patent metadata

Field	Value
Publication number	US-11555270-B2
Application number	US-201816606732-A
Country	US
Kind code	B2
Filing date	Mar 12, 2018
Priority date	Apr 21, 2017
Publication date	Jan 17, 2023
Grant date	Jan 17, 2023

Abstract

To provide a new inorganic particle composite fiber including a large amount of adhering inorganic particles, An inorganic particle composite fiber includes: fiber; and inorganic particles fixed to the fiber, the fiber being thread-like in shape, the inorganic particles being fixed to the fiber via an ionic polymer.

First claim

The invention claimed is:

1. An inorganic particle composite fiber, comprising:
fiber; and
inorganic particles fixed to the fiber,
the fiber being thread-like in shape,
the inorganic particles being fixed to the fiber via an ionic polymer,
the inorganic particle composite fiber including a plurality of layers each containing a portion of the ionic polymer which portion is present between the fiber and the inorganic particles,
the plurality of layers being a stack of a layer containing a cationic polymer and a layer containing an anionic polymer,
the fiber being selected from a regenerated fiber, a semi-synthetic, and a synthetic fiber, and
the fiber having a surface not less than 15% of which is covered with the inorganic particles,
wherein the synthetic fiber is at least one selected from a group of the synthetic fibers consisting of a polyester, a polyamide, a polyolefin, polyurethane fiber, acrylic fiber, vinylon, vinylidene, polyvinyl chloride, glass fiber, and metal fiber.

2. The inorganic particle composite fiber according to claim 1 , wherein
The inorganic particles are bound to each other via the ionic polymer in such a manner as to form a layer containing the inorganic particles.

3. The inorganic particle composite fiber according to claim 1 , wherein
the ionic polymer has an electric charge opposite in polarity to an electric charge of the inorganic particles.

4. The inorganic particle composite fiber according to claim 1 , wherein
the ionic polymer is an anionic polymer or copolymer selected from a polymer or copolymer comprising an unsaturated carboxylic acid(s) and a polymer or copolymer comprising an unsaturated sulfonic acid(s).

5. The inorganic particle composite fiber according to claim 1 , wherein
the fiber has a surface on which a polar group is present.

6. The inorganic particle composite fiber according to claim 1 , wherein
the inorganic particles have an average primary particle diameter of not more than 3 μm.

7. The inorganic particle composite fiber according to claim 1 , wherein
the inorganic particles at least partially contain calcium, silicic acid, magnesium, barium, aluminum, titanium, copper, silver, zinc, platinum, iron, palladium, or zirconium.

8. The inorganic particle composite fiber according to claim 1 ,
wherein the inorganic particles are contained in a plurality of layers that are a stack of a layer containing inorganic particles and a layer containing an ionic polymer.

9. A method for producing an inorganic particle composite fiber according to claim 1 , the method comprising:
fixing the inorganic particles to the fiber by (i) immersing the fiber into a solution containing the ionic polymer or applying the fiber to the solution containing the ionic polymer; and
subsequently (ii) immersing the fiber into a dispersion containing the inorganic particles or applying the fiber to the dispersion containing the inorganic particles.

10. The method according to claim 5 , further comprising:
before immersing the fiber into the solution containing the ionic polymer, treating the fiber so that the fiber has a surface on which a polar group is present.

11. A method for producing an inorganic particle composite fiber recited in claim 1 , wherein
the inorganic particles are bound to each other via the ionic polymer in such a manner as to form a layer containing the inorganic particles,
the method comprising:
forming the layer containing the inorganic particles by (i) immersing the fiber alternately into a solution containing the ionic polymer or a dispersion containing the inorganic particles or (ii) applying the fiber alternately to the solution containing the ionic polymer or the dispersion containing the inorganic particles.

12. A method for producing an inorganic particle composite fiber according to claim 1 , the method comprising:
forming the plurality of layers by, before forming a layer containing the inorganic particles, (i) immersing the fiber into a solution containing a cationic polymer as a solution containing the ionic polymer and into a solution containing an anionic polymer as the solution containing the ionic polymer or (ii) applying the fiber to the solution containing the cationic polymer as the solution containing the ionic polymer and to the solution containing the anionic polymer as the solution containing the ionic polymer.

13. A molded article produced by molding an inorganic particle composite fiber according to claim 1 .

Assignees

• Jujo Paper Co Ltd

Inventors

• Fukuoka Moe
• Goto Shisei

Classifications

• D21H17/56

  Polyamines; Polyimines; Polyester-imides · CPC title

• D06M15/61

  Polyamines {polyimines} · CPC title

• D21H17/43

  Carboxyl groups or derivatives thereof · CPC title

• D06M15/267

  of unsaturated carboxylic esters having amino or quaternary ammonium groups · CPC title

• D06M11/44

  Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates · CPC title