Method for making laminated light-blocking decorative article

Patent metadata

Field	Value
Publication number	US-11549213-B2
Application number	US-201916720041-A
Country	US
Kind code	B2
Filing date	Dec 19, 2019
Priority date	Dec 19, 2019
Publication date	Jan 10, 2023
Grant date	Jan 10, 2023

Abstract

Laminated light-blocking decorative articles are prepared by applying an aqueous foamed opacifying composition to a non-woven fabric, drying, laminating a decorative fabric to the resulting dry foamed opacifying layer, and densifying that layer to have a thickness that is at least 20% less than before densifying. This operation can be carried out so that non-woven fabric, decorative fabric, and aqueous foamed opacifying composition are supplied in a single-pass, in-line operation to make any desired quantity of a laminated light-blocking decorative article. The applied aqueous foamed opacifying composition has 35%-70% solids and a foam density of 0.1-0.5 g/cm 3 . It is composed of (a) porous particles, (b) a binder material, (c) two or more additives comprising at least one foaming surfactant and at least one foam stabilizer, (d) an aqueous medium, and (e) at least 0.0001 weight % of an opacifying colorant that absorbs electromagnetic radiation having a wavelength of 380-800 nm.

First claim

The invention claimed is:

1. A method for making a laminated light-blocking decorative article in a single pass, the method comprising, in order:
A) providing a non-woven fabric having a face side and a back side;
B) applying an aqueous foamed opacifying composition to the back side of the non-woven fabric;
C) drying the applied aqueous foamed opacifying composition to provide a dry foamed opacifying layer having a dry coverage of less than or equal to 1000 g/m 2 and a light blocking value (LBV oc ) of at least 2;
D) providing a decorative fabric having a face side and a backside;
E) laminating the backside of the decorative fabric to the dry foamed opacifying layer; and
F) simultaneously with E) or subsequently to E), densifying only or densifying and curing the dry foamed opacifying layer so that the dry foamed opacifying layer has a thickness that is at least 20% less than its thickness before densifying,
to form a laminated light-blocking decorative article,
wherein the aqueous foamed opacifying composition has at least 35% and up to and including 70% solids and a foam density of at least 0.1 g/cm 3 and up to and including 0.5 g/cm 3 , and comprises:
(a) porous particles in an amount of at least 0.05 weight % and up to and including 20 weight %, each porous particle comprising a continuous polymeric phase and discrete pores dispersed within the continuous polymeric phase, the porous particles having a mode particle size of at least 2 μm and up to and including 50 μm and a porosity of at least 20 volume % and up to and including 70 volume %;
(b) a binder material in an amount of at least 15 weight % and up to and including 70 weight %,
(c) two or more additives in an amount of at least 0.0001 weight % and up to and including 30 weight %, the two or more additives comprising at least one foaming surfactant and at least one foam stabilizer,
(d) an aqueous medium, and
(e) an opacifying colorant in an amount of at least 0.0001 weight % and up to and including 0.5 weight %, the opacifying colorant being a different material from the (a) porous particles, (b) binder material, and (c) two or more additives, and which opacifying colorant absorbs electromagnetic radiation having a wavelength of at least 380 nm and up to and including 800 nm,
all amounts of (a) porous particles, (b) binder material, (c) two or more additives, and (e) opacifying colorant being based on the total weight of the aqueous foamed opacifying composition.

2. The method of claim 1 , wherein the dry foamed opacifying layer is subjected in the F) densifying step to a densification pressure of at least 5 psi (34.5 kPa) and up to and including 200 psi (1379 kPa) at a temperature of at least 20° C. and up to and including 150° C.

3. The method of claim 1 , wherein the E) laminating step includes curing the dry foamed opacifying layer.

4. The method of claim 1 , wherein the C) drying step includes curing the applied aqueous foamed opacifying composition.

5. The method of claim 1 , further comprising:
before the A) providing step, forming the aqueous foamed opacifying composition by aerating an aqueous foamable opacifying composition to have the foam density of at least 0.1 g/cm 3 and up to and including 0.5 g/cm 3 .

6. The method of claim 1 , wherein the non-woven fabric is a spunlace non-woven fabric.

7. The method of claim 1 , wherein the non-woven fabric has a basis weight of at least 0.5 oz/yd 2 (16.95 g/m 2 ).

8. The method of claim 1 , wherein the decorative fabric is a woven fabric having a repeating design pattern that is woven or embroidered into the decorative fabric.

9. The method of claim 1 , wherein the decorative fabric is a double cloth jacquard.

10. The method of claim 1 , wherein the laminated light-blocking decorative article is a blackout drapery exhibiting a stiffness of less than 15 mN, as measured by L&W bending force.

11. The method of claim 1 , wherein the laminated light-blocking decorative article is a blackout shade fabric exhibiting a stiffness as measured by L&W bending force of at least 15 mN.

12. The method of claim 1 , wherein either the non-woven fabric or the decorative fabric, or both the non-woven fabric and the decorative fabric, comprise an antimicrobial agent, a fire retardant, or a soil release agent, or any combination thereof.

13. The method of claim 1 , wherein the (e) opacifying colorant is present in the aqueous foamed opacifying composition in an amount of at least 0.001 weight % and up to and including 0.3 weight %, based on the total weight of the aqueous foamed opacifying composition.

14. The method of claim 1 , wherein the (e) opacifying colorant is a carbon black, a neutral or black pigment or dye other than a carbon black, or a combination of two or more of such materials.

15. The method of claim 1 , wherein the (e) opacifying colorant is located solely within the (a) porous particles.

16. The method of claim 1 , wherein the aqueous foamed opacifying composition further comprises an adhesive material.

17. The method of claim 1 , wherein the (b) binder material has a glass transition temperature (T g ) of less than 25° C.

18. The method of claim 1 , wherein the continuous polymeric phase of the (a) porous particles comprises one or more cellulose polymers, a polyester, a polystyrene, or a combination thereof.

19. The method of claim 1 , wherein the at least one foaming surfactant and the at least one foam stabilizer are independently one of the following compounds, or a mixture thereof: ammonium stearate, ammonium palmitate, sodium lauryl sulfate, ammonium lauryl sulfate, ammonium or sodium alkyl sulfosuccinate, disodium stearyl sulfosuccinate, diammonium n-octadecyl sulfosuccinamate, ethoxylated alcohols, a fatty acid soap, and a fatty acid condensation product with an alkylene oxide.

Assignees

• Eastman Kodak Co

Inventors

• Nair Mridula
• Herrick Diane Marie

Classifications

• D06N2209/147

  Stainproof, stain repellent · CPC title

• B32B2307/4026

  within the layer by addition of a colorant, e.g. pigments, dyes · CPC title

• B32B5/022

  Non-woven fabric · CPC title

• B32B2250/20

  All layers being fibrous or filamentary · CPC title

• D06N2209/0853

  Opaque · CPC title