Process for making cellulose fibre or film

Patent metadata

Field	Value
Publication number	US-11549200-B2
Application number	US-201816481071-A
Country	US
Kind code	B2
Filing date	Jan 30, 2018
Priority date	Jan 30, 2017
Publication date	Jan 10, 2023
Grant date	Jan 10, 2023

Abstract

According to an example aspect of the present invention, there is provided A process for making a cellulose fibre or film comprising the steps of dissolving pulp in an ionic liquid containing a cationic 1,5,7-triazabicyclo[4.4.0]dec-5-enium [TBDH]+ moiety and an anion selected from the group according to Formula a), Formula b) and Formula c), wherein each of R, R2, R3, R4, R5, R7, R8, R9 and R10 is H or an organyl radical and X− is selected from the group consisting of halides, pseudohalides, carboxylates, alkyl sulphite, alkyl sulphate, dialkylphosphite, dialkyl phosphate, dialkyl phosphonites and dialkyl phosphonates, to provide a spinning dope, extruding the spinning dope through a spinneret to form one or more filaments, and a step selected from the group consisting of spinning cellulose fibres from the solution, and extruding a cellulose film from the solution.

First claim

The invention claimed is:

1. A process for making cellulose filaments, fibres, and/or a film comprising the steps of:
dissolving pulp in an ionic liquid containing a cationic 1,5,7-triazabicyclo[4.4.0]dec-5-enium [TBDH]+ moiety and an anion selected from the group consisting of Formula a), Formula b), and Formula c),

wherein each of R, R 2 , R 3 , R 4 , R 5 , R 7 , R 8 , R 9 and R 10 is H or an organyl radical and X − is selected from the group consisting of halides, pseudohalides, carboxylates, alkyl sulphite, alkyl sulphate, dialkylphosphite, dialkyl phosphate, dialkyl phosphonites and dialkyl phosphonates, to provide a spinning dope, extruding the spinning dope through a spinneret to form the cellulose filaments, fibres, and/or film.

2. The process according to claim 1 , wherein at least one of R, R 2 , R 3 , R 4 , R 5 , R 7 , R 8 , R 9 and R 10 comprises an organyl radical, and wherein the organyl radical comprises an alkyl group.

3. The process according to claim 1 , wherein at least one of R, R 2 , R 3 , R 4 , R 5 , R 7 , R 8 , R 9 and R 10 comprises an organyl radical, and wherein the organyl radical comprises a polyether chain.

4. The process according to claim 1 , wherein at least one of R, R 2 , R 3 , R 4 , R 5 , R 7 , R 8 , R 9 and R 10 comprises an organyl radical, and wherein the organyl radical comprises a methyl group.

5. The process according to claim 1 , wherein the anion comprises a halide selected from the group consisting of fluoride, chloride, bromide, and iodide.

6. The process according to claim 1 , wherein the anion comprises a carboxylate selected from the group consisting of formate, acetate, propionate, and butyrate.

7. The process according to claim 1 , wherein the anion comprises a pseudohalide selected from the group consisting of cyanide, thiocyanide, and cyanate.

8. The process according to claim 1 , wherein the pulp comprises paper or dissolving pulp.

9. The process according to claim 1 , wherein the dissolving is done at a temperature in the range of 30° C. to 150° C.

10. The process according to claim 1 , wherein the dissolving provides a spinning dope having a zero shear viscosity in a range of 20000 to 60000 Pas.

11. The process according to claim 1 , wherein the dissolving provides a spinning dope having a cross over point of dynamic moduli being located between 0.2-2 sec −1 and 1500-7000 Pa.

12. The process according to claim 1 , wherein the spinning dope is extruded into an air gap during the extruding.

13. The process according to claim 1 , wherein the extruding is done at a temperature in a range of 60° C. to 100° C.

14. The process according to claim 1 , further comprising drawing the filament through a spin bath for regenerating cellulose, said spin bath containing an antisolvent or a mixture of the antisolvent and the ionic liquid.

15. The process according to claim 14 , wherein the antisolvent is water.

16. The process according to claim 1 , wherein the extruding forms a cellulose fibre having a dry tenacity of >35 cN/tex and a wet-to-dry tenacity of >0.70.

17. The process according to claim 1 , further comprising recycling the ionic liquid after the extruding.

18. The process of claim 1 , wherein the forming comprises a step selected from the group consisting of:
spinning cellulose fibres from the one or more filaments, and
extruding a cellulose film from the one or more filaments.

Assignees

• Aalto Univ Foundation Sr
• Helsingin Yliopisto

Inventors

• Sixta Herbert
• Hummel Michael
• Le Boulch Kadvaël
• Kilpeläinen Ilkka
• King Alistair W T
• Helminen Jussi
• Hellsten Sanna

Classifications

• B29C48/761

  the vented material being in liquid form · CPC title

• Y02P70/62

  related technologies for production or treatment of textile or flexible materials or products thereof, including footwear · CPC title

• C08J5/18

  Manufacture of films or sheets · CPC title

• C08J2301/02

  Cellulose; Modified cellulose · CPC title

• B29C48/10

  flexible, e.g. blown foils · CPC title