Film-forming powder, film forming method, and film-forming powder preparing method

Patent metadata

Field	Value
Publication number	US-11549185-B2
Application number	US-201916511283-A
Country	US
Kind code	B2
Filing date	Jul 15, 2019
Priority date	Jul 17, 2018
Publication date	Jan 10, 2023
Grant date	Jan 10, 2023

Abstract

A film-forming powder containing a rare earth oxyfluoride has an average particle size D50 of 0.6-15 μm, a total volume of ≤10 μm pores of 0.51-1.5 cm3/g as measured by mercury porosimetry, and a BET surface area of 3-50 m2/g is suitable for forming a dense film in high yields or deposition rates and high productivity. The film-forming powder having a greater pore volume can be prepared by forming a rare earth ammonium fluoride complex salt on surfaces of rare earth oxide particles to provide precursor particles, and heat treating the precursor particles at a temperature of 350 to 700° C.

First claim

The invention claimed is:

1. A film-forming powder comprising a rare earth oxyfluoride, and having an average particle size D50 of 0.6 to 15 μm, a total volume of pores having a diameter of up to 10 μm in the range of 0.615 to 1.5 cm 3 /g as measured by mercury porosimetry, and a specific surface area of 3 to 50 m 2 /g as measured by the BET method.

2. The powder of claim 1 wherein the fraction of particles having a particle size of up to 0.3 μm is up to 0.5% by volume.

3. The powder of claim 1 , having an aspect ratio of 1.2 to 3.

4. The powder of claim 1 , having a dispersity index (b80) of up to 1.6, the dispersity index (b80) being determined according to the formula (1):
(D90-D10)/D50  (1)

wherein D10, D50 and D90 are cumulative 10%, 50% and 90% diameters in volume basis particle size distribution, respectively.

5. The powder of claim 1 wherein the rare earth oxyfluoride is yttrium oxyfluoride.

6. A method for forming a film, comprising the step of depositing the film-forming powder of claim 1 on a substrate by the aerosol deposition method.

Assignees

• Shinetsu Chemical Co

Inventors

• Kimura Yuji
• Takai Yasushi
• Nakamura Shigeyuki

Classifications

• C01P2004/51

  Particles with a specific particle size distribution · CPC title

• C23C24/04 Primary

  Impact or kinetic deposition of particles · CPC title

• C01P2006/12

  Surface area · CPC title

• C01P2004/62

  Submicrometer sized, i.e. from 0.1-1 micrometer · CPC title

• C01P2004/03

  obtained by SEM · CPC title