Apparatus and method for syngas bio-methanation

Patent metadata

Field	Value
Publication number	US-11549088-B2
Application number	US-201816624264-A
Country	US
Kind code	B2
Filing date	Jun 7, 2018
Priority date	Jun 23, 2017
Publication date	Jan 10, 2023
Grant date	Jan 10, 2023

Abstract

A waste treatment, pyrolysis and gasification and concerns an apparatus for syngas bio-methanation include a unit for pyrolysis/gasification receiving organic material, the unit for pyrolysis/gasification generating syngas, comprising at least one membrane reactor inside a liquid bath comprising at least one bacteria population, the membrane reactor comprising at least one hollow fiber in contact with the liquid bath, around which a biofilm is formed and into which the syngas from the unit for pyrolysis/gasification flows, so as to convert the syngas into methane. A method for bio-methanation of syngas comprising a step of providing syngas from a unit for pyrolysis/gasification to a membrane reactor inside a liquid bath comprising at least one suitable bacteria population, the membrane reactor comprising at least one hollow fiber in contact with the liquid bath, around which a biofilm is formed and into which the output syngas of the unit for pyrolysis flows, so as to convert the syngas into methane.

First claim

The invention claimed is:

1. An apparatus for syngas bio-methanation comprising:
a unit for pyrolysis/gasification configured to receive organic material, the unit for pyrolysis/gasification being configured to generate syngas;
at least one membrane reactor configured to be placed inside a liquid bath, the liquid bath comprising at least one bacteria population, the at least one membrane reactor comprises at least one hollow fiber arranged in such a way that, when the membrane reactor is in contact with the liquid bath, a biofilm is formed around the at least one hollow fiber and so that the syngas generated at the unit for pyrolysis/gasification flows into the at least one hollow fiber, so as to convert the syngas into methane; and
an anaerobic digester configured to be fed with organic material and to generate biogas comprising methane and a digestate,
wherein an inlet of the digester is connected in series to an outlet of the at least one membrane reactor, and
wherein the at least one membrane reactor is outside of the digester.

2. The apparatus according to claim 1 , further comprising a dewatering unit configured to dewater the digestate from the anaerobic digester so as to lead to a solid cake and a liquid centrate.

3. The apparatus according to claim 2 , wherein the apparatus is configured to inject at least a part of the liquid centrate into the liquid bath of the at least one membrane reactor.

4. The apparatus according to claim 2 , wherein the apparatus is configured to feed the solid cake to the unit for pyrolysis/gasification or to a second unit for pyrolysis/gasification.

5. The apparatus according to claim 1 , wherein the apparatus is configured to add a liquid portion of an outlet stream from the liquid bath of the at least one membrane reactor to the organic material configured to feed the anaerobic digester.

6. The apparatus according to claim 1 , further comprising a plurality of membrane reactors, wherein the plurality of membrane reactors are positioned in derivation in relation to each other.

7. The apparatus according to claim 1 , wherein the at least one population of bacteria is homoacetogenic bacteria and/or acetogenic methanogens or hydrogenotrophic methanogens and/or carboxydotrophic acetogens and acetogenic methanogens.

8. A method for syngas bio-methanation, comprising:
a step of providing syngas from a unit for pyrolysis/gasification receiving organic material to at least one membrane reactor inside a liquid bath comprising at least one bacteria population, said at least one membrane reactor comprising at least one hollow fiber in contact with the liquid bath, around which a biofilm is formed and into which the syngas from the unit for pyrolysis/gasification flows, so as to convert the syngas into methane, and
sequentially, a step of feeding an anaerobic digester at an inlet of the anaerobic digester-with organic material and generating biogas comprising methane and a digestate with an outlet stream of the at least one membrane reactor.

9. The method according to claim 8 , further comprising a step of feeding the digestate from the anaerobic digester into a dewatering unit configured to dewater the digestate from the anaerobic digester leading to a solid cake and a liquid centrate.

10. The method according to claim 9 , further comprising a step of injecting at least a part of the liquid centrate into the liquid bath of the at least one membrane reactor.

11. The method according to claim 9 , further comprising a step of feeding the solid cake to the unit for pyrolysis/gasification or to a second unit for pyrolysis/gasification.

12. The method according to claim 8 , further comprising a step of adding a liquid portion of an outlet stream from the liquid bath of the at least one membrane reactor to the organic material feeding the anaerobic digester.

13. The method according to claim 8 , wherein the at least one population of bacteria is homoacetogenic bacteria and/or acetogenic methanogens or hydrogenotrophic methanogens and/or carboxydotrophic acetogens and acetogenic methanogens.

14. The method according to claim 8 , wherein the at least one membrane reactor is outside of the digester.

Assignees

• Suez Groupe
• Suez Int

Inventors

• Camacho Patricia
• Haddad Mathieu

Classifications

• Y02E50/30

  Fuel from waste, e.g. synthetic alcohol or diesel · CPC title

• C12P5/023 Primary

  Methane · CPC title

• C10J2300/1662

  to methane · CPC title

• C12M29/16

  Hollow fibers (hollow fiber modules in general B01D63/02) · CPC title

• C02F11/04

  Anaerobic treatment; Production of methane by such processes · CPC title