Polyester film and method for reproducing polyester container using same

Patent metadata

Field	Value
Publication number	US-11548996-B2
Application number	US-201916614720-A
Country	US
Kind code	B2
Filing date	Apr 30, 2019
Priority date	Apr 30, 2018
Publication date	Jan 10, 2023
Grant date	Jan 10, 2023

Abstract

The embodiments relate to a polyester film, which comprises a copolymerized polyester resin comprising a diol component and a dicarboxylic acid component and has a heat shrinkage rate of 30% or more in the main shrinkage direction upon thermal treatment at a temperature of 80° C. for 10 seconds and a melting point of 170° C. or higher as measured by differential scanning calorimetry, which not only solve the environmental problems by improving the recyclability of the polyester container, but also are capable of enhancing the yield and productivity, and a process for regenerating a polyester container using the same.

First claim

The invention claimed is:

1. A polyester film, which comprises a copolymerized polyester resin comprising a diol component and a dicarboxylic acid component and
has a heat shrinkage rate of 30% or more in the main shrinkage direction upon thermal treatment at a temperature of 80° C. for 10 seconds and
a melting point of 170° C. or higher as measured by differential scanning calorimetry.

2. The polyester film of claim 1 , wherein the diol component is at least one selected from the group consisting of ethylene glycol, diethylene glycol, neopentyl glycol, and cyclohexanedimethanol.

3. The polyester film of claim 1 , wherein the copolymerized polyester resin comprises ethylene glycol in an amount of 55 to 94% by mole and diethylene glycol in an amount of 1 to 20% by mole based on the total number of moles of the diol component.

4. The polyester film of claim 1 , wherein the copolymerized polyester resin comprises neopentyl glycol in an amount of 5 to 35% by mole based on the total number of moles of the diol component.

5. The polyester film of claim 1 , wherein the crystallization temperature of the polyester film is not measured or is 70° C. to 95° C. by differential scanning calorimetry.

6. The polyester film of claim 5 , wherein the heat of crystallization of the polyester film at the crystallization temperature is not measured or is 0.01 to 50 J/g.

7. The polyester film of claim 1 , which has a heat shrinkage rate of 30% or more in a first direction upon thermal treatment at a temperature of 100° C. for 10 seconds,
a heat shrinkage rate of 50% or more in the first direction upon thermal treatment at a temperature of 90° C. for 10 seconds, and
a heat shrinkage rate of 5% to 55% in the first direction upon thermal treatment at a temperature of 70° C. for 10 seconds.

8. The polyester film of claim 1 , wherein the rate of increase in the heat shrinkage rate in a first direction in the temperature range of 0.35×Tm° C. to 0.40×Tm° C. is 2.5%/° C. to 4.0%/° C., and
the rate of increase in the heat shrinkage rate in the first direction in the temperature range of 0.45×Tm° C. to 0.50×Tm° C. is 0.1%/° C. to 1.0%/° C.

9. A polyester film, which comprises a copolymerized polyester resin comprising a diol component and a dicarboxylic acid component and has a haze of 50% or less when immersed in a 1% aqueous solution of NaOH for 15 minutes.

10. A polyester film, which comprises a first layer comprising a copolymerized polyester resin comprising a diol component and a dicarboxylic acid component and a second layer comprising a resin having a glass transition temperature (Tg) of 70° C. or higher.

11. The polyester film of claim 10 , wherein the second layer comprises at least one resin selected from the group consisting of polyethylene terephthalate (PET), polycyclohexylene dimethylene terephthalate (PCT), polymethylmethacrylate (PMMA), copolymerized polyethylene terephthalate (co-PET), polyethylene naphthalate (PEN), polyethersulfone (PES), polycarbonate (PC), polystyrene (PS), polyamide (PA), and polyimide (PI).

12. The polyester film of claim 10 , wherein the thicknesses of the first layer and the second layer are 30 to 100 nm, respectively.

13. The polyester film of claim 10 , which is composed of 2 to 100 layers by laminating the first layer and the second layer.

14. The polyester film of claim 10 , which is composed 3 to 100 layers by laminating the first layer and the second layer, wherein the second layer is located in the outermost layers.

15. A process for regenerating a polyester container, which comprises preparing the polyester container provided with the polyester film according to claim 1 ;
crushing the container provided with the polyester film to obtain flakes; and
thermally treating the flakes to produce regenerated polyester chips,
wherein when the flakes are thermally treated at a temperature of 200° C. to 220° C. for 60 minutes to 120 minutes, the clumping fraction is 8% or less, and
the flakes comprise first flakes obtained by crushing the container and second flakes obtained by crushing the polyester film.

16. The process for regenerating a polyester container of claim 15 , wherein the particle size of the first flakes is 0.1 to 20 mm, and the particle size of the second flakes is 0.1 to 20 mm.

17. The process for regenerating a polyester container of claim 15 , wherein the container comprises polyethylene terephthalate in an amount of 90% by weight or more.

18. Regenerated polyester chips prepared according to the regeneration process of claim 15 .

19. The regenerated polyester chips of claim 18 , which comprise first flakes that comprise polyethylene terephthalate and second flakes that comprise a copolymerized polyester resin.

20. The regenerated polyester chips of claim 18 , which have an intrinsic viscosity (IV) of 0.60 dl/g or more.

Assignees

• Skc Co Ltd
• Skc Inc

Inventors

• Shin Dae Yong
• Kim Yong Deuk
• Lee Jung Kyu
• Son Jaehyong
• Jung Eugene
• Kim Chul Kyu
• Yang Joo Ho

Classifications

• C08J5/18

  Manufacture of films or sheets · CPC title

• B29C61/02

  Thermal shrinking · CPC title

• C08G2390/00

  Containers · CPC title

• Y02W30/62

  Plastics recycling; Rubber recycling · CPC title

• B32B27/36

  comprising polyesters · CPC title