Openly porous acoustic foam, process for manufacture and uses thereof

Patent metadata

Field	Value
Publication number	US-11548994-B2
Application number	US-201716466127-A
Country	US
Kind code	B2
Filing date	Dec 1, 2017
Priority date	Dec 2, 2016
Publication date	Jan 10, 2023
Grant date	Jan 10, 2023

Abstract

There is provided a method of manufacturing an openly and highly porous thermoset foam, the method comprising the steps of mixing a thermosetting resin and crystals to form a mixture; applying pressure to the mixture to expel excess thermosetting resin, thereby producing a network of crystals touching each other with the thermosetting resin filling the interstices between the crystals of said network; curing the thermosetting resin in the mixture under pressure to produce a cured material; and contacting the cured material with a solvent for the crystals, thereby leaching the crystals out of the cured material, thereby obtaining said openly and highly porous thermoset foam. There is also provided a thermoset foam made of a thermoset and having a porosity of at least about 70%, wherein more than about 75% of the pores in the foam are connected to a neighboring pore.

First claim

The invention claimed is:

1. A method of manufacturing an openly porous thermoset foam, the method comprising the steps of:
i) mixing a thermosetting resin and crystals to form a mixture;
ii) applying pressure to the mixture to expel excess thermosetting resin, thereby producing a network of crystals touching each other with the thermosetting resin in the interstices between the crystals of said network;
iii) curing the thermosetting resin in the mixture under pressure to produce a cured material; and
iv) contacting the cured material with a solvent for the crystals, thereby leaching the crystals out of the cured material and producing said openly porous thermoset foam.

2. The method according to claim 1 , wherein the thermosetting resin is a thermosetting plastic resin, is in the form of a solid powder, and/or is a bi-component resin.

3. The method according to claim 1 , wherein the crystals are water-soluble and the solvent is water or an aqueous solution.

4. The method according to claim 1 , wherein the crystals are present in a crystal:thermosetting resin weight ratio of:
about 75:25, about 80:20, about 85:15, about 95:5, or about 90:10.

5. The method according to claim 1 further comprising heating the mixture before step ii) to lower the viscosity of the thermosetting resin.

6. The method according to claim 1 wherein the applied pressure is between about 15 MPa.

7. The method according to claim 1 , wherein the thermosetting resin is a chemically-curable resin and in the curing step, the thermosetting resin is cured by waiting and thus allowing curing to occur.

8. The method according to claim 1 , wherein the thermosetting resin is a heat-curable resin and in the curing step, the thermosetting resin is cured by heating the mixture to the curing temperature of the thermosetting resin or above.

9. The method according to claim 1 , wherein the thermosetting resin is a radiation-curable resin and in the curing step, the thermosetting resin is cured by exposing the thermosetting resin to curing radiation.

10. The method according to claim 1 , wherein steps ii and iii partly overlap.

11. The method according to claim 1 , wherein steps ii and iii are carried out consecutively.

12. The method according to claim 1 , wherein the solvent with which the cured material is contacted is heated.

13. The method according to claim 1 , wherein step iii) comprises;
iii′) completely or at least partially curing the thermosetting resin under pressure to produce an at least partially cured material in which the thermosetting resin has at least reached its gel point,
iii″) producing an additional at least partially cured material by;
a) placing an additional mixture as defined in claim 1 adjacent to the at least partially cured material;
b) applying pressure to the additional mixture to expel excess thermosetting resin of the additional mixture, leaving a network of crystals in the additional mixture touching each other with the thermosetting resin of the additional mixture in the interstices of said network;
c) completely or at least partially curing the thermosetting resin in the additional mixture, under pressure, to produce an additional at least partially cured material in which the thermosetting resin of the additional mixture has at least reached its gel point;
iii″′) optionally repeating step iii″) one or more times, each additional at least partially cured material produced in each step iii″′) being formed adjacent to a previously formed at least partially cured material; and iii″″) if curing was partial in step iii′) and step iii″ c), completing curing the thermosetting resin of the mixture and the additional mixture(s).

14. The method according to claim 1 , further comprising tailoring the size and shape of pores created by leaching the crystals out of the cured material by varying the size and shape of the crystals.

Assignees

• Safran

Inventors

• Fotsing Edith Roland
• Dubourg Arnaud
• Ross Annie

Classifications

• C08J2300/24

  Thermosetting resins · CPC title

• C08J2205/05

  Open cells, i.e. more than 50% of the pores are open · CPC title

• C08J9/008

  Nanoparticles · CPC title

• C08J2333/14

  of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen · CPC title

• C08J9/26 Primary

  by elimination of a solid phase from a macromolecular composition or article, e.g. leaching out · CPC title