Heterocyclic compounds as pesticides

Patent metadata

Field	Value
Publication number	US-11548854-B2
Application number	US-202017093130-A
Country	US
Kind code	B2
Filing date	Nov 9, 2020
Priority date	Oct 2, 2012
Publication date	Jan 10, 2023
Grant date	Jan 10, 2023

Abstract

The present application relates to the use of heterocyclic compounds for controlling animal pests including arthropods, insects and nematodes, to novel heterocyclic compounds, to processes for their preparation and to intermediates for preparing the heterocyclic compounds.

First claim

The invention claimed is:

1. A compound of formula (I)

in which
A represents

in which the broken line represents the bond to Q and in which A furthermore carries m substituents R2,

Q represents

in which the nitrogen is attached to ring A and the arrow represents the bond to D and

D represents the radical of the formula

in which the nitrogen is attached to Q and the arrow represents the bond to B,

B represents a radical from the group consisting of

in which the broken line represents the bond to D and in which B furthermore carries n substituents R7,

Z represents oxygen or sulphur,
R2 represents a radical selected from the group consisting of halogen, cyano, nitro, amino, hydroxy, C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, C 3 -C 6 -cycloalkyl, C 1 -C 6 -alkoxy, C 3 -C 6 -alkenyloxy, C 3 -C 6 -alkynyloxy, C 3 -C 6 -cycloalkyloxy, C 1 -C 6 -alkylcarbonyloxy, C 2 -C 6 -alkenylcarbonyloxy, C 2 -C 6 -alkynylcarbonyloxy, C 3 -C 6 -cycloalkylcarbonyloxy, C 1 -C 6 -alkoxycarbonyloxy, C 1 -C 6 -alkylsulphonyloxy, C 1 -C 6 -alkylamino, di-(C 1 -C 6 -alkyl)-amino, C 3 -C 6 -alkenylamino, C 3 -C 6 -alkynylamino, C 3 -C 6 -cycloalkylamino, C 1 -C 6 -alkylcarbonylamino, C 2 -C 6 -alkenylcarbonylamino, C 2 -C 6 -alkynylcarbonylamino, C 3 -C 6 -cycloalkylcarbonylamino, C 1 -C 6 -alkoxycarbonylamino, C 1 -C 6 -alkylsulphonylamino, C 1 -C 6 -alkylthio, C 3 -C 6 -alkenylthio, C 3 -C 6 -alkynylthio, C 3 -C 6 -cycloalkylthio, C 1 -C 6 -alkylsulphinyl, C 1 -C 6 -alkylsulphonyl, C 1 -C 6 -alkylcarbonyl, C 1 -C 6 -alkoxyimino-C 1 -C 6 -alkyl, C 1 -C 6 -alkoxycarbonyl, aminocarbonyl, C 1 -C 6 -alkylaminocarbonyl, di-(C 1 -C 6 -alkyl)-aminocarbonyl, aminothiocarbonyl, C 1 -C 6 -alkylaminosulphonyl, C 1 -C 6 -alkylsulphonylamino, C 1 -C 6 -alkylcarbonylamino, C 1 -C 6 -alkylthiocarbonylamino, C 4 -C 12 -bicycloalkyl, aryl, aryloxy, arylamino, arylthio, heteroaryl, heteroaryloxy, heteroarylamino and heteroarylthio, each of which is optionally substituted by one or more identical or different substituents, where the substituents independently of one another are selected from the group consisting of halogen, cyano, nitro, hydroxy, amino, C 1 -C 6 -alkyl, C 1 -C 6 -alkoxy, C 3 -C 6 -cycloalkyl, C 1 -C 6 -haloalkoxy, and C 1 -C 6 -alkylthio, aryl, aryloxy, arylthio, heteroaryl, heteroaryloxy and heteroarylthio,
R3 represents a radical selected from the group consisting of hydrogen, halogen, cyano, nitro, amino, hydroxy, C 1 -C 6 -alkyl, C 1 -C 6 -alkoxy, C 1 -C 6 -haloalkyl and C 1 -C 6 -haloalkoxy,
R4 represents a radical selected from the group consisting of hydrogen, halogen, amino, hydroxy, C 1 -C 6 -alkyl, C 1 -C 6 -alkoxy, C 1 -C 6 -haloalkyl and C 1 -C 6 -haloalkoxy,
R5 represents a radical selected from the group consisting of hydrogen, C 1 -C 6 -alkyl, C 3 -C 6 -cycloalkyl, C 1 -C 6 -haloalkyl, C 2 -C 6 -alkenyl, C 3 -C 6 -alkynyl, C 3 -C 6 -cycloalkyl-C 1 -C 6 -alkyl, cyano-C 1 -C 6 -alkyl, C 1 -C 6 -alkylcarbonyl, C 2 -C 6 -alkenylcarbonyl, C 1 -C 6 -haloalkylcarbonyl, C 2 -C 6 -haloalkenylcarbonyl, C 1 -C 6 -alkoxy-C 1 -C 6 -alkyl, C 1 -C 6 -alkoxycarbonyl, C 1 -C 6 -alkylsulphonyl and C 1 -C 6 -haloalkylsulphonyl or represents C(═O)—B,
R6 represents a radical selected from the group consisting of hydrogen (only in the radicals B-33 and B-36), halogen, cyano, nitro, amino, hydroxy, carboxyl, C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, C 3 -C 6 -cycloalkyl, C 1 -C 6 -alkoxy, C 3 -C 6 -alkenyloxy, C 3 -C 6 -alkynyloxy, C 3 -C 6 -cycloalkyloxy, C 1 -C 6 -alkylcarbonyloxy, C 2 -C 6 -alkenylcarbonyloxy, C 2 -C 6 -alkynylcarbonyloxy, C 3 -C 6 -cycloalkylcarbonyloxy, C 1 -C 6 -alkoxycarbonyloxy, C 1 -C 6 -alkylsulphonyloxy, C 3 -C 6 -alkenylamino, C 3 -C 6 -alkynylamino, C 3 -C 6 -cycloalkylamino, C 1 -C 6 -alkylcarbonylamino, C 2 -C 6 -alkenylcarbonylamino, C 2 -C 6 -alkynylcarbonylamino, C 3 -C 6 -cycloalkylcarbonylamino, C 1 -C 6 -alkoxycarbonylamino, C 1 -C 6 -alkylsulphonylamino, C 1 -C 6 -alkylthio, C 3 -C 6 -alkenylthio, C 3 -C 6 -alkynylthio, C 3 -C 6 -cycloalkylthio, C 1 -C 6 -alkylsulphinyl, C 1 -C 6 -alkylsulphonyl, C 1 -C 6 -alkylcarbonyl, C 1 -C 6 -alkoxyimino-C 1 -C 6 -alkyl, C 1 -C 6 -alkoxycarbonyl, aminocarbonyl, C 1 -C 6 -alkylaminocarbonyl, di-(C 1 -C 6 -alkyl)-aminocarbonyl, aminothiocarbonyl, C 1 -C 6 -alkylaminosulphonyl, C 1 -C 6 -alkylsulphonylamino, C 1 -C 6 -alkylcarbonyl amino, C 1 -C 6 -haloalkylcarbonylamino, C 1 -C 6 -alkylthiocarbonylamino, C 4 -C 12 -bicycloalkyl, aryl, aryloxy, heteroaryl, and heteroaryloxy, each of which is optionally substituted by one or more identical or different substituents, where the substituents independently of one another are selected from the group consisting of halogen, cyano, nitro, hydroxy, amino, C 1 -C 6 -alkyl, C 1 -C 6 -alkoxy, C 3 -C 6 -cycloalkyl, C 1 -C 6 -haloalkoxy and C 1 -C 6 -alkylthio,
R7 represents a radical selected from the group consisting of halogen, nitro, cyano, amino, hydroxy, C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, C 3 -C 6 -cycloalkyl, C 1 -C 6 -alkoxy, C 3 -C 6 -alkenyloxy, C 3 -C 6 -alkynyloxy, C 3 -C 6 -cycloalkyloxy, C 1 -C 6 -alkylcarbonyloxy, C 2 -C 6 -alkenylcarbonyloxy, C 2 -C 6 -alkynylcarbonyloxy, C 3 -C 6 -cycloalkylcarbonyloxy, C 1 -C 6 -alkoxycarbonyloxy, C 1 -C 6 -alkylsulphonyloxy, C 1 -C 6 -alkylcarbonylamino, C 2 -C 6 -alkenylcarbonylamino, C 2 -C 6 -alkynylcarbonylamino, C 3 -C 6 -cycloalkylcarbonylamino, C 1 -C 6 -alkoxycarbonylamino, C 1 -C 6 -alkylsulphonylamino, C 3 -C 6 -alkenylamino, C 3 -C 6 -alkynylamino, C 1 -C 6 -alkylthio, C 3 -C 6 -alkenylthio, C 3 -C 6 -alkynylthio, C 3 -C 6 -cycloalkylthio, C 1 -C 6 -alkylsulphinyl, C 1 -C 6 -alkylsulphonyl, C 1 -C 6 -alkylcarbonyl, C 1 -C 6 -alkoxyimino-C 1 -C 6 -alkyl, C 1 -C 6 -alkoxycarbonyl, aminocarbonyl, C 1 -C 6 -alkylaminocarbonyl, di-(C 1 -C 6 -alkyl)-aminocarbonyl, aminothiocarbonyl, C 1 -C 6 -alkylaminosulphonyl, C 1 -C 6 -alkylthiocarbonylamino, aryl, aryloxy, heteroaryl, heteroaryloxy, C 4 -C 12 -bicycloalkyl, each of which is optionally substituted by one or more identical or different substituents, where the substituents independently of one another are selected from the group consisting of halogen, cyano, nitro, hydroxy, amino, C 1 -C 6 -alkyl, C 1 -C 6 -alkoxy, C 3 -C 6 -cycloalkyl, C 1 -C 6 -haloalkoxy and C 1 -C 6 -alkylthio,
R9 represents a radical selected from the group consisting of hydrogen, C 1 -C 6 -alkyl, C 3 -C 6 -cycloalkyl, haloalkyl, C 3 -C 6 -alkenyl, C 3 -C 6 -alkynyl, C 3 -C 6 -cycloalkyl-C 1 -C 6 -alkyl, cyano-C 1 -C 6 -alkyl, C 1 -C 6 -alkylcarbonyl, C 2 -C 6 -alkenylcarbonyl, C 1 -C 6 -haloalkylcarbonyl, C 2 -C 6 -haloalkenylcarbonyl, C 1 -C 6 -alkoxy-C 1 -C 6 -alkyl, C 1 -C 6 -alkoxycarbonyl, C 1 -C 6 -alkylsulphonyl and C 1 -C 6 -haloalkylsulphonyl,
m represents a number selected from the group consisting of 0, 1, 2 and 3, where for m>1 the radicals R2 may be identical or different and
n represents a number selected from the group consisting of 0, 1, 2 and 3, where for n>1 the radicals

Assignees

• Bayer Cropscience Ag

Inventors

• Heilmann Eike Kevin
• Greul Joerg
• Trautwein Axel
• Schwarz Hans-Georg
• Adelt Isabelle
• Andree Roland
• Luemmen Peter
• Hink Maike
• Adamczewski Martin
• Drewes Mark
• Becker Angela
• Voerste Arnd
• Goergens Ulrich
• Ilg Kerstin
• Jansen Johannes-Rudolf
• Portz Daniela

Classifications

• A01N43/60

  1,4-Diazines; Hydrogenated 1,4-diazines · CPC title

• A01N43/58

  1,2-Diazines; Hydrogenated 1,2-diazines · CPC title

• A61P33/02

  Antiprotozoals, e.g. for leishmaniasis, trichomoniasis, toxoplasmosis · CPC title

• A01N43/56

  1,2-Diazoles; Hydrogenated 1,2-diazoles · CPC title

• C07D231/06

  having one double bond between ring members or between a ring member and a non-ring member · CPC title