Compressible foam electrode

Patent metadata

Field	Value
Publication number	US-11548798-B2
Application number	US-201916392461-A
Country	US
Kind code	B2
Filing date	Apr 23, 2019
Priority date	Apr 23, 2019
Publication date	Jan 10, 2023
Grant date	Jan 10, 2023

Abstract

A foam electrode comprising surface treatment by the steps of: 1) impregnating soft compressible polymeric foams with a conductive coating via sequential infiltration synthesis and 2) functionalizing the chemically altered voids with an ultrathin redox coating to enhance capacitive deionization (CDI). The redox coating will allow treated foam to absorb ions under the application of a bias, and mechanical compression/decompression. The CDI apparatus uses the void volume of the foam in the uncompressed state to flow liquids through it while the compressed state is used to enhance desalination by limiting the diffusion pathways for the ions to find an adsorption surface.

First claim

What is claimed is:

1. A capacitive deionization apparatus comprising:
a first foam electrode;
a second foam electrode;
a compressible container having the first foam electrode and the second foam electrode disposed therein;
a separator positioned between the first foam electrode and the second foam electrode;
a water feed inlet and an effluent water outlet associated with the separator; and
a compression mechanism for controllably compressing at least one of the first foam electrode and the second foam electrode.

2. The apparatus of claim 1 , further comprising a first conductive plate between the first foam electrode and the housing and a second conductive plate between the second foam electrode and the housing.

3. The apparatus of claim 1 , wherein the first foam electrode comprises a plurality of first electrodes.

4. The apparatus of claim 3 wherein the second foam electrode comprises a plurality of second electrodes.

5. The apparatus of claim 1 , wherein the compression mechanism comprises a first roller and a second roller opposed to the first roller.

6. The apparatus of claim 1 wherein the compression mechanism comprises a first piston associated with the first foam electrode and a second piston associated with the second foam electrode.

7. The apparatus of claim 1 , further comprising a conductive carbon integrated into at least one of the first foam electrode and the second foam electrode.

8. The apparatus of claim 7 wherein the conductive carbon forms a conductive network with binders and the first foam electrode.

9. The apparatus of claim 1 wherein the separator is configured for the flow of liquid from the water feed inlet to the water feed outlet, the separator in fluid communication with the first foam electrode and the second foam electrode, with the first foam electrode and the second foam electrode being electrically isolated from each other.

10. A capacitive deionization apparatus comprising:
a first plurality of foam electrodes;
a second plurality of foam electrodes;
a separator positioned between the first plurality of foam electrodes and the second plurality of foam electrodes;
a water feed inlet and an effluent water outlet associated with the separator; and
a compression mechanism for controllably compressing at least one of the plurality of foam electrodes and the second plurality of foam electrodes.

11. The apparatus of claim 10 , further comprising a compressible housing disposed about the first plurality of foam electrodes and the second plurality of foam electrodes.

12. The apparatus of claim 10 , further comprising a first conductive plate between the first plurality of foam electrodes and the housing and a second conductive plate between the second plurality of foam electrodes and housing.

13. The apparatus of claim 10 , wherein the compression mechanism comprises a first roller and a second roller opposed to the first roller.

14. The apparatus of claim 10 wherein the compression mechanism comprises a first piston associated with the first plurality of foam electrodes and a second piston associated with the second plurality of foam electrodes.

15. The apparatus of claim 10 , further comprising a conductive carbon integrated into at least one of the first plurality of foam electrodes and the second plurality of foam electrodes.

16. The apparatus of claim 15 wherein the conductive carbon forms a conductive network with binders and the first plurality of foam electrodes.

17. The apparatus of claim 10 wherein the separator is configured for the flow of liquid from the water feed inlet to the water feed outlet, the separator in fluid communication with the first plurality of foam electrodes and the plurality of foam electrodes, with the first plurality of foam electrodes and the second plurality of foam electrodes being electrically isolated from each other.

18. A capacitive deionization apparatus comprising:
a first foam electrode;
a second foam electrode;
a separator positioned between the first foam electrode and the second foam electrode;
a water feed inlet and an effluent water outlet associated with the separator; and
a compression device selected from fa) a first roller and a second roller opposed to the first roller, and (b) a first piston associated with the first foam electrode and a second piston associated with the second foam electrode.

19. The apparatus of claim 18 , further comprising a conductive carbon integrated into at least one of the first foam electrode and the second foam electrode.

Assignees

• Uchicago Argonne Llc

Inventors

• Young Matthias John
• Barry Edward F
• Elam Jeffrey W

Classifications

• C25B11/031

  Porous electrodes · CPC title

• C02F2001/46161

  Porous electrodes · CPC title

• C02F2103/08

  Seawater, e.g. for desalination · CPC title

• C02F1/4691 Primary

  Capacitive deionisation · CPC title

• C25B11/073

  characterised by the electrocatalyst material · CPC title