Process to treat metal or mineral ores and collector composition therefor

Patent metadata

Field	Value
Publication number	US-11548012-B2
Application number	US-201816756875-A
Country	US
Kind code	B2
Filing date	Oct 16, 2018
Priority date	Oct 20, 2017
Publication date	Jan 10, 2023
Grant date	Jan 10, 2023

Abstract

A process to treat metal or mineral ores is disclosed. The metal or mineral ore is a metallic sulphide ore including copper, gold, platinum, silver, nickel, molybdenum, arsenic sulphides, cobalt, zinc, lead, tin, antimony, or combinations thereof with a collector composition including a dimeric fatty nitrile. The dimeric fatty nitrile is prepared by a process including reacting a dimer fatty acid with ammonia at a temperature between about 200° C. and about 400° C. to form a dimeric amide and removing water from the dimeric amide to form the dimeric nitrile. The present disclosure also provides a collector composition containing the dimeric fatty nitrile and at least one further collector or frother compound.

First claim

What is claimed is:

1. A method to treat metal or mineral ores, wherein the metal or mineral ore is a metallic sulphide ore including copper, gold, platinum, silver, nickel, molybdenum, arsenic, cobalt, zinc, lead, tin, antimony, or combinations thereof with a collector composition comprising a dimeric nitrile, wherein the dimeric nitrile is obtainable by a process comprising:
reacting a dimer fatty acid with ammonia at a temperature between about 200° C. and about 400° C. to form a dimeric amide; and
removing water from the dimeric amide to form the dimeric nitrile.

2. The method of claim 1 wherein the dimeric nitrile is obtainable by reacting the dimer fatty acid with the ammonia at a pressure between about 0 kPa and about 507 kPa.

3. The method of claim 2 wherein the dimeric nitrile is obtainable by adding the ammonia to a reaction vessel containing the dimer fatty acid at a rate of about 0.1 moles per hour to about 5 moles per hour.

4. The method of claim 2 wherein the dimeric nitrile is obtainable by reacting the dimer fatty acid with the ammonia in the presence of a metal oxide catalyst.

5. The method of claim 1 wherein the dimeric nitrile is obtainable by adding the ammonia to a reaction vessel containing the dimer fatty acid at a rate of about 0.1 moles per hour to about 5 moles per hour.

6. The method of claim 1 wherein the dimeric nitrile is obtainable by reacting the dimer fatty acid with the ammonia in the presence of a metal oxide catalyst.

7. The method of claim 6 wherein the dimeric nitrile is obtainable by using the metal oxide catalyst selected from ZnO, CoO, and combinations thereof.

8. The method of claim 7 wherein the metal oxide catalyst is ZnO, and wherein the ZnO has a concentration relative to the dimer fatty acid of about 0.001% by weight to about 0.2% by weight.

9. The method of claim 8 wherein the dimer fatty acid includes from 12 to 60 carbon atoms.

10. The method of claim 9 wherein the dimer fatty acid includes from 24 to 48 carbon atoms.

11. The method of claim 1 wherein the dimer fatty acid includes from 12 to 60 carbon atoms.

12. The method of claim 11 wherein the dimer fatty acid includes from 24 to 48 carbon atoms.

13. The method of claim 1 wherein the dimeric nitrile is obtainable by removing the water from the dimeric amide at a temperature between about 200° C. and about 400° C. under flow of a gas or application of a vacuum.

14. The method of claim 1 wherein the collector composition includes less than about 30 wt % of dimeric amine based on the weight of dimeric fatty nitrile.

15. The method of claim 1 wherein the collector composition additionally includes at least one collector selected from xanthates, dithiophosphates, thionocarbamates, thiocarbamates, mercaptobenzylthiazoles, monothiophosphates, dithiophosphinates, hydroxamates, alkynes, and combinations thereof or a frother selected from phenols, alkyl sulfates, C5-C8 cyclic alcohols, alkoxyalkanes, polypropylene glycol ethers, polyglycol ethers, polyglycol glycerol ethers, pyridine base, natural oils, mixed ethers, ethoxylated alcohols, and combinations thereof.

16. The method of claim 1 wherein the dimeric nitrile has the general formula (I):

wherein R 1 , R 2 , R 3 , and R 4 are saturated or unsaturated, aliphatic or aromatic, linear, cyclic or branched, hydrocarbon groups, each group independently including from 3 to 14 carbon atoms, and
wherein the degree of unsaturation of the dimeric nitrile is from about 0.1 to 0.5.

17. The method of claim 1 comprising the steps of:
conditioning, in an aqueous solution, a pulped metallic or mineral ore wherein the metallic or mineral ore is a metallic sulphide ore including copper, gold, platinum, silver, nickel, molybdenum, arsenic, cobalt, zinc, lead, tin, antimony, or combinations thereof to form a mixture;
optionally concentrating the mixture with magnetic separation;
optionally adding a frother to the mixture;
optionally conditioning the mixture with a flotation depressant or flotation activator;
optionally adjusting the pH of the mixture;
adding the collector composition;
optionally adding an additional flotation aid to the mixture; and
performing a froth flotation by introducing air into the mixture and skimming off froth formed therein to recover metals and/or minerals.

18. A collector composition comprising:
as component (a), from 1% by weight to 99% by weight of a dimeric nitrile compound obtainable by a process comprising:
reacting a dimer fatty acid with ammonia at a temperature between about 200° C. and about 400° C. to form a dimeric amide; and
removing water from the dimeric amide to form the dimeric nitrile compound;

wherein the dimeric nitrile compound has the general formula (I):

wherein R 1 , R 2 , R 3 , and R 4 are saturated or unsaturated, aliphatic or aromatic, linear, cyclic or branched, hydrocarbon groups, each group independently including from 3 to 14 carbon atoms, and wherein the degree of unsaturation of the dimeric nitrile compound is from 0.1 to 0.5, and
as component (b), from 1% by weight to 99% by weight of a collector selected from xanthates, dithiophosphates, thionocarbamates, thiocarbamates, alkynes, mercaptobenzylthiazoles, monothiophosphates, dithiophosphinates, hydroxamates, and combinations thereof or a frother selected from phenols, alkyl sulfates, C5-C8 cyclic alcohols, alkoxyalkanes, polypropylene glycol ethers, polyglycol ethers, polyglycol glycerol ethers, pyridine base, natural oils, mixed ethers, ethoxylated alcohols, and combinations thereof.

19. The collector composition of claim 18 wherein the dimer fatty acid includes from 12 to 60 carbon atoms, the dimer fatty acid is reacted with the ammonia at a pressure between about 0 kPa and about 507 kPa, the ammonia is added to a reaction vessel containing the dimer fatty acid at a rate of about 0.1 moles per hour to about 5 moles per hour, the dimer fatty acid is reacted with the ammonia in the presence of a metal oxide catalyst, and the water is removed from the dimeric amide at a temperature between about 200° C. and about 400° C. under flow of a gas or application of a vacuum.

20. The collector composition of claim 18 including from 20% by weight to 80% by weight of component (a) and from 20% by weight to 80% by weight of component (b).

Assignees

• Nouryon Chemicals Int Bv

Inventors

• Lewis Andrew Clist
• Baan Willem Hendrikus

Classifications

• B03D1/01 Primary

  containing nitrogen · CPC title

• C07C255/00

  Carboxylic acid nitriles (cyanogen or compounds thereof C01C3/00) · CPC title

• B03D2201/02

  Collectors · CPC title

• C07C253/18

  by reaction of ammonia or amines with compounds containing carbon-to-carbon multiple bonds other than in six-membered aromatic rings · CPC title

• C02F2101/20

  Heavy metals or heavy metal compounds · CPC title