Nuclear reactor component having a coating of amorphous chromium carbide

Patent metadata

Field	Value
Publication number	US-11545273-B2
Application number	US-202017022866-A
Country	US
Kind code	B2
Filing date	Sep 16, 2020
Priority date	Sep 28, 2016
Publication date	Jan 3, 2023
Grant date	Jan 3, 2023

Abstract

A composite nuclear reactor component comprises a support and a protective layer (2). The support contains a substrate (1) based on a metal. The substrate is coated with an interposed layer (3) positioned between the substrate (1) and the protective layer (2). The protective layer (2) is composed of a material which comprises amorphous chromium carbide. The nuclear reactor component provides for improved resistance to oxidation, hydriding, and/or migration of undesired material.

First claim

The invention claimed is:

1. A nuclear component chosen from a nuclear fuel cladding, a spacer grid, a guide tube, a plate fuel or an absorber rod, comprising:
i) a support containing a substrate based on a metal chosen from zirconium, titanium, vanadium, molybdenum or base alloys thereof ( 1 ), the substrate ( 1 ) being coated with an interposed layer ( 3 ) placed between the substrate ( 1 ) and at least one protective layer ( 2 );
ii) said at least one protective layer ( 2 ) coating said interposed layer and composed of a protective material comprising chromium which is an amorphous chromium carbide, wherein the interposed layer ( 3 ) comprises at least one interposed material chosen from tantalum, molybdenum, tungsten, niobium, vanadium, alloys thereof, a titanium carbonitride, a mixed titanium silicon nitride, a mixed titanium silicon carbide, a mixed titanium silicon carbonitride, a mixed titanium aluminum nitride, or mixtures thereof.

2. Nuclear component according to claim 1 , wherein the nuclear component further comprises a liner ( 4 ) placed on the inner surface of said support, the inner surface of said support being the surface opposite to the medium that is external to the nuclear component.

3. Nuclear component according to claim 1 , wherein said at least one protective layer ( 2 ) is an outer protective layer ( 2 A) which coats the outer surface of said interposed layer which is the surface of said interposed layer facing the medium that is external to the nuclear component; and/or, when the nuclear component comprises an inner volume, an inner protective layer ( 2 B) which coats the inner surface of said support.

4. Nuclear component according to claim 2 , wherein the material of which the liner ( 4 ) is composed comprises a titanium nitride, a titanium carbonitride, a mixed titanium silicon nitride, a mixed titanium silicon carbide, a mixed titanium silicon carbonitride, a mixed titanium aluminum nitride, or mixtures thereof.

5. Nuclear component according to claim 1 , wherein the protective material is doped with an addition element chosen from yttrium, aluminum, vanadium, niobium, molybdenum, tungsten, or mixtures thereof.

6. Nuclear component according to claim 5 , wherein the protective material comprises the addition element in a content of from 1 atom % to 10 atom %.

7. Nuclear component according to claim 1 , wherein the nuclear component comprises:
a zirconium-based substrate ( 1 ) and a protective layer ( 2 ) comprising amorphous chromium carbide, or;
a molybdenum-based substrate ( 1 ) and a protective layer ( 2 ) comprising amorphous chromium carbide.

8. Nuclear component according to claim 1 , wherein said at least one protective layer ( 2 ) has a composition gradient.

9. Nuclear component according to claim 1 , wherein said at least one protective layer ( 2 ) has an equiaxed structure.

10. Nuclear component according to claim 1 , wherein said at least one protective layer ( 2 ) has a density comprised between 90% and 100% of the density in solid form of the stable metallic chromium of centered cubic crystallographic structure according to the Im-3m space group.

11. Nuclear component according to claim 1 , wherein several protective layers of identical or different composition form, respectively, a homogeneous multilayer protective coating or a heterogeneous multilayer protective coating.

12. Nuclear component according to claim 11 , wherein the heterogeneous multilayer protective coating comprises protective layers composed of:
chromium and amorphous chromium carbide, or
amorphous chromium carbide and chromium nitride, or
chromium, amorphous chromium carbide and chromium nitride, or
mixed chromium silicon carbide and amorphous chromium carbide, or
mixed chromium silicon nitride and amorphous chromium carbide.

13. The nuclear component according to claim 2 , wherein said at least one protective layer ( 2 ) is an outer protective layer ( 2 A) which coats the outer surface of said interposed layer which is the surface of said interposed layer facing the medium that is external to the nuclear component; and/or, when the nuclear component comprises an inner volume, an inner protective layer ( 2 B) which coats the inner surface of said support coated with the liner ( 4 ), the liner ( 4 ) being positioned between the inner protective layer ( 2 B) and the substrate ( 1 ).

Assignees

• Commissariat Energie Atomique

Inventors

• Schuster Frédéric
• Lomello Fernando
• Maury Francis
• Michau Alexandre
• Boichot Raphaël
• Pons Michel

Classifications

• C23C16/32

  Carbides · CPC title

• C23C16/18

  from metallo-organic compounds · CPC title

• G21C3/36

  Assemblies of plate-shaped fuel elements or coaxial tubes · CPC title

• C23C16/045

  Coating cavities or hollow spaces, e.g. interior of tubes; Infiltration of porous substrates · CPC title

• G21C3/34

  Spacer grids · CPC title