Flue gas recycle method for thermochemical regeneration

Patent metadata

Field	Value
Publication number	US-11543183-B2
Application number	US-201916585378-A
Country	US
Kind code	B2
Filing date	Sep 27, 2019
Priority date	Oct 16, 2018
Publication date	Jan 3, 2023
Grant date	Jan 3, 2023

Abstract

In a thermochemical regenerator wherein gaseous combustion products that are formed by combustion in a furnace are passed from the furnace into and through a first regenerator, the combustion products are combined with gaseous fuel, and the resulting mixture is passed into and through a second regenerator wherein the mixture undergoes an endothermic reaction to form syngas, the thermochemical regeneration is enhanced by injecting fuel gas into a recycle stream comprising the combustion products from the first regenerator to entrain recycled flue gas that passes out of the first regenerator and to impel the mixture into the other regenerator.

First claim

What is claimed is:

1. A method of carrying out combustion in a furnace, comprising
(A) combusting fuel in a furnace to produce gaseous combustion products, and
(B) alternately

(1) passing gaseous combustion products from the furnace into and through a cooled first regenerator to heat the first regenerator and cool said gaseous combustion products, and injecting a stream of gaseous fuel into a recycle stream comprising said gaseous combustion products cooled in said first regenerator, to entrain said recycle stream into said injected stream of gaseous fuel thereby forming a mixture of the gaseous fuel with said entrained gaseous combustion products and to impel the mixture into a heated second regenerator, ad feeing additional gaseous fuel into the mixture of gaseous fuel with entrained gaseous combustion products before the mixture is impelled into the heated second regenerator and, in the second regenerator, reacting the gaseous combustion products and the fuel in said mixture in an endothermic reaction to form syngas comprising hydrogen and CO, and passing said syngas from the second regenerator into the furnace and combusting it in the furnace, and
(2) passing gaseous combustion products from the furnace into and through a cooled second regenerator to heat the second regenerator and cool said gaseous combustion products, and injecting a stream of gaseous fuel into a recycle stream comprising said gaseous combustion products cooled in said second regenerator, to entrain said recycle stream into said injected stream of gaseous fuel thereby forming a mixture of the gaseous fuel with said entrained gaseous combustion products and to impel the mixture into a heated first regenerator, and feeding additional gaseous fuel into the mixture of gaseous fuel with entrained gaseous combustion products before the mixture is impelled into the heated first generator and, in the first regenerator, reacting the gaseous combustion products and the fuel in said mixture in an endothermic reaction to form syngas comprising hydrogen and CO, and passing said syngas from the first regenerator into the furnace and combusting it in the furnace.

2. A method according to claim 1 where in step (B)(1) said stream of gaseous fuel is injected into said gaseous combustion products in a first chamber of a device that has first and second chambers that are connected by a passageway, and said mixture of gaseous fuel and gaseous combustion products is passed from said first chamber through said passageway and through said second chamber into the heated second regenerator; and wherein in step (B)(2) said stream of gaseous fuel is injected into said gaseous combustion products in said second chamber of said device and said mixture of gaseous fuel and gaseous combustion products is passed from said second chamber through said passageway and through said first chamber into the heated first regenerator.

3. A method according to claim 2 wherein the first chamber is within the first regenerator and the second chamber is within the second regenerator, the first and second regenerators are separated by a wall that is in contact with regenerators, and the passageway between the first and second chambers passes through the wall.

4. A method according to claim 2 wherein said passageway has a converging-diverging section in the passageway.

5. A method according to claim 4 wherein said converging-diverging section is geometrically symmetrical.

6. A method according to claim 1 wherein at the end of step (B)(1) before step (B)(2) is begun, the passage of gaseous fuel into the second regenerator is discontinued, and then a stream of motive gas which does not contain gaseous fuel is injected into a recycle stream comprising said gaseous combustion products cooled in said first regenerator, to entrain said recycle stream into said injected stream of motive gas thereby forming, a mixture of the motive gas with said entrained gaseous combustion products and to impel the mixture into a heated second regenerator, to purge gaseous fuel from the second regenerator; and wherein at the end of step (B)(2) before step (B)(1) is begun, the passage of gaseous fuel into the first regenerator is discontinued, and then a stream of motive gas which does not contain gaseous fuel is injected into a recycle stream comprising said gaseous combustion products cooled in said second regenerator, to entrain said recycle stream into said injected stream of motive gas thereby forming a mixture of the motive gas with said entrained gaseous combustion products and to impel the mixture into a heated first regenerator, to purge gaseous fuel from the first regenerator.

7. A method according to claim 6 wherein said motive gas is selected from the group consisting of steam, air, recycled cooled flue gas, and mixtures thereof.

8. A method according to claim 6 wherein the ratio of the mass flow rate of said entrained recycle stream to the mass flow rate of said stream of motive gas is between 1 to 30.

9. A method according to claim 6 wherein the ratio of the mass flow rate of said entrained recycle stream to the mass flow rate of said stream of motive gas is between 1 to 20.

10. A method according to claim 6 wherein the ratio of the mass flow rate of said entrained recycle stream to the mass flow rate of said stream of motive gas is between 5 to 30.

11. A method according to claim 6 wherein the ratio of the mass flow rate of said entrained recycle stream to the mass flow rate of said stream of motive gas is between 5 to 20.

12. A method according to claim 6 wherein the ratio of the mass flow rate of said entrained recycle stream to the mass flow rate of said stream of motive gas is between 10 to 30.

13. A method according to claim 6 wherein the oxygen concentration in said mixture of the motive gas with said entrained gaseous combustion products is less than 10% volume on a wet basis.

14. A method according to claim 6 wherein the oxygen concentration in said mixture of the motive gas with said entrained gaseous combustion products is less than 6% volume on a wet basis.

15. A method according to claim 6 wherein the oxygen concentration in said mixture of the motive gas with said entrained gaseous combustion products is less than 4% volume on a wet basis.

16. A method according to claim 6 wherein the oxygen concentration in said mixture of the motive gas with said entrained gaseous combustion products is less than 2% volume on a wet basis.

17. A method according to claim 1 wherein the mass flow ratio of said entrained recycle stream to said gaseous fuel is between 0.5 to 30.

18. A method according to claim 1 wherein the mass flow ratio of said entrained recycle stream to said gaseous fuel is between 0.5 to 20.

19. A method according to claim 1 wherein the mass flow rate of said additional fuel is greater than the mass flow rate of said gaseous fuel.

Assignees

• Kobayashi Hisashi
• Praxair Technology Inc

Inventors

• Kobayashi Hisashi

Classifications

• F27B3/266 Primary

  Exhaust gases reversing flow devices · CPC title

• C03B5/237

  Regenerators or recuperators specially adapted for glass-melting furnaces · CPC title

• C03B5/235 Primary

  Heating the glass (C03B5/02, C03B5/18, C03B5/225 take precedence) · CPC title

• F23L15/02 Primary

  Arrangements of regenerators · CPC title

• C01B2203/148

  involving a recycle stream to the feed of the process for making hydrogen or synthesis gas · CPC title